Academic Bibliography

 Search 200 years of publications by Ghent University researchers.
Advanced search
3 files | 6.58 MB
Add to list
  1. Search results
  2. CO2 methanation with Ru@MIL-101 nanop...

CO2 methanation with Ru@MIL-101 nanoparticles fixated on silica nanofibrous veils as stand-alone structured catalytic carrier

Eva Loccufier (UGent) , Geert Watson (UGent) , Yingrui Zhao, Maria Meledina, Robbe Denis, Parviz Gohari Derakhshandeh (UGent) , Pascal Van Der Voort (UGent) , Karen Leus (UGent) , Damien P. Debecker, Klaartje De Buysser (UGent) , et al.
(2023) APPLIED CATALYSIS B-ENVIRONMENTAL. 320.
Author
Organization
Abstract
An important challenge in the valorization of CO2 and H2 into fuels is the development of a stable, reusable and easy to handle heterogeneous catalyst. Here, a silica nanofibrous membrane is investigated as carrier for Ru nanoparticles, themselves encapsulated inside the metal organic framework (MOF) Cr-MIL-101. The catalytic membrane is investigated for the Sabatier methanation reaction. The direct electrospinning of a tetraorthosilicate (TEOS) sol results in a highly thermal resistant silica nanofibrous structure (up to 1100 degrees C) with pores between the fibers in the mu m-range, allowing a high gas throughput with low pressure requirements. A straightforward dip-coating procedure of the carrier was used to obtain a Ru@MIL-101 functionalized silica nanofibrous veil, avoiding Ru clustering. The obtained catalytic membrane exhibited an apparent turnover frequency of 3257 h-1 at 250 degrees C. This system therefore paves the way towards structured reactors for efficient CO2 hydrogenation processes.
Keywords
Process Chemistry and Technology, General Environmental Science, Catalysis, Silica nanofibers, Metal -organic frameworks, Ruthenium nanoparticles, Heterogeneous catalysis, Structured catalyst, METAL-ORGANIC FRAMEWORKS, CARBON-DIOXIDE, RU/TIO2 CATALYSTS, SABATIER REACTION, COMPOSITE MEMBRANES, CERAMIC NANOFIBERS, MOF, FABRICATION, ADSORPTION, HYDROGENATION

Downloads

  • Download
    (...).pdf
    • full text (Published version)
    • |
    • UGent only
    • |
    • PDF
    • |
    • 5.26 MB
  • Download
    Van der Voort Pascal et al Manuscript with highlights (2) (1).pdf
    • full text (Accepted manuscript)
    • |
    • open access
    • |
    • PDF
    • |
    • 1.08 MB
  • Download
    Van der Voort Pascal et al Supporting Information.pdf
    • supplementary material
    • |
    • open access
    • |
    • PDF
    • |
    • 238.71 KB

Citation

Please use this url to cite or link to this publication:

