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Production of biobased HMF derivatives by reductive amination

Ana Cukalovic (UGent) and Christian Stevens (UGent)
(2010) GREEN CHEMISTRY. 12(7). p.1201-1206
Author
Organization
Abstract
5-(Hydroxymethyl)furfural (HMF) has recently attracted a significant amount of revived attention as a renewable building block for the conversion to a wide range of useful derivatives. A simple procedure for the conversion of HMF to (5-alkylaminomethyl-furan-2-yl)methanol has now been developed. Reactions were conducted without the use of a catalyst and under very mild conditions. As a proof of concept, a small library of derivatives was produced from HMF and several aliphatic and aromatic amines in high yields and requiring only minimal purification. This route presents a novel way for the production of furan-based renewable building blocks.
Keywords
IMINES, WATER, BIOMASS, LIQUIDS, GLUCOSE, SOLVENT, CONVERSION, DEHYDRATION, D-FRUCTOSE, ION-EXCHANGE-RESIN

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Citation

Please use this url to cite or link to this publication:

MLA
Cukalovic, Ana, and Christian Stevens. “Production of Biobased HMF Derivatives by Reductive Amination.” GREEN CHEMISTRY, vol. 12, no. 7, 2010, pp. 1201–06, doi:10.1039/c002340j.
APA
Cukalovic, A., & Stevens, C. (2010). Production of biobased HMF derivatives by reductive amination. GREEN CHEMISTRY, 12(7), 1201–1206. https://doi.org/10.1039/c002340j
Chicago author-date
Cukalovic, Ana, and Christian Stevens. 2010. “Production of Biobased HMF Derivatives by Reductive Amination.” GREEN CHEMISTRY 12 (7): 1201–6. https://doi.org/10.1039/c002340j.
Chicago author-date (all authors)
Cukalovic, Ana, and Christian Stevens. 2010. “Production of Biobased HMF Derivatives by Reductive Amination.” GREEN CHEMISTRY 12 (7): 1201–1206. doi:10.1039/c002340j.
Vancouver
1.
Cukalovic A, Stevens C. Production of biobased HMF derivatives by reductive amination. GREEN CHEMISTRY. 2010;12(7):1201–6.
IEEE
[1]
A. Cukalovic and C. Stevens, “Production of biobased HMF derivatives by reductive amination,” GREEN CHEMISTRY, vol. 12, no. 7, pp. 1201–1206, 2010.
@article{921335,
  abstract     = {{5-(Hydroxymethyl)furfural (HMF) has recently attracted a significant amount of revived attention as a renewable building block for the conversion to a wide range of useful derivatives. A simple procedure for the conversion of HMF to (5-alkylaminomethyl-furan-2-yl)methanol has now been developed. Reactions were conducted without the use of a catalyst and under very mild conditions. As a proof of concept, a small library of derivatives was produced from HMF and several aliphatic and aromatic amines in high yields and requiring only minimal purification. This route presents a novel way for the production of furan-based renewable building blocks.}},
  author       = {{Cukalovic, Ana and Stevens, Christian}},
  issn         = {{1463-9262}},
  journal      = {{GREEN CHEMISTRY}},
  keywords     = {{IMINES,WATER,BIOMASS,LIQUIDS,GLUCOSE,SOLVENT,CONVERSION,DEHYDRATION,D-FRUCTOSE,ION-EXCHANGE-RESIN}},
  language     = {{eng}},
  number       = {{7}},
  pages        = {{1201--1206}},
  title        = {{Production of biobased HMF derivatives by reductive amination}},
  url          = {{http://doi.org/10.1039/c002340j}},
  volume       = {{12}},
  year         = {{2010}},
}

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