Synthesis of nitrile-functionalized polydentate N-heterocycles as building blocks for covalent triazine frameworks
- Author
- Jonas Everaert (UGent) , Maarten Debruyne (UGent) , Flore Vanden Bussche, Kristof Van Hecke (UGent) , Thomas Heugebaert (UGent) , Pascal Van Der Voort (UGent) , Veronique Van Speybroeck (UGent) and Christian Stevens (UGent)
- Organization
- Project
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- Study of nucleation and crystal growth of pharmaceuticals by X-ray and harmonic light scattering
- Model based synthesis of Covalent Organic Frameworks (COFs) for heterogeneous catalysis in flow.
- Model based synthesis of Covalent Organic Frameworks (COFs) for heterogeneous catalysis in flow.
- Model based synthesis of Covalent Organic Frameworks (COFs) for heterogeneous catalysis in flow.
- Synthesis and evaluation of novel covalent triazine frameworks for heterogeneous catalysis in flow systems
- 3D Structureel Platform voor Chemische Excellentie .
- Abstract
- Covalent triazine frameworks (CTFs) based on polydentate ligands are highly promising supports to anchor catalytic metal complexes. The modular nature of CTFs allows to tailor the composition, structure, and function to its specific application. Access to a broad range of chelating building blocks is therefore essential. In this respect, we extended the current available set of CTF building blocks with new nitrile-functionalized N-heterocyclic ligands. This paper presents the synthesis of the six ligands which vary in the extent of the aromatic system and the denticity. The new building blocks may help in a rational design of enhanced support materials in catalysis.
- Keywords
- N-heterocycles, 1, 4-diazadiene ligands, 2, 2 '-bipyridine, 2, 2 '-biquinoline, 2, 6-bis(benzimidazolyl)pyridine, nitrile building blocks, covalent triazine frameworks, CATALYZED CYANATION, METAL-COMPLEXES, LIGAND, OXIDES, 2, 2'-BIPYRIDINE, BIPYRIDINE
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Citation
Please use this url to cite or link to this publication: http://hdl.handle.net/1854/LU-8724717
- MLA
- Everaert, Jonas, et al. “Synthesis of Nitrile-Functionalized Polydentate N-Heterocycles as Building Blocks for Covalent Triazine Frameworks.” SYNTHESIS-STUTTGART, vol. 53, 2021, p. A-H, doi:10.1055/a-1626-5749.
- APA
- Everaert, J., Debruyne, M., Vanden Bussche, F., Van Hecke, K., Heugebaert, T., Van Der Voort, P., … Stevens, C. (2021). Synthesis of nitrile-functionalized polydentate N-heterocycles as building blocks for covalent triazine frameworks. SYNTHESIS-STUTTGART, 53, A-H. https://doi.org/10.1055/a-1626-5749
- Chicago author-date
- Everaert, Jonas, Maarten Debruyne, Flore Vanden Bussche, Kristof Van Hecke, Thomas Heugebaert, Pascal Van Der Voort, Veronique Van Speybroeck, and Christian Stevens. 2021. “Synthesis of Nitrile-Functionalized Polydentate N-Heterocycles as Building Blocks for Covalent Triazine Frameworks.” SYNTHESIS-STUTTGART 53: A-H. https://doi.org/10.1055/a-1626-5749.
- Chicago author-date (all authors)
- Everaert, Jonas, Maarten Debruyne, Flore Vanden Bussche, Kristof Van Hecke, Thomas Heugebaert, Pascal Van Der Voort, Veronique Van Speybroeck, and Christian Stevens. 2021. “Synthesis of Nitrile-Functionalized Polydentate N-Heterocycles as Building Blocks for Covalent Triazine Frameworks.” SYNTHESIS-STUTTGART 53: A-H. doi:10.1055/a-1626-5749.
- Vancouver
- 1.Everaert J, Debruyne M, Vanden Bussche F, Van Hecke K, Heugebaert T, Van Der Voort P, et al. Synthesis of nitrile-functionalized polydentate N-heterocycles as building blocks for covalent triazine frameworks. SYNTHESIS-STUTTGART. 2021;53:A-H.
- IEEE
- [1]J. Everaert et al., “Synthesis of nitrile-functionalized polydentate N-heterocycles as building blocks for covalent triazine frameworks,” SYNTHESIS-STUTTGART, vol. 53, p. A-H, 2021.
@article{8724717,
abstract = {{Covalent triazine frameworks (CTFs) based on polydentate ligands are highly promising supports to anchor catalytic metal complexes. The modular nature of CTFs allows to tailor the composition, structure, and function to its specific application. Access to a broad range of chelating building blocks is therefore essential. In this respect, we extended the current available set of CTF building blocks with new nitrile-functionalized N-heterocyclic ligands. This paper presents the synthesis of the six ligands which vary in the extent of the aromatic system and the denticity. The new building blocks may help in a rational design of enhanced support materials in catalysis.}},
author = {{Everaert, Jonas and Debruyne, Maarten and Vanden Bussche, Flore and Van Hecke, Kristof and Heugebaert, Thomas and Van Der Voort, Pascal and Van Speybroeck, Veronique and Stevens, Christian}},
issn = {{0039-7881}},
journal = {{SYNTHESIS-STUTTGART}},
keywords = {{N-heterocycles,1,4-diazadiene ligands,2,2 '-bipyridine,2,2 '-biquinoline,2,6-bis(benzimidazolyl)pyridine,nitrile building blocks,covalent triazine frameworks,CATALYZED CYANATION,METAL-COMPLEXES,LIGAND,OXIDES,2,2'-BIPYRIDINE,BIPYRIDINE}},
language = {{eng}},
pages = {{A--H}},
title = {{Synthesis of nitrile-functionalized polydentate N-heterocycles as building blocks for covalent triazine frameworks}},
url = {{http://doi.org/10.1055/a-1626-5749}},
volume = {{53}},
year = {{2021}},
}
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