Synthesis, crystal structures, and properties of novel heterometallic La/Pr-Cu-K and Sm/Eu/Tb-Cu coordination polymers
(2010) CRYSTAL GROWTH & DESIGN. 10(3). p.1059-1067- abstract
- Five new heterometallic coordination polymers, {[LnCu(2)K(pydc)(4)(H2O)(9)]center dot H2O}(n) [Ln = La (1), Ln = Pr (2), H(2)pydc = pyridine-2,5-dicarboxylic acid], {[Ln(2)Cu(pydc)(4)(H2O)(8)]center dot H2O}n [Ln = Sm (3), Ln = Eu (4), Ln = Tb (5)], have been synthesized under hydrothermal conditions and characterized by elemental analysis, IR, thermogravimetric analysis, and single-crystal X-ray diffraction. X-ray structural analysis revealed that complexes 1 and 2 are the first Ln/Cu/K structures containing Cu(II) sandwiched in the interlayer regions of the two La/K planes alternately arranged along the b-axis. In complexes 3-5, two distinct types of building blocks, Ln(pydc)(H2O)(4) and Cu(pydc)(2), are linked together by pydc ligands to form a two-dimensional net structure. The magnetic properties of 1 and 2 and the luminescence properties of 3-5 have been investigated.
Please use this url to cite or link to this publication:
http://hdl.handle.net/1854/LU-976320
- author
- Ya-guan Sun, Xiao-fu Gu, Fu Ding, Philippe Smet UGent, En-jun Gao, Dirk Poelman UGent and Francis Verpoort UGent
- organization
- year
- 2010
- type
- journalArticle (original)
- publication status
- published
- subject
- keyword
- HYDROTHERMAL REACTION, STORAGE, METAL-ORGANIC FRAMEWORK, CHANNELS, METHANE, COMPLEXES, LN, MAGNETIC-PROPERTIES, SYSTEMATIC DESIGN, NANOTUBULAR STRUCTURE
- journal title
- CRYSTAL GROWTH & DESIGN
- Cryst. Growth Des.
- volume
- 10
- issue
- 3
- pages
- 1059 - 1067
- Web of Science type
- Article
- Web of Science id
- 000275049800009
- JCR category
- MATERIALS SCIENCE, MULTIDISCIPLINARY
- JCR impact factor
- 4.389 (2010)
- JCR rank
- 24/219 (2010)
- JCR quartile
- 1 (2010)
- ISSN
- 1528-7483
- DOI
- 10.1021/cg900299v
- language
- English
- UGent publication?
- yes
- classification
- A1
- id
- 976320
- handle
- http://hdl.handle.net/1854/LU-976320
- date created
- 2010-06-10 10:59:01
- date last changed
- 2018-01-29 12:13:08
@article{976320, abstract = {Five new heterometallic coordination polymers, \{[LnCu(2)K(pydc)(4)(H2O)(9)]center dot H2O\}(n) [Ln = La (1), Ln = Pr (2), H(2)pydc = pyridine-2,5-dicarboxylic acid], \{[Ln(2)Cu(pydc)(4)(H2O)(8)]center dot H2O\}n [Ln = Sm (3), Ln = Eu (4), Ln = Tb (5)], have been synthesized under hydrothermal conditions and characterized by elemental analysis, IR, thermogravimetric analysis, and single-crystal X-ray diffraction. X-ray structural analysis revealed that complexes 1 and 2 are the first Ln/Cu/K structures containing Cu(II) sandwiched in the interlayer regions of the two La/K planes alternately arranged along the b-axis. In complexes 3-5, two distinct types of building blocks, Ln(pydc)(H2O)(4) and Cu(pydc)(2), are linked together by pydc ligands to form a two-dimensional net structure. The magnetic properties of 1 and 2 and the luminescence properties of 3-5 have been investigated.}, author = {Sun, Ya-guan and Gu, Xiao-fu and Ding, Fu and Smet, Philippe and Gao, En-jun and Poelman, Dirk and Verpoort, Francis}, issn = {1528-7483}, journal = {CRYSTAL GROWTH \& DESIGN}, keyword = {HYDROTHERMAL REACTION,STORAGE,METAL-ORGANIC FRAMEWORK,CHANNELS,METHANE,COMPLEXES,LN,MAGNETIC-PROPERTIES,SYSTEMATIC DESIGN,NANOTUBULAR STRUCTURE}, language = {eng}, number = {3}, pages = {1059--1067}, title = {Synthesis, crystal structures, and properties of novel heterometallic La/Pr-Cu-K and Sm/Eu/Tb-Cu coordination polymers}, url = {http://dx.doi.org/10.1021/cg900299v}, volume = {10}, year = {2010}, }
- Chicago
- Sun, Ya-guan, Xiao-fu Gu, Fu Ding, Philippe Smet, En-jun Gao, Dirk Poelman, and Francis Verpoort. 2010. “Synthesis, Crystal Structures, and Properties of Novel Heterometallic La/Pr-Cu-K and Sm/Eu/Tb-Cu Coordination Polymers.” Crystal Growth & Design 10 (3): 1059–1067.
- APA
- Sun, Ya-guan, Gu, X., Ding, F., Smet, P., Gao, E., Poelman, D., & Verpoort, F. (2010). Synthesis, crystal structures, and properties of novel heterometallic La/Pr-Cu-K and Sm/Eu/Tb-Cu coordination polymers. CRYSTAL GROWTH & DESIGN, 10(3), 1059–1067.
- Vancouver
- 1.Sun Y, Gu X, Ding F, Smet P, Gao E, Poelman D, et al. Synthesis, crystal structures, and properties of novel heterometallic La/Pr-Cu-K and Sm/Eu/Tb-Cu coordination polymers. CRYSTAL GROWTH & DESIGN. 2010;10(3):1059–67.
- MLA
- Sun, Ya-guan, Xiao-fu Gu, Fu Ding, et al. “Synthesis, Crystal Structures, and Properties of Novel Heterometallic La/Pr-Cu-K and Sm/Eu/Tb-Cu Coordination Polymers.” CRYSTAL GROWTH & DESIGN 10.3 (2010): 1059–1067. Print.