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O,N-bidentate ruthenium azo complexes as catalysts for olefin isomerization reactions

Fu Ding, Yaguang Sun and Francis Verpoort UGent (2010) EUROPEAN JOURNAL OF INORGANIC CHEMISTRY. p.1536-1543
abstract
A series of ruthenium complexes [(eta(6)-p-cymene)RuCl(L)] [ligands L incorporate an azo group (1-5) or an imino group (6-7)] have been synthesized and studied as olefin isomerization catalyst with allylbenzene and 1-octene as model substrates. Temperature and catalyst/substrate mol ratio have been taken into account as parameters to optimize the isomerization reaction conditions. By using H-1, C-13 NMR, FT-IR and microanalysis, the new complexes have been characterized and the molecular structure of complex 4 has been determined by crystal structure determination.
Please use this url to cite or link to this publication:
author
organization
year
type
journalArticle (original)
publication status
published
subject
keyword
SCHIFF-BASE LIGANDS, DOUBLE-BOND MIGRATION, Olefins, Ruthenium, Isomerization, ASYMMETRIC TRANSFER HYDROGENATION, ELASTOMERIC POLYPROPYLENE, CARBENE COMPLEXES, CRYSTAL-STRUCTURE, METAL-COMPLEXES, MECHANISM, METATHESIS, KETONES
journal title
EUROPEAN JOURNAL OF INORGANIC CHEMISTRY
Eur. J. Inorg. Chem.
issue
10
pages
1536 - 1543
Web of Science type
Article
Web of Science id
000276744100011
JCR category
CHEMISTRY, INORGANIC & NUCLEAR
JCR impact factor
2.909 (2010)
JCR rank
11/43 (2010)
JCR quartile
2 (2010)
ISSN
1434-1948
DOI
10.1002/ejic.200900926
language
English
UGent publication?
yes
classification
A1
copyright statement
I have transferred the copyright for this publication to the publisher
id
976292
handle
http://hdl.handle.net/1854/LU-976292
date created
2010-06-10 10:42:15
date last changed
2010-06-22 09:15:46
@article{976292,
  abstract     = {A series of ruthenium complexes [(eta(6)-p-cymene)RuCl(L)] [ligands L incorporate an azo group (1-5) or an imino group (6-7)] have been synthesized and studied as olefin isomerization catalyst with allylbenzene and 1-octene as model substrates. Temperature and catalyst/substrate mol ratio have been taken into account as parameters to optimize the isomerization reaction conditions. By using H-1, C-13 NMR, FT-IR and microanalysis, the new complexes have been characterized and the molecular structure of complex 4 has been determined by crystal structure determination.},
  author       = {Ding, Fu and Sun, Yaguang and Verpoort, Francis},
  issn         = {1434-1948},
  journal      = {EUROPEAN JOURNAL OF INORGANIC CHEMISTRY},
  keyword      = {SCHIFF-BASE LIGANDS,DOUBLE-BOND MIGRATION,Olefins,Ruthenium,Isomerization,ASYMMETRIC TRANSFER HYDROGENATION,ELASTOMERIC POLYPROPYLENE,CARBENE COMPLEXES,CRYSTAL-STRUCTURE,METAL-COMPLEXES,MECHANISM,METATHESIS,KETONES},
  language     = {eng},
  number       = {10},
  pages        = {1536--1543},
  title        = {O,N-bidentate ruthenium azo complexes as catalysts for olefin isomerization reactions},
  url          = {http://dx.doi.org/10.1002/ejic.200900926},
  year         = {2010},
}

Chicago
Ding, Fu, Yaguang Sun, and Francis Verpoort. 2010. “O,N-bidentate Ruthenium Azo Complexes as Catalysts for Olefin Isomerization Reactions.” European Journal of Inorganic Chemistry (10): 1536–1543.
APA
Ding, F., Sun, Y., & Verpoort, F. (2010). O,N-bidentate ruthenium azo complexes as catalysts for olefin isomerization reactions. EUROPEAN JOURNAL OF INORGANIC CHEMISTRY, (10), 1536–1543.
Vancouver
1.
Ding F, Sun Y, Verpoort F. O,N-bidentate ruthenium azo complexes as catalysts for olefin isomerization reactions. EUROPEAN JOURNAL OF INORGANIC CHEMISTRY. 2010;(10):1536–43.
MLA
Ding, Fu, Yaguang Sun, and Francis Verpoort. “O,N-bidentate Ruthenium Azo Complexes as Catalysts for Olefin Isomerization Reactions.” EUROPEAN JOURNAL OF INORGANIC CHEMISTRY 10 (2010): 1536–1543. Print.