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Chemical sensors based on a Eu(iii)-centered periodic mesoporous organosilica hybrid material using picolinic acid as an efficient secondary ligand

(2021) DALTON TRANSACTIONS. 50(32). p.11061-11070
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Organization
Abstract
Through a series of post synthetic modification methods applied to the 100% trans ethenylene-bridged Periodic Mesoporous Organosilica (ePMO), the lanthanide-functionalized hybrid nanomaterial ePMO@Eu_PA (PA = picolinic acid) has been prepared. The pristine and lanthanide-grafted ePMO materials were characterized by powder X-ray diffraction, DRIFTs, TGA, N-2 sorption, SEM and TEM. The selected PA ligand could effectively sensitize the Eu3+ ion, leading to the characteristic luminescence of Eu3+ in ePMO@Eu_PA. The luminescence properties of the ePMO@Eu_PA were studied in detail in the solid state and after dispersing in water. The material was investigated for the use as ion sensor and showed a selective monitoring of Fe3+, Co-2(+) and Cu2+ ions with luminescence quenching. In addition, the material showed a linear relationship between the luminescence intensity and the pH value in the pH range from 7.7 to 10.2. These findings demonstrate that ePMO@Eu_PA possesses potential practical applications in ion sensing as well as in pH sensing.
Keywords
Inorganic Chemistry, METAL-ORGANIC FRAMEWORKS, LANTHANIDE COMPLEXES, FLUORESCENT SENSOR, FE3+ IONS, EU-MOF, LUMINESCENT, PH, CHEMOSENSOR, PLATFORM, WATER

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Citation

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MLA
Liu, Wanlu, et al. “Chemical Sensors Based on a Eu(Iii)-Centered Periodic Mesoporous Organosilica Hybrid Material Using Picolinic Acid as an Efficient Secondary Ligand.” DALTON TRANSACTIONS, vol. 50, no. 32, 2021, pp. 11061–70, doi:10.1039/d1dt01767e.
APA
Liu, W., Kaczmarek, A., Rijckaert, H., Van Der Voort, P., & Van Deun, R. (2021). Chemical sensors based on a Eu(iii)-centered periodic mesoporous organosilica hybrid material using picolinic acid as an efficient secondary ligand. DALTON TRANSACTIONS, 50(32), 11061–11070. https://doi.org/10.1039/d1dt01767e
Chicago author-date
Liu, Wanlu, Anna Kaczmarek, Hannes Rijckaert, Pascal Van Der Voort, and Rik Van Deun. 2021. “Chemical Sensors Based on a Eu(Iii)-Centered Periodic Mesoporous Organosilica Hybrid Material Using Picolinic Acid as an Efficient Secondary Ligand.” DALTON TRANSACTIONS 50 (32): 11061–70. https://doi.org/10.1039/d1dt01767e.
Chicago author-date (all authors)
Liu, Wanlu, Anna Kaczmarek, Hannes Rijckaert, Pascal Van Der Voort, and Rik Van Deun. 2021. “Chemical Sensors Based on a Eu(Iii)-Centered Periodic Mesoporous Organosilica Hybrid Material Using Picolinic Acid as an Efficient Secondary Ligand.” DALTON TRANSACTIONS 50 (32): 11061–11070. doi:10.1039/d1dt01767e.
Vancouver
1.
Liu W, Kaczmarek A, Rijckaert H, Van Der Voort P, Van Deun R. Chemical sensors based on a Eu(iii)-centered periodic mesoporous organosilica hybrid material using picolinic acid as an efficient secondary ligand. DALTON TRANSACTIONS. 2021;50(32):11061–70.
IEEE
[1]
W. Liu, A. Kaczmarek, H. Rijckaert, P. Van Der Voort, and R. Van Deun, “Chemical sensors based on a Eu(iii)-centered periodic mesoporous organosilica hybrid material using picolinic acid as an efficient secondary ligand,” DALTON TRANSACTIONS, vol. 50, no. 32, pp. 11061–11070, 2021.
@article{8716780,
  abstract     = {{Through a series of post synthetic modification methods applied to the 100% trans ethenylene-bridged Periodic Mesoporous Organosilica (ePMO), the lanthanide-functionalized hybrid nanomaterial ePMO@Eu_PA (PA = picolinic acid) has been prepared. The pristine and lanthanide-grafted ePMO materials were characterized by powder X-ray diffraction, DRIFTs, TGA, N-2 sorption, SEM and TEM. The selected PA ligand could effectively sensitize the Eu3+ ion, leading to the characteristic luminescence of Eu3+ in ePMO@Eu_PA. The luminescence properties of the ePMO@Eu_PA were studied in detail in the solid state and after dispersing in water. The material was investigated for the use as ion sensor and showed a selective monitoring of Fe3+, Co-2(+) and Cu2+ ions with luminescence quenching. In addition, the material showed a linear relationship between the luminescence intensity and the pH value in the pH range from 7.7 to 10.2. These findings demonstrate that ePMO@Eu_PA possesses potential practical applications in ion sensing as well as in pH sensing.}},
  author       = {{Liu, Wanlu and Kaczmarek, Anna and Rijckaert, Hannes and Van Der Voort, Pascal and Van Deun, Rik}},
  issn         = {{1477-9226}},
  journal      = {{DALTON TRANSACTIONS}},
  keywords     = {{Inorganic Chemistry,METAL-ORGANIC FRAMEWORKS,LANTHANIDE COMPLEXES,FLUORESCENT SENSOR,FE3+ IONS,EU-MOF,LUMINESCENT,PH,CHEMOSENSOR,PLATFORM,WATER}},
  language     = {{eng}},
  number       = {{32}},
  pages        = {{11061--11070}},
  title        = {{Chemical sensors based on a Eu(iii)-centered periodic mesoporous organosilica hybrid material using picolinic acid as an efficient secondary ligand}},
  url          = {{http://doi.org/10.1039/d1dt01767e}},
  volume       = {{50}},
  year         = {{2021}},
}

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