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A simple synthesis of [RuCl2(NHC)(p-cymene)] complexes and their use in olefin oxidation catalysis

Xinyuan Ma (UGent) , Sébastien Guillet (UGent) , Min Peng (UGent) , Kristof Van Hecke (UGent) and Steven Nolan (UGent)
(2021) DALTON TRANSACTIONS. 50(11). p.3959-3965
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Abstract
A simple and efficient synthetic route to [RuCl2(NHC)(p-cymene)] and [Ru(CO3)(NHC)(p-cymene)] complexes making use of a weak base, under aerobic conditions, is reported. This method enables access to a series of NHC-ruthenium compounds with moderate to good yields under mild conditions. The Ru pre-catalysts were successfully used in olefin oxidation catalysis at low catalyst loading and reach complete conversion in short times.
Keywords
OPENING METATHESIS POLYMERIZATION

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MLA
Ma, Xinyuan, et al. “A Simple Synthesis of [RuCl2(NHC)(p-Cymene)] Complexes and Their Use in Olefin Oxidation Catalysis.” DALTON TRANSACTIONS, vol. 50, no. 11, 2021, pp. 3959–65, doi:10.1039/d1dt00030f.
APA
Ma, X., Guillet, S., Peng, M., Van Hecke, K., & Nolan, S. (2021). A simple synthesis of [RuCl2(NHC)(p-cymene)] complexes and their use in olefin oxidation catalysis. DALTON TRANSACTIONS, 50(11), 3959–3965. https://doi.org/10.1039/d1dt00030f
Chicago author-date
Ma, Xinyuan, Sébastien Guillet, Min Peng, Kristof Van Hecke, and Steven Nolan. 2021. “A Simple Synthesis of [RuCl2(NHC)(p-Cymene)] Complexes and Their Use in Olefin Oxidation Catalysis.” DALTON TRANSACTIONS 50 (11): 3959–65. https://doi.org/10.1039/d1dt00030f.
Chicago author-date (all authors)
Ma, Xinyuan, Sébastien Guillet, Min Peng, Kristof Van Hecke, and Steven Nolan. 2021. “A Simple Synthesis of [RuCl2(NHC)(p-Cymene)] Complexes and Their Use in Olefin Oxidation Catalysis.” DALTON TRANSACTIONS 50 (11): 3959–3965. doi:10.1039/d1dt00030f.
Vancouver
1.
Ma X, Guillet S, Peng M, Van Hecke K, Nolan S. A simple synthesis of [RuCl2(NHC)(p-cymene)] complexes and their use in olefin oxidation catalysis. DALTON TRANSACTIONS. 2021;50(11):3959–65.
IEEE
[1]
X. Ma, S. Guillet, M. Peng, K. Van Hecke, and S. Nolan, “A simple synthesis of [RuCl2(NHC)(p-cymene)] complexes and their use in olefin oxidation catalysis,” DALTON TRANSACTIONS, vol. 50, no. 11, pp. 3959–3965, 2021.
@article{8708361,
  abstract     = {{A simple and efficient synthetic route to [RuCl2(NHC)(p-cymene)] and [Ru(CO3)(NHC)(p-cymene)] complexes making use of a weak base, under aerobic conditions, is reported. This method enables access to a series of NHC-ruthenium compounds with moderate to good yields under mild conditions. The Ru pre-catalysts were successfully used in olefin oxidation catalysis at low catalyst loading and reach complete conversion in short times.}},
  author       = {{Ma, Xinyuan and Guillet, Sébastien and Peng, Min and Van Hecke, Kristof and Nolan, Steven}},
  issn         = {{1477-9226}},
  journal      = {{DALTON TRANSACTIONS}},
  keywords     = {{OPENING METATHESIS POLYMERIZATION}},
  language     = {{eng}},
  number       = {{11}},
  pages        = {{3959--3965}},
  title        = {{A simple synthesis of [RuCl2(NHC)(p-cymene)] complexes and their use in olefin oxidation catalysis}},
  url          = {{http://dx.doi.org/10.1039/d1dt00030f}},
  volume       = {{50}},
  year         = {{2021}},
}

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