MLA
Loccufier, Eva, et al. “CO2 Methanation with Ru@MIL-101 Nanoparticles Fixated on Silica Nanofibrous Veils as Stand-Alone Structured Catalytic Carrier.” APPLIED CATALYSIS B-ENVIRONMENTAL, vol. 320, 2023, doi:10.1016/j.apcatb.2022.121972.
APA
Loccufier, E., Watson, G., Zhao, Y., Meledina, M., Denis, R., Gohari Derakhshandeh, P., … De Clerck, K. (2023). CO2 methanation with Ru@MIL-101 nanoparticles fixated on silica nanofibrous veils as stand-alone structured catalytic carrier. APPLIED CATALYSIS B-ENVIRONMENTAL, 320. https://doi.org/10.1016/j.apcatb.2022.121972
Chicago author-date
Loccufier, Eva, Geert Watson, Yingrui Zhao, Maria Meledina, Robbe Denis, Parviz Gohari Derakhshandeh, Pascal Van Der Voort, et al. 2023. “CO2 Methanation with Ru@MIL-101 Nanoparticles Fixated on Silica Nanofibrous Veils as Stand-Alone Structured Catalytic Carrier.” APPLIED CATALYSIS B-ENVIRONMENTAL 320. https://doi.org/10.1016/j.apcatb.2022.121972.
Chicago author-date (all authors)
Loccufier, Eva, Geert Watson, Yingrui Zhao, Maria Meledina, Robbe Denis, Parviz Gohari Derakhshandeh, Pascal Van Der Voort, Karen Leus, Damien P. Debecker, Klaartje De Buysser, and Karen De Clerck. 2023. “CO2 Methanation with Ru@MIL-101 Nanoparticles Fixated on Silica Nanofibrous Veils as Stand-Alone Structured Catalytic Carrier.” APPLIED CATALYSIS B-ENVIRONMENTAL 320. doi:10.1016/j.apcatb.2022.121972.
Vancouver
1.
Loccufier E, Watson G, Zhao Y, Meledina M, Denis R, Gohari Derakhshandeh P, et al. CO2 methanation with Ru@MIL-101 nanoparticles fixated on silica nanofibrous veils as stand-alone structured catalytic carrier. APPLIED CATALYSIS B-ENVIRONMENTAL. 2023;320.
IEEE
[1]
E. Loccufier et al., “CO2 methanation with Ru@MIL-101 nanoparticles fixated on silica nanofibrous veils as stand-alone structured catalytic carrier,” APPLIED CATALYSIS B-ENVIRONMENTAL, vol. 320, 2023.
@article{8768522,
  abstract     = {{An important challenge in the valorization of CO2 and H2 into fuels is the development of a stable, reusable and easy to handle heterogeneous catalyst. Here, a silica nanofibrous membrane is investigated as carrier for Ru nanoparticles, themselves encapsulated inside the metal organic framework (MOF) Cr-MIL-101. The catalytic membrane is investigated for the Sabatier methanation reaction. The direct electrospinning of a tetraorthosilicate (TEOS) sol results in a highly thermal resistant silica nanofibrous structure (up to 1100 degrees C) with pores between the fibers in the mu m-range, allowing a high gas throughput with low pressure requirements. A straightforward dip-coating procedure of the carrier was used to obtain a Ru@MIL-101 functionalized silica nanofibrous veil, avoiding Ru clustering. The obtained catalytic membrane exhibited an apparent turnover frequency of 3257 h-1 at 250 degrees C. This system therefore paves the way towards structured reactors for efficient CO2 hydrogenation processes.}},
  articleno    = {{121972}},
  author       = {{Loccufier, Eva and Watson, Geert and Zhao, Yingrui and Meledina, Maria and Denis, Robbe and Gohari Derakhshandeh, Parviz and Van Der Voort, Pascal and Leus, Karen and Debecker, Damien P. and De Buysser, Klaartje and De Clerck, Karen}},
  issn         = {{0926-3373}},
  journal      = {{APPLIED CATALYSIS B-ENVIRONMENTAL}},
  keywords     = {{Process Chemistry and Technology,General Environmental Science,Catalysis,Silica nanofibers,Metal -organic frameworks,Ruthenium nanoparticles,Heterogeneous catalysis,Structured catalyst,METAL-ORGANIC FRAMEWORKS,CARBON-DIOXIDE,RU/TIO2 CATALYSTS,SABATIER REACTION,COMPOSITE MEMBRANES,CERAMIC NANOFIBERS,MOF,FABRICATION,ADSORPTION,HYDROGENATION}},
  language     = {{eng}},
  pages        = {{11}},
  title        = {{CO2 methanation with Ru@MIL-101 nanoparticles fixated on silica nanofibrous veils as stand-alone structured catalytic carrier}},
  url          = {{http://doi.org/10.1016/j.apcatb.2022.121972}},
  volume       = {{320}},
  year         = {{2023}},
}
Altmetric
View in Altmetric
Web of Science
Times cited: