Academic Bibliography

 Search 200 years of publications by Ghent University researchers.
Advanced search
Add to list
  1. Search results
  2. Periodic mesoporous organosilica cont...

Periodic mesoporous organosilica containing bridges with N-sulfonic acid groups : a new catalyst for the efficient formylation of amines and alcohols

Mahdieh Haghighat (UGent) , Farhad Shirini and Mostafa Golshekan
(2020) SILICON. 12(9). p.2087-2098
Author
Organization
Abstract
In this study, periodic mesoporous organosilica containing bridges withN-sulfonic acid groups (SA-PMO), was easily prepared in two steps: (i) preparation of periodic mesoporous organosilica containing amine-bridges (AM-PMO) via co-condensation of bis[3-(trimethoxysilyl)propyl] amine and tetraethoxysilane and (ii) functionalization of AM-PMO with sulfonic acid. The formation and morphology of the reagent were confirmed by N(2)adsorption-desorption isotherms, pH measurement, X-ray diffraction (XRD), transmission electron microscopy (TEM) and Fourier transform infrared FT-IR analysis. After identification, the catalytic ability of this reagent was investigated in the formylation of amines and alcohols using formic acid. Eco-friendly protocol, excellent yields, short reaction times, reusability of the catalyst and easy and quick isolation of the products are the main advantages of the presented method.
Keywords
Electronic, Optical and Magnetic Materials, Periodic mesoporous organosilica (PMO), N-Sulfonic acid groups, Amine-bridged periodic mesoporous organosilica, Bis[3-(trimethoxysilyl)propyl]amine, Formylation, Amines, Alcohols

Citation

Please use this url to cite or link to this publication:

MLA
Haghighat, Mahdieh, et al. “Periodic Mesoporous Organosilica Containing Bridges with N-Sulfonic Acid Groups : A New Catalyst for the Efficient Formylation of Amines and Alcohols.” SILICON, vol. 12, no. 9, 2020, pp. 2087–98, doi:10.1007/s12633-019-00293-4.
APA
Haghighat, M., Shirini, F., & Golshekan, M. (2020). Periodic mesoporous organosilica containing bridges with N-sulfonic acid groups : a new catalyst for the efficient formylation of amines and alcohols. SILICON, 12(9), 2087–2098. https://doi.org/10.1007/s12633-019-00293-4
Chicago author-date
Haghighat, Mahdieh, Farhad Shirini, and Mostafa Golshekan. 2020. “Periodic Mesoporous Organosilica Containing Bridges with N-Sulfonic Acid Groups : A New Catalyst for the Efficient Formylation of Amines and Alcohols.” SILICON 12 (9): 2087–98. https://doi.org/10.1007/s12633-019-00293-4.
Chicago author-date (all authors)
Haghighat, Mahdieh, Farhad Shirini, and Mostafa Golshekan. 2020. “Periodic Mesoporous Organosilica Containing Bridges with N-Sulfonic Acid Groups : A New Catalyst for the Efficient Formylation of Amines and Alcohols.” SILICON 12 (9): 2087–2098. doi:10.1007/s12633-019-00293-4.
Vancouver
1.
Haghighat M, Shirini F, Golshekan M. Periodic mesoporous organosilica containing bridges with N-sulfonic acid groups : a new catalyst for the efficient formylation of amines and alcohols. SILICON. 2020;12(9):2087–98.
IEEE
[1]
M. Haghighat, F. Shirini, and M. Golshekan, “Periodic mesoporous organosilica containing bridges with N-sulfonic acid groups : a new catalyst for the efficient formylation of amines and alcohols,” SILICON, vol. 12, no. 9, pp. 2087–2098, 2020.
@article{8728018,
  abstract     = {{In this study, periodic mesoporous organosilica containing bridges withN-sulfonic acid groups (SA-PMO), was easily prepared in two steps: (i) preparation of periodic mesoporous organosilica containing amine-bridges (AM-PMO) via co-condensation of bis[3-(trimethoxysilyl)propyl] amine and tetraethoxysilane and (ii) functionalization of AM-PMO with sulfonic acid. The formation and morphology of the reagent were confirmed by N(2)adsorption-desorption isotherms, pH measurement, X-ray diffraction (XRD), transmission electron microscopy (TEM) and Fourier transform infrared FT-IR analysis. After identification, the catalytic ability of this reagent was investigated in the formylation of amines and alcohols using formic acid. Eco-friendly protocol, excellent yields, short reaction times, reusability of the catalyst and easy and quick isolation of the products are the main advantages of the presented method.}},
  author       = {{Haghighat, Mahdieh and Shirini, Farhad and Golshekan, Mostafa}},
  issn         = {{1876-990X}},
  journal      = {{SILICON}},
  keywords     = {{Electronic,Optical and Magnetic Materials,Periodic mesoporous organosilica (PMO),N-Sulfonic acid groups,Amine-bridged periodic mesoporous organosilica,Bis[3-(trimethoxysilyl)propyl]amine,Formylation,Amines,Alcohols}},
  language     = {{eng}},
  number       = {{9}},
  pages        = {{2087--2098}},
  title        = {{Periodic mesoporous organosilica containing bridges with N-sulfonic acid groups : a new catalyst for the efficient formylation of amines and alcohols}},
  url          = {{http://doi.org/10.1007/s12633-019-00293-4}},
  volume       = {{12}},
  year         = {{2020}},
}
Altmetric
View in Altmetric
Web of Science
Times cited: