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Production of biobased HMF derivatives by reductive amination

Ana Cukalovic UGent and Chris Stevens UGent (2010) GREEN CHEMISTRY. 12(7). p.1201-1206
abstract
5-(Hydroxymethyl)furfural (HMF) has recently attracted a significant amount of revived attention as a renewable building block for the conversion to a wide range of useful derivatives. A simple procedure for the conversion of HMF to (5-alkylaminomethyl-furan-2-yl)methanol has now been developed. Reactions were conducted without the use of a catalyst and under very mild conditions. As a proof of concept, a small library of derivatives was produced from HMF and several aliphatic and aromatic amines in high yields and requiring only minimal purification. This route presents a novel way for the production of furan-based renewable building blocks.
Please use this url to cite or link to this publication:
author
organization
year
type
journalArticle (original)
publication status
published
subject
keyword
IMINES, WATER, BIOMASS, LIQUIDS, GLUCOSE, SOLVENT, CONVERSION, DEHYDRATION, D-FRUCTOSE, ION-EXCHANGE-RESIN
journal title
GREEN CHEMISTRY
Green Chem.
volume
12
issue
7
pages
1201 - 1206
Web of Science type
Article
Web of Science id
000279566300012
JCR category
CHEMISTRY, MULTIDISCIPLINARY
JCR impact factor
5.472 (2010)
JCR rank
19/142 (2010)
JCR quartile
1 (2010)
ISSN
1463-9262
DOI
10.1039/c002340j
language
English
UGent publication?
yes
classification
A1
copyright statement
I have transferred the copyright for this publication to the publisher
id
921335
handle
http://hdl.handle.net/1854/LU-921335
date created
2010-04-07 10:26:22
date last changed
2010-10-07 09:38:11
@article{921335,
  abstract     = {5-(Hydroxymethyl)furfural (HMF) has recently attracted a significant amount of revived attention as a renewable building block for the conversion to a wide range of useful derivatives. A simple procedure for the conversion of HMF to (5-alkylaminomethyl-furan-2-yl)methanol has now been developed. Reactions were conducted without the use of a catalyst and under very mild conditions. As a proof of concept, a small library of derivatives was produced from HMF and several aliphatic and aromatic amines in high yields and requiring only minimal purification. This route presents a novel way for the production of furan-based renewable building blocks.},
  author       = {Cukalovic, Ana and Stevens, Chris},
  issn         = {1463-9262},
  journal      = {GREEN CHEMISTRY},
  keyword      = {IMINES,WATER,BIOMASS,LIQUIDS,GLUCOSE,SOLVENT,CONVERSION,DEHYDRATION,D-FRUCTOSE,ION-EXCHANGE-RESIN},
  language     = {eng},
  number       = {7},
  pages        = {1201--1206},
  title        = {Production of biobased HMF derivatives by reductive amination},
  url          = {http://dx.doi.org/10.1039/c002340j},
  volume       = {12},
  year         = {2010},
}

Chicago
Cukalovic, Ana, and Chris Stevens. 2010. “Production of Biobased HMF Derivatives by Reductive Amination.” Green Chemistry 12 (7): 1201–1206.
APA
Cukalovic, A., & Stevens, C. (2010). Production of biobased HMF derivatives by reductive amination. GREEN CHEMISTRY, 12(7), 1201–1206.
Vancouver
1.
Cukalovic A, Stevens C. Production of biobased HMF derivatives by reductive amination. GREEN CHEMISTRY. 2010;12(7):1201–6.
MLA
Cukalovic, Ana, and Chris Stevens. “Production of Biobased HMF Derivatives by Reductive Amination.” GREEN CHEMISTRY 12.7 (2010): 1201–1206. Print.