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Palladate precatalysts for the formation of C-N and C-C bonds
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- Journal Article
- A1
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Copper(I)-N-heterocyclic carbene complexes as efficient catalysts for the synthesis of 1,4-disubstituted 1,2,3-sulfonyltriazoles in air
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- Journal Article
- A1
- open access
Expedient syntheses of neutral and cationic Au(I)-NHC complexes
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- Journal Article
- A1
- open access
Inner-sphere versus outer-sphere coordination of BF4- in a NHC-gold(I) complex
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Mechanism of the Suzuki-Miyaura cross-coupling reaction mediated by [Pd(NHC)(allyl)Cl] precatalysts
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Synthesis and characterization of gold(I) complexes of dibenzotropylidene-functionalized NHC ligands (Trop-NHCs)
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Synthesis of homoleptic and heteroleptic bis-N-heterocylic carbene group 11 complexes
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Mechanistic insight into asymmetric N-H insertion cooperatively catalyzed by a dirhodium compound and a spiro chiral phosphoric acid
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Mechanistic insight into the rhodium-catalyzed O-H insertion reaction : a DFT study
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Exploring the coordination of cyclic selenoureas to gold(I)
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Methoxy-functionalized N-heterocyclic carbenes
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[Pd(IPr*OMe)(cin)Cl] (cin = cinnamyl) : a versatile catalyst for C-N and C-C bond formation
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New [Au(NHC)(OH)] complexes for silver-free protocols
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Mechanistic insight into the (NHC)copper(I)-catalyzed hydrosilylation of ketones
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Mixed N heterocyclic carbene/phosphite ruthenium complexes : the effect of a Bulkier NHC
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Chemoselective oxidation of secondary alcohols using a ruthenium phenylindenyl complex
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Effect of electronic enrichment of NHCs on the catalytic activity of [Pd(NHC)(acac)Cl] in Buchwald-Hartwig coupling
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Enhanced activity of [Ni(NHC)CpCl] complexes in arylamination catalysis
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Exploring the limits of catalytic ammonia-borane dehydrogenation using a bis(N-heterocyclic carbene) iridium(III) complex
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Steric and electronic parameters of a bulky yet flexible N-heterocyclic carbene : 1,3-bis(2,6-bis(1-ethylpropyl)phenyl)imidazol-2-ylidene (IPent)
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Synthesis of N-heterocyclic carbene gold complexes using solution-phase and solid-state protocols
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[{Au(NHC)}2(µ-OH)][BF4] : silver-free and acid-free catalysts for water-inclusive gold-mediated organic transformations
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[Pd(IPr*OMe)(acac)Cl] : tuning the N-heterocyclic carbene in catalytic C-N bond formation
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Striking a compromise : polar functional group tolerance versus insertion barrier height for olefin polymerization catalysts
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Synthesis and reactivity of ruthenium phosphite indenylidene complexes
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Effect of ligand bulk in ruthenium-catalyzed olefin metathesis : IPr* vs IPr
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[Pd(IPr*)(3-Cl-pyridinyl)Cl2] : a novel and efficient PEPPSI precatalyst
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Bulky N-heterocyclic carbene IPr* in selected organo- and transition metal-mediated catalytic applications
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[Pd(IPr*(acac)Cl] : an easily synthesized, bulky precatalyst for C-N bond formation
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Coordinatively unsaturated ruthenium complexes as efficient alkyne-azide cycloaddition catalysts
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Heteroleptic bis(N-heterocyclic carbene)copper(I) complexes : highly efficient systems for the [3+2] cycloaddition of azides and alkynes
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Polymerization of racemic β-butyrolactone using gold catalysts : a simple access to biodegradable polymers
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Luminescent hyperbranched polymers : combining thiol-yne chemistry with gold-mediated C-H bond activation
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Steric and electronic parameters characterizing bulky and electron-rich dialkylbiarylphosphines
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Ruthenium hydroxide complexes in the racemization of secondary alcohols
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Selectivity switch in the synthesis of vinylgold(I) intermediates
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Influence of a very bulky N-heterocyclic carbene in gold-mediated catalysis
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Highly active iridium(III)-NHC system for the catalytic B-N bond activation and subsequent solvolysis of ammonia-borane
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Synthesis, characterization, and reactivity of N-heterocyclic carbene palladium(II) hydroxide dimers
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Highly active well-defined palladium precatalysts for the efficient amination of aryl chlorides
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Expeditious synthesis of [Au(NHC)(L)]+ (NHC = N-heterocyclic carbene; L = phosphine or NHC) complexes
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Solution calorimetric study of ligand exchange reactions in the [Au(L)Cl] system (L = phosphine and phosphite)
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A versatile cuprous synthon : [Cu(IPr)(OH)] (IPr=1,3 bis(diisopropylphenyl)imidazol-2-ylidene)
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Gold-catalyzed Meyer-Schuster rearrangement : application to the synthesis of prostaglandins
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Ruthenium complexes bearing two N-heterocyclic carbene ligands in low catalyst loading olefin metathesis reactions
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Mixed phosphite/N-heterocyclic carbene complexes : synthesis, characterization and catalytic studies
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Ruthenium olefin metathesis catalysts with N-heterocyclic carbene ligands bearing N-naphthyl side chains
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Synthetic and structural studies of [AuCl3(NHC)] complexes
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Indenylidene ruthenium complex bearing a sterically demanding NHC ligand : an efficient catalyst for olefin metathesis at room temperature
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A comparative study on (NHC)Pd(acac)Cl complexes (NHC = N-heterocyclic carbene) : indications for the origin of the different reactivity of saturated and unsaturated NHC in cross-coupling reactions
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Highly active [Pd(µ-Cl)(Cl)(NHC)]2 (NHC = N-heterocyclic carbene) in the cross-coupling of Grignard reagents with aryl chlorides
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Reaction intermediates in the synthesis of new hydrido, N-heterocyclic dicarbene iridium(III) pincer complexes
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Remarkable base effect in the synthesis of mono- and dinuclear iridium(I) NHC complexes
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N-Heterocyclic carbenes (NHCs) containing N-C-palladacycle complexes : synthesis and reactivity in aryl amination reactions
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Synthetic, structural, and thermochemical studies of N-heterocyclic carbene (NHC) and tertiary phosphine ligands in the [(L)2Ni(CO)2] (L = PR3, NHC) system
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Thermodynamics of N-heterocyclic carbene dimerization : the balance of sterics and electronics
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Ionic liquid anchored 'Boomerang' catalysts bearing saturated and unsaturated NHCs : recyclability in biphasic media for cross-metathesis
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Determination of N-heterocyclic carbene (NHC) steric and electronic parameters using the [(NHC)Ir(CO)2Cl] system
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Bis-coordination of N-(alkyl)-N '-(2,6-diisopropylphenyl) heterocyclic carbenes to Grubbs catalysts
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A polystyrene-supported tin trichloride catalyst with a C11-spacer. Catalysis monitoring using high-resolution magic angle spinning NMR
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Electronic properties of N-heterocyclic carbene (NHC) ligands : synthetic, structural, and spectroscopic studies of (NHC)platinum(II) complexes
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Insertion of a N-heterocyclic carbene (NHC) into a platinum-olefin bond
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Synthesis, characterization, and structure of [GaCl3(NHC)] complexes
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Synthesis, characterization and reactivity of N-heterocyclic carbene gold(III) complexes
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Synthesis and characterization of gold(I) N-heterocyclic carbene complexes bearing biologically compatible moieties
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Homogeneous nickel catalysts for the selective transfer of a single arylthio group in the catalytic hydrothiolation of alkynes
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Alkane carbon-hydrogen bond functionalization with (NHC)MCl precatalysts (M = Cu, Au ; NHC=N-heterocyclic carbene)
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Cationic copper(I) complexes as efficient precatalysts for the hydrosilylation of carbonyl compounds
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Synthesis of well-defined N-heterocyclic carbene silver(I) complexes
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Simple synthesis of CpNi(NHC)Cl complexes (Cp = cyclopentadienyl; NHC=N-heterocyclic carbene)
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Synthesis and structural characterization of N-heterocyclic carbene gold(I) complexes
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N-heterocyclic carbenes as activating ligands for hydrogenation and isomerization of unactivated olefins
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N-heterocyclic carbene palladium complexes bearing carboxylate ligands and their catalytic activity in the hydroarylation of alkynes
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Synthetic and structural studies of (NHC)Pd(allyl)Cl complexes (NHC = N-heterocyclic carbene)
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(NHC)Cu-I (NHC = N-heterocyclic carbene) complexes as efficient catalysts for the reduction of carbonyl compounds
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Structure characterization of the products of the reaction between racemic 1,2,4-butane triol and di-tert-butyltin oxide
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A combined experimental and theoretical study examining the binding of N-heterocyclic carbenes (NHC) to the Cp*RuCl (Cp* = η5-C5Me5) moiety : insight into stereoelectronic differences between unsaturated and saturated NHC ligands
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Telomerization of amines mediated by cationic N-heterocyclic carbene (NHC) palladium complexes
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Binding of specialty phosphines to metals : synthesis, structure, and solution calorimetry of the phosphirane complex [PtMe2(iPrBABAR-Phos)2]
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High-activity catalysts for Suzuki coupling and amination reactions with deactivated aryl chloride substrates : importance of the palladium source
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Activation and reactivity of (NHC)Pd(allyl)Cl (NHC = N-heterocyclic carbene) complexes in cross-coupling reactions
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Suzuki-Miyaura cross-coupling reactions mediated by palladium/imidazolium salt systems
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π effects involving Rh-PZ3 compounds : the quantitative analysis of ligand effects (QALE)
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Efficient Sonogashira, reactions of aryl bromides with alkynylsilanes catalyzed by a palladium/imidazolium salt system
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Preparation and activity of recyclable polymer-supported ruthenium olefin metathesis catalysts
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Improved one-pot synthesis of second-generation ruthenium olefin metathesis catalysts
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Di-n-butyltin methyl- and phenylphosphonates
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Cationic iridium complexes bearing imidazol-2-ylidene ligands as transfer hydrogenation catalysts
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Catalytic dehalogenation of aryl halides mediated by a palladium/imidazolium salt system
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Structural and thermochemical studies of chiral nucleophilic carbenes in the Cp*RuCl(L*) (Cp* = η5-C5Me5; L* = chiral nucleophilic carbene) system
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A cationic iridium complex bearing an imidazol-2-ylidene ligand as alkene hydrogenation catalyst
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Catalytic hydrogenation of alkenes by the ruthenium-carbene complex HRu(CO)Cl(PCy3)(IMes) (IMes = bis(1,3-(2,4,6-trimethylphenyl)imidazol-2-ylidene)
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Reaction of butyltin hydroxide oxide with p-toluenesulfonic acid: Synthesis, X-ray crystal analysis, and multinuclear NMR characterization of {(BuSn)(12)O-14(OH)(6)}(4-CH3C6H4SO3)(2)
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Simple and convenient synthetic procedure leading to ruthenium olefin metathesis catalysts bearing the N,N'-bis(mesityl)imidazol-2-ylidene (IMes) ligand
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Synthetic, structural, and solution calorimetric studies of Pt(CH3)(2)(PP) complexes
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Intramolecular C-H activation involving a rhodium-imidazol-2-ylidene complex and its reaction with H2 and CO
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Effect of ancillary ligation on the relative bond disruption enthalpies of Ru-H and Ru-Cl bonds in Cp(PR3)2RuX (PR3 = PMe3, PMe2Ph, PMePh2, PPh3; X = H, Cl)
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13C-119Sn Correlation NMR in solution and solid-state CP/MAS NMR of bis(tributylstannyl(IV))O-5,6-isopropylidene-l-(+)-ascorbate
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Influence of sterically demanding carbene ligation on catalytic behavior and thermal stability of ruthenium olefin metathesis catalysts
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Indenylidene-imidazolylidene complexes of ruthenium as ring-closing metathesis catalysts
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Coordinatively unsaturated 16-electron ruthenium allenylidene complexes : synthetic, structural, and catalytic studies
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(p-cymene)RuLCl2 (L=1,3-bis(2,4,6-trimethylphenyl)imidazol-2-ylidene and 1,3-bis(2,6-diisopropylphenyl)imidazol-2-ylidene) and related complexes as ring closing metathesis catalysts
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Correlation between structural and solution calorimetric data for Cp*Ru(PR3)2Cl (Cp* = C5Me5) complexes
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Stereoelectronic effects characterizing nucleophilic carbene ligands bound to the Cp*RuCl (Cp* = η5-C5Me5) moiety : a structural and thermochemical investigation
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Catalytic dehalogenation of aryl chlorides mediated by ruthenium(II) phosphine complexes
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Synthetic, structural, and solution thermochemical studies in the dimethylbis(phosphine)platinum(II) system : dichotomy between structural and thermodynamic trends
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Lewis acids accelerate reductive elimination of RCN from P2Pd(R)(CN)
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Synthesis and structure of Di-n-butyltin pyridine-2-phosphonate-6-carboxylate
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Thermochemical investigation of phosphine ligand substitution reactions involving trans-(PR3)2Cl2Ru=CH-CH=CPh2 complexes
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Synthetic, thermochemical, and catalytic studies involving novel R2P(ORf) [R = alkyl or aryl ; R-f = CH2CH2(CF2)5CF3] ligands
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Synthesis and reactivity of the ruthenium(II) dihydride Ru(Ph2PNMeNMePPh2)2H2
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Enthalpies of reaction of [(p-cymene)OsCl2]2 with monodentate tertiary phosphine ligands : importance of steric and electronic ligand factors in an omium(II) system
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Solution calorimetric investigation of oxidative addition of HEAr (E = O, S, Se; Ar = C6H4X, X = CH3, H, Cl, NO2) to (PMe3)4Ru(C2H4) : relationship between HEAr acidity and enthalpy of reaction
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Enthalpies of reaction of Cp'Ru(COD)Cl (Cp' = C5H5, C5Me5, COD = cyclooctadiene) with π-acceptor chelating phosphine ligands
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Solution thermochemical study of tertiary phosphine ligand substitution reactions in the Rh(acac)(CO)(PR3) system
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Terminal platinum(II) phosphido complexes : synthesis, structure, and thermochemistry
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Solution thermochemical study of a fluorous tertiary phosphine ligand in rhodium and ruthenium systems
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Solution thermochemical and structural studies of ligand substitution of N-pyrrolyl phosphine ligands in the (p-cymene)RuCl2(PR3) system
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Synthesis, molecular structure, and stereochemical nonrigidity of bis(3-(dimethylamino)propyl)difluorostal dihydrate, {[Me(2)N(CH2)(3)]2SnF2 center dot 2H(2)O}, and enhanced reactivity of its fluoride adduct {[Me(2)N(CH2)(3)]2SnF3}(-)Bu(4)N(+) toward dichloromethane
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Convenient synthesis of ruthenium(II) dihydride phosphine complexes Ru(H)2(PP)2 and Ru(H)2(PR3)x (x = 3 and 4)
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Synthesis, characterization, and catalytic behavior of ruthenium(II) Schiff base complexes
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Ligand (L) influence on CO binding enthalpies to Ru(CO)2L2
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N-pyrrolyl phosphines : enhanced π-acceptor character via carboalkoxy substitution
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X-ray diffraction and gradient-assisted 2D H-1-Sn-119 HMQC NMR studies on the structure of condensation complexes of salicylaldoxime and dimethyltin(IV) oxide
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Organoruthenium thermochemistry : enthalpies of reaction of Cp'Ru(COD)Cl (Cp'=η5-C5H5 and η5-C5Me5) with tertiary phosphite ligands
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Thermochemistry of oxygen atom transfer from Cp*ReO3
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Estimating the effective steric impact of PtBu2Me, PiPr3, and PCy3
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Solution thermochemical study of tertiary phosphine ligand substitution reactions in the RhCl(CO)(PR3)2 system
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Solution thermochemical and structural studies of ligand substitution of N-pyrrolyl-substituted phosphine ligands in the Cp'Ru(PR3)2Cl (Cp'=η5-C5H5 and η5-C5Me5) systems
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Relative finding energies of tertiary phosphine ligands to the Cp*RuOCH2CF3 (Cp*= η5-C5Me5) moiety
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Enthalpies of reaction of Cp'Ru(COD)Cl (Cp' = C5H5, C5Me5; COD = cyclooctadiene) with P(p-XC6H4)3 (X = Cl, F, H, CH3, CF3, OCH3) ligands : ligand steric vs electronic contributions to the enthalpy of reaction
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Enthalpies of reaction of ((p-cymene)RuCl2)2 with monodentate tertiary phosphine ligands : importance of both steric and electronic ligand factors in a ruthenium(II) system
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Addition of aldehydes and acyl chlorides to [Rh(PiPr3)2Cl]2 : thermodynamics and molecular and crystal structures of Rh(PiPr3)2ClX[C(O)Ph] (X = H, Cl)
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Solution thermochemical study of ligand steric influences on substitution enthalpies in the L2Fe(CO)3 system
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Thermodynamic studies of the addition of N2, C2H4, and alkynes to [Rh(PiPr3)2Cl]2
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Organoiron thermochemistry : solution thermochemical investigation of tertiary phosphine ligand electronic effects in trans-(P(p-XC6H4)3)2Fe(CO)3 complexes
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Organoruthenium thermochemistry : absolute metal-ligand bond disruption enthalpies in the (η5-C5Me5)(CO)2Ru-X system (X = H, Cl, Br, I) and thermodynamic influences of ancillary ligand variation on the Ru-X bond disruption enthalpy
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Enthalpies of reaction of (η5-C5H5)Ru(cyclooctadiene)Cl with tertiary phosphine ligands : ligand substitution as a gauge for metal basicity and a linear correlation of bond length and bond enthalpy
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Enthalpies of reaction of Cp*Ru(COD)Cl (Cp* = η5-C5Me5; COD = cyclooctadiene) with chelating tertiary phosphine ligands : solution thermochemical investigation of ligand substitution and ring strain energies in Cp*Ru(PP)Cl complexes
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Synthesis of (η5-C5Me5)Ru(η6-tryptamine)(CF3SO3) complexes : chemospecific η6 coordination of the (η5-C5Me5)Ru+ moiety
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Relative binding energies of sterically demanding tertiary phosphine ligands to the Cp*RuCl (Cp* = η5-C5Me5) moiety : thermochemical investigation of coordinatively nnsaturated organoruthenium complexes
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Enthalpies of reaction of CpRu(COD)Cl (Cp = η5-C5H5; COD = cyclooctadiene) with chelating tertiary phosphine ligands : solution thermochemical investigation of ligand substitution and ring strain energies in CpRu(R2P(CH2)nPR2)Cl complexes
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Organoruthenium thermochemistry : enthalpies of reaction of (Cp*RuCl)4 and Cp*Ru(COD)Cl (Cp* = η5-C5Me5, COD = cyclooctadiene) with dienes and tertiary phosphine ligands
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Alkyne coupling reactions mediated by organolanthanides : probing the mechanism by metal and alkyne variation
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Enthalpies of reaction of complex Cp*Ru(CH3CN)3+O3SCF3- (Cp* = η5-C5Me5) with arenes : solution thermochemical study of arene binding to the Cp*Ru+ fragment
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Synthesis and characterization of an organoyttrium dimer produced via an Arbuzov dealkylation reaction
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Enthalpies of reaction of (benzylideneacetone)iron tricarbonyl, (BDA)Fe(CO)3, with phosphine ligands : thermodynamic insights into iron chemistry
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Synthesis and structural characterization of a tetranuclear organolanthanide hydrazido complex
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Organolanthanide-catalyzed dehydrogenative coupling of silanes : mechanistic implications
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Organo-f-element thermochemistry : actinide-group 14 element and actinide-transition-element bond disruption enthalpies and stoichiometric/catalytic chemical implications thereof in heterobimetallic tris(cyclopentadienyl)uranium(IV) compounds
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Organolanthanide-centered hydroamination/cyclization of aminoolefins : expedient oxidative access to catalytic cycles
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Thermodynamic and kinetic studies of the complexes W(CO)3(PCy3)2(L) (L = H2, N2, NCCH3, pyridine, P(OMe)3, CO)
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Heats of reaction of (toluene)Mo(CO)3 with substituted arenes, sodium cyclopentadiene, nitriles, isocyanides, and other ligands : solution thermodynamic study of ligand exchange in the complexes fac-L3Mo(CO)3