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Influence of impurities on the front velocity of sputter deposited Al/CuO thermite multilayers

Dulmaa Altangerel (UGent) and Diederik Depla (UGent)
(2021) MATERIALS. 14(23).
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Abstract
CuO and Al thin films were successively deposited using direct current (reactive) magnetron sputter deposition. A multilayer of five bilayers was deposited on glass, which can be ignited by heating a Ti resistive thin film. The velocity of the reaction front which propagates along the multilayer was optically determined using a high-speed camera. During the deposition of the aluminum layers, air was intentionally leaked into the vacuum chamber to introduce impurities in the film. Depositions at different impurity/metal flux ratios were performed. The front velocity reaches a value of approximately 20 m/s at low flux ratios but drops to approximately 7 m/s at flux ratios between 0.6 and 1. The drop is rather abrupt as the front velocity stays constant above flux ratios larger than 1. This behavior is explained based on the hindrance of the oxygen transport from the oxidizer (CuO) to the fuel (Al).
Keywords
General Materials Science, thermite, multilayer, magnetron sputter deposition, impurities, THIN-FILMS, STICKING COEFFICIENT, FLAME PROPAGATION, GRAIN-GROWTH, CUO, CONDUCTIVITY, AL, PERFORMANCE, COMBUSTION, THICKNESS

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Citation

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MLA
Altangerel, Dulmaa, and Diederik Depla. “Influence of Impurities on the Front Velocity of Sputter Deposited Al/CuO Thermite Multilayers.” MATERIALS, vol. 14, no. 23, 2021, doi:10.3390/ma14237224.
APA
Altangerel, D., & Depla, D. (2021). Influence of impurities on the front velocity of sputter deposited Al/CuO thermite multilayers. MATERIALS, 14(23). https://doi.org/10.3390/ma14237224
Chicago author-date
Altangerel, Dulmaa, and Diederik Depla. 2021. “Influence of Impurities on the Front Velocity of Sputter Deposited Al/CuO Thermite Multilayers.” MATERIALS 14 (23). https://doi.org/10.3390/ma14237224.
Chicago author-date (all authors)
Altangerel, Dulmaa, and Diederik Depla. 2021. “Influence of Impurities on the Front Velocity of Sputter Deposited Al/CuO Thermite Multilayers.” MATERIALS 14 (23). doi:10.3390/ma14237224.
Vancouver
1.
Altangerel D, Depla D. Influence of impurities on the front velocity of sputter deposited Al/CuO thermite multilayers. MATERIALS. 2021;14(23).
IEEE
[1]
D. Altangerel and D. Depla, “Influence of impurities on the front velocity of sputter deposited Al/CuO thermite multilayers,” MATERIALS, vol. 14, no. 23, 2021.
@article{8730180,
  abstract     = {{CuO and Al thin films were successively deposited using direct current (reactive) magnetron sputter deposition. A multilayer of five bilayers was deposited on glass, which can be ignited by heating a Ti resistive thin film. The velocity of the reaction front which propagates along the multilayer was optically determined using a high-speed camera. During the deposition of the aluminum layers, air was intentionally leaked into the vacuum chamber to introduce impurities in the film. Depositions at different impurity/metal flux ratios were performed. The front velocity reaches a value of approximately 20 m/s at low flux ratios but drops to approximately 7 m/s at flux ratios between 0.6 and 1. The drop is rather abrupt as the front velocity stays constant above flux ratios larger than 1. This behavior is explained based on the hindrance of the oxygen transport from the oxidizer (CuO) to the fuel (Al).}},
  articleno    = {{7224}},
  author       = {{Altangerel, Dulmaa and Depla, Diederik}},
  issn         = {{1996-1944}},
  journal      = {{MATERIALS}},
  keywords     = {{General Materials Science,thermite,multilayer,magnetron sputter deposition,impurities,THIN-FILMS,STICKING COEFFICIENT,FLAME PROPAGATION,GRAIN-GROWTH,CUO,CONDUCTIVITY,AL,PERFORMANCE,COMBUSTION,THICKNESS}},
  language     = {{eng}},
  number       = {{23}},
  pages        = {{13}},
  title        = {{Influence of impurities on the front velocity of sputter deposited Al/CuO thermite multilayers}},
  url          = {{http://doi.org/10.3390/ma14237224}},
  volume       = {{14}},
  year         = {{2021}},
}

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