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We need to talk about Kekule : the 150th anniversary of the benzene structure
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WY 1048, a 17-methyl 19-nor D-ring analog of vitamin D3, in combination with risedronate restores bone mass in a mouse model of postmenopausal osteoporosis
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- Journal Article
- A1
- open access
Possibility of [1,5] sigmatropic shifts in bicyclo[4.2.0]octa-2,4-dienes
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- Journal Article
- A1
- open access
1,25-Dihydroxyvitamin D-3 and its analog TX527 promote a stable regulatory T cell phenotype in T cells from type 1 diabetes patients
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A proteomic approach on the effects of TX527, a 1α,25-dihydroxyvitamin D₃ analog, in human T lymphocytes
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Cell cycle arrest and apoptosis induced by 1α,25(OH)₂D₃ and TX527 in Kaposi sarcoma is VDR dependent
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- Conference Paper
- C3
- open access
Convenient and versatile route to 2-alkyl-19-nor-analogues of calcitriol
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Synthesis of 2-ethyl-19-nor analogs of 1α,25-dihydroxyvitamin D₃
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The vitamin D analog TX527 ameliorates disease symptoms in a chemically induced model of inflammatory bowel disease
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A convenient and versatile route to 2-alkyl-19-nor-analogs of calcitriol
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Applications of (4+3) cycloaddition reactions of furfuryl cations
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Analogs of calcitriol
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CD-ring modified vitamin D-3 analogs and their superagonistic action
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Cyclopentanones XIV : the synthesis of a prostanoid synthon starting from 3-alkyl-1,2,4-cyclopentanetriones
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Cyclopentanones XVII : prostaglandin synthesis involving the lithium-liquid ammonia reduction of 3-alkyl-4-hydroxy-2-(1′-octynyl)-2-cyclopentenones
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Development of Analogues of 1 alpha,25-Dihydroxyvitamin D-3 with Biased Side-Chain Orientation: C20 Methylated Des-C,D-homo Analogues
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- Journal Article
- A1
- open access
Synthesis of 1 alpha,25-Dihydroxyvitamin D Analogues Featuring a S-2-symmetric CD-ring Core
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Synthesis of 22-oxaspiro[4.5]decane CD-ring modified analogs of 1 alpha,25-dihydroxyvitamin D3
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Microarray analysis of MCF-7 breast cancer cells treated with 1,25-dihydroxyvitamin D-3 or a 17-methyl-D-ring analog
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Antiproliferative and Calcemic Actions of Trans-Decalin CD-Ring Analogs of 1,25-Dihydroxyvitamin D-3
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Nonenzymic polycyclisation of analogues of oxidosqualene with a preformed C-ring
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Synthesis of a tripodal scaffold for solid phase synthesis of artificial receptors
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Superagonistic Fluorinated Vitamin D3 analogs Stabilize Helix 12 of the Vitamin D receptor
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Microarray analysis of MCF-7 breast cancer cells treated with 1,25-(OH)(2)D-3 or the analog WY1112
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Synthesis of 3,4,7,8-Tetrahydronaphthalene-1,5(2H,6H)-dione
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Mechanism and potential of the growth-inhibitory actions of vitamin D and analogs
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The development of CD-ring modified analogs of 1 alpha,25-dihydroxyvitamin D
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Fast and easy detection of aromatic amines on solid support
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Asymmetric synthesis of the epimeric (3S)-3-((E)-Hex-1-eny1)-2-methylcyclohexanones
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- Journal Article
- A1
- open access
Removal of C-ring from the CD-ring skeleton of 1 alpha,25-dihydroxyvitamin D-3 does not alter its target tissue metabolism significantly
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Solid-supported synthesis of highly functionalized tripodal peptides with flexible but preorganized geometry: towards potential serine protease mimics
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Application of the B-alkyl Suzuki-Miyaura cross-coupling reaction to the stereoselective synthesis of analogues of (3S)-oxidosqualene
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Vitamin D analogs and coactivators
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Application of the solid-phase Julia-Lythgoe olefination in vitamin D side-chain construction
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Asymmetric synthesis of (7aS)-7a-methyl-4,5,7,7a-tetrahydro-1H-indene-2,6-dione and useful derivatives thereof
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Synthesis of spiro[4.5] decane CF-ring analogues of 1 alpha,25-dihydroxyvitamin D-3
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Superagonistic action of 14-epi-analogs of 1,25-dihydroxyvitamin D explained by vitamin D receptor-coactivator interaction
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Fine-tuning furan toxicity: fast and quantitative DNA interchain crosslink formation upon selective oxidation of a furan containing oligonucleotide
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Synthesis of 2-methyl and ethyl-substituted 19-nor-1 alpha,25-dihydroxyvitamin D-3 analogues via the cyclovitamin strategy
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Mechanisms for the selective action of Vitamin D analogs
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Altered Vitamin D receptor-coactivator interactions reflect superagonism of Vitamin D analogs
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1,25-Dihydroxyvitamin D-3 and analogues protect primary human keratinocytes against UVB-induced DNA damage
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Biological activity and conformational analysis of C20 and C14 epimers of CD-ring modified trans-decalin 1 alpha,25-dihydroxyvitamin D analogs
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Synthesis and biological activity of 22-oxa CD-ring modified analogues of 1 α,25-dihydroxyvitamin D3 : cis-perhydrindane CE-ring analogues
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Synthesis and biological activity of 22-oxa CD-ring modified analogues of 1 α,25-dihydroxyvitamin D3 : spiro[5.5]undecane CF-ring analogues
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Two 14-epi analogues of 1,25-dihydroxyvitamin D-3 protect human keratinocytes against the effects of UVB
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Synthesis, biological activity, and conformational analysis of CD-ring modified trans-decalin 1 alpha,25-dihydroxyvitamin D analogs
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- Journal Article
- A1
- open access
Previtamin D3 with a trans-fused decalin CD-ring has pronounced genomic activity
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- Journal Article
- A1
- open access
Synthesis and binding affinity studies of muscarinic receptor antagonists related to dehydrohimbacine
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Carbon-carbon bond formation on solid support : application of the classical Julia-Lythgoe olefination
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Synthesis and affinity studies of himbacine derived muscarinic receptor antagonists
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Vitamin D-3 : synthesis of seco-C-9,11-bisnor-17-methyl-1 alpha, 25-dihydroxyvitamin D-3 analogues
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An intramolecular Furan-Diene Diels-Alder approach to 11-oxo 10 alpha-steroids
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A novel short convergent entry into himbacine derivatives
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Evaluation of a two-stage screening procedure in the combinatorial search for serine protease-like activity
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Vitamin D-3: Synthesis of seco C-9,11,21-trisnor-17-methyl-1 alpha,25-dihydroxyvitamin D-3 analogues (vol 12, pg 1629, 2002).
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Vitamin D-3: Synthesis of seco C-9,11,21-trisnor-17-methyl-1 alpha, 25-dihydroxyvitamin D-3 analogues.
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Peptide sequence determination of peptidosteroids on a single bead by electrospray ionization-mass spectroscopy.
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Interaction of two novel 14-epivitamin D-3 analogs with vitamin D-3 receptor-retinoid X receptor heterodimers on vitamin D-3 responsive elements
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A pentaerythritol-based molecular scaffold for solid-phase combinatorial chemistry
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A practical synthesis of 14-epi-19-nor-1a, 25-dihydroxyvitamin D3 analogues and their a-ring epimers
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A short intramolecular Diels-Alder route to himbacine derivatives
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Development of analogues of 1 alpha,25-dihydroxyvitamin D-3 with biased side chain orientation : methylated des-C,D-homo analogues
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Asymmetrization of all-cis-3,5-dihydroxy1-(methoxycarbonyl)cyclohexane and of the 4-methyl and 4-ethyl substituted homologues
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A model for the nonenzymatic BCD cyclization of squalene
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Two novel 14-epi-analogues of 1,25-dihydroxyvitamin D-3 inhibit the growth of human breast cancer cells in vitro and in vivo
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Convergent synthesis of 1 alpha-hydroxyvitamin D-5
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Biological activity of CD-ring modified 1 alpha,25-dihydroxyvitamin D analogues : C-ring and five-membered D-ring analogues
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Application of combinatorial procedures in the search for serine-protease-like activity with focus on the acyl transfer step
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On the unexpected stereochemical outcome of the magnesium in methanol : conjugate reduction of an exocyclic alpha,beta-unsaturated ester
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Novel sensitive colorimetric assay for visual detection of solid-phase bound amines
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Synthesis, biological activity, and conformational analysis of four seco-D-15,19-bisnor-1 alpha,25-dihydroxyvitamin D analogues, diastereomeric at C17 and C20
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Stepwise approach toward first generation nonenzymatic hydrolases
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The biological activity of nonsteroidal vitamin D hormone analogs lacking both the C- and D-rings
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Studies directed towards the total synthesis of (+)-himbacine
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On the use of volume maps in the conformational analysis of vitamin D analogs
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The synthesis of CD-ring modified 1α,25-dihydroxy vitamin D analogues : six-membered D-ring analogues I
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The synthesis of CD-ring modified 1α,25-dihydroxy vitamin D analogues : six-membered D-ring analogues II
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Structure-reactivity relationships in the rate of esterification by acetylimidazole : the influence of the second hydroxy group and of the length of the N-omega-hydroxy-n-alkyl chain in 3-(N-methyl, N-omega-hydroxy-n-alkyl)amino-2-tert-butylpropan-1-ols
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Biotin : a timeless challenge for total synthesis
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Total synthesis of 1 alpha,25-dihydroxy-18-norvitamin D-3
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Estramicins : a novel cyclic diyl precursor derived from estradiol
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Synthesis of CD-ring modified 1 alpha,25-dihydroxy vitamin D analogues : five-membered D-ring analogues
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Synthesis and biological evaluation of 1 alpha-hydroxy-25(R and S)-25,26-epoxy-23-yne vitamin D-3 and of 1a,25(R and S),26-trihydroxy-23-yne vitamin D-3
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The synthesis of di(hydroxyalkyl) substituted bicyclic guanidines
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Mechanism of esterification of 1,3-dimethylamino alcohols by N-acetylimidazole in acetonitrile and the influence of alkyl and geminal dialkyl substitution upon the rate
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Estramycins : a potential acyclic diyl precursor derived from estradiol
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Synthesis of new vitamin D-3 analogues with a decalin-type CD-ring
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Synthesis of CD-ring modified 1 alpha,25-dihydroxy vitamin D analogues : E-ring analogues
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Synthesis of CD-ring modified 1 alpha,25-dihydroxy vitamin D analogues : C-ring analogues
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Studies directed towards the total synthesis of (±)-himbacine
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Estramycins : a new diyl precursor family derived from estradiol
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Synthesis of enantiomerically pure (R)-3-methyl-2-cyclopenten-1-OL and (S)-3-methyl-2-cyclopenten-1-OL
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Biological evaluation of epoxy analogs of 1-alpha,25-dihydroxyvitamin-D-3
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Polyene cyclizations related to oxidosqualene cyclization : a model for the anti-markovnikov closure of ring-C
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Synthesis of a chiral DI(hydroxyalkyl) substituted bicyclic guanidine
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Intramolecular Diels-Alder reaction with furan-diene : syntheses of gibberellins (+)-GA(1) AND (+)-GA(3)
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Novel enantioselective synthesis of (+)-biotin.
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A novel enantioselective synthesis of (+)-biotin
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Intramolecular diels-alder reaction of 8-trifluoromethyl-1,3,8-nonatrienes : an access to angular trifluoromethylated hydrindenes