Production of biobased HMF derivatives by reductive amination
- Author
- Ana Cukalovic (UGent) and Christian Stevens (UGent)
- Organization
- Abstract
- 5-(Hydroxymethyl)furfural (HMF) has recently attracted a significant amount of revived attention as a renewable building block for the conversion to a wide range of useful derivatives. A simple procedure for the conversion of HMF to (5-alkylaminomethyl-furan-2-yl)methanol has now been developed. Reactions were conducted without the use of a catalyst and under very mild conditions. As a proof of concept, a small library of derivatives was produced from HMF and several aliphatic and aromatic amines in high yields and requiring only minimal purification. This route presents a novel way for the production of furan-based renewable building blocks.
- Keywords
- IMINES, WATER, BIOMASS, LIQUIDS, GLUCOSE, SOLVENT, CONVERSION, DEHYDRATION, D-FRUCTOSE, ION-EXCHANGE-RESIN
Downloads
-
(...).pdf
- full text
- |
- UGent only
- |
- |
- 149.81 KB
Citation
Please use this url to cite or link to this publication: http://hdl.handle.net/1854/LU-921335
- MLA
- Cukalovic, Ana, and Christian Stevens. “Production of Biobased HMF Derivatives by Reductive Amination.” GREEN CHEMISTRY, vol. 12, no. 7, 2010, pp. 1201–06, doi:10.1039/c002340j.
- APA
- Cukalovic, A., & Stevens, C. (2010). Production of biobased HMF derivatives by reductive amination. GREEN CHEMISTRY, 12(7), 1201–1206. https://doi.org/10.1039/c002340j
- Chicago author-date
- Cukalovic, Ana, and Christian Stevens. 2010. “Production of Biobased HMF Derivatives by Reductive Amination.” GREEN CHEMISTRY 12 (7): 1201–6. https://doi.org/10.1039/c002340j.
- Chicago author-date (all authors)
- Cukalovic, Ana, and Christian Stevens. 2010. “Production of Biobased HMF Derivatives by Reductive Amination.” GREEN CHEMISTRY 12 (7): 1201–1206. doi:10.1039/c002340j.
- Vancouver
- 1.Cukalovic A, Stevens C. Production of biobased HMF derivatives by reductive amination. GREEN CHEMISTRY. 2010;12(7):1201–6.
- IEEE
- [1]A. Cukalovic and C. Stevens, “Production of biobased HMF derivatives by reductive amination,” GREEN CHEMISTRY, vol. 12, no. 7, pp. 1201–1206, 2010.
@article{921335, abstract = {{5-(Hydroxymethyl)furfural (HMF) has recently attracted a significant amount of revived attention as a renewable building block for the conversion to a wide range of useful derivatives. A simple procedure for the conversion of HMF to (5-alkylaminomethyl-furan-2-yl)methanol has now been developed. Reactions were conducted without the use of a catalyst and under very mild conditions. As a proof of concept, a small library of derivatives was produced from HMF and several aliphatic and aromatic amines in high yields and requiring only minimal purification. This route presents a novel way for the production of furan-based renewable building blocks.}}, author = {{Cukalovic, Ana and Stevens, Christian}}, issn = {{1463-9262}}, journal = {{GREEN CHEMISTRY}}, keywords = {{IMINES,WATER,BIOMASS,LIQUIDS,GLUCOSE,SOLVENT,CONVERSION,DEHYDRATION,D-FRUCTOSE,ION-EXCHANGE-RESIN}}, language = {{eng}}, number = {{7}}, pages = {{1201--1206}}, title = {{Production of biobased HMF derivatives by reductive amination}}, url = {{http://doi.org/10.1039/c002340j}}, volume = {{12}}, year = {{2010}}, }
- Altmetric
- View in Altmetric
- Web of Science
- Times cited: