The solubilities of current purines, pyrimidines and their nucleosides in urea and sucrose solutions
- Author
- Jean Stockx, A. Van Aert and J. Clauwaert
- Organization
- Abstract
- The solubilities of the heterocyclic bases adenine, guanine, cytosine, uracil and the corresponding nucleosides adenosine, guanosine, cytidine and uridine were determined at room temperature in function of urea and sucrose concentration. Although urea exerts a solubilizing effect on adenine, guanine, cytosine, adenosine, guanosine, cytidine and uridine, strong individual differences in behavior emerge. Uracil shows a maximum in solubility around 12% urea. Sucrose solutions promote to a lesser extent the solubilities of adenine, cytosine, adenosine and guanosine; they show no effect on uracil solubility but depress that of the pyrimidine nucleosides. In urea solutions the influence of the ribosyl substituent shows up by enhanced solubility increments of the purine nucleosides and diminished ones for cytidine, uridine taking an intermediate position. In sucrose solutions the attachment of the ribosyl group to the bases results into a negative slope for the relation nucleocide solubility: base solubility ratio vs sucrose concentration for adenosine, cytidine and uridine.
- Keywords
- General Chemistry
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Citation
Please use this url to cite or link to this publication: http://hdl.handle.net/1854/LU-8693956
- MLA
- Stockx, Jean, et al. “The Solubilities of Current Purines, Pyrimidines and Their Nucleosides in Urea and Sucrose Solutions.” BULLETIN DES SOCIÉTÉS CHIMIQUES BELGES, vol. 75, no. 9–10, 1966, pp. 673–90, doi:10.1002/bscb.19660750911.
- APA
- Stockx, J., Van Aert, A., & Clauwaert, J. (1966). The solubilities of current purines, pyrimidines and their nucleosides in urea and sucrose solutions. BULLETIN DES SOCIÉTÉS CHIMIQUES BELGES, 75(9–10), 673–690. https://doi.org/10.1002/bscb.19660750911
- Chicago author-date
- Stockx, Jean, A. Van Aert, and J. Clauwaert. 1966. “The Solubilities of Current Purines, Pyrimidines and Their Nucleosides in Urea and Sucrose Solutions.” BULLETIN DES SOCIÉTÉS CHIMIQUES BELGES 75 (9–10): 673–90. https://doi.org/10.1002/bscb.19660750911.
- Chicago author-date (all authors)
- Stockx, Jean, A. Van Aert, and J. Clauwaert. 1966. “The Solubilities of Current Purines, Pyrimidines and Their Nucleosides in Urea and Sucrose Solutions.” BULLETIN DES SOCIÉTÉS CHIMIQUES BELGES 75 (9–10): 673–690. doi:10.1002/bscb.19660750911.
- Vancouver
- 1.Stockx J, Van Aert A, Clauwaert J. The solubilities of current purines, pyrimidines and their nucleosides in urea and sucrose solutions. BULLETIN DES SOCIÉTÉS CHIMIQUES BELGES. 1966;75(9–10):673–90.
- IEEE
- [1]J. Stockx, A. Van Aert, and J. Clauwaert, “The solubilities of current purines, pyrimidines and their nucleosides in urea and sucrose solutions,” BULLETIN DES SOCIÉTÉS CHIMIQUES BELGES, vol. 75, no. 9–10, pp. 673–690, 1966.
@article{8693956,
abstract = {{The solubilities of the heterocyclic bases adenine, guanine, cytosine, uracil and the corresponding nucleosides adenosine, guanosine, cytidine and uridine were determined at room temperature in function of urea and sucrose concentration. Although urea exerts a solubilizing effect on adenine, guanine, cytosine, adenosine, guanosine, cytidine and uridine, strong individual differences in behavior emerge.
Uracil shows a maximum in solubility around 12% urea.
Sucrose solutions promote to a lesser extent the solubilities of adenine, cytosine, adenosine and guanosine; they show no effect on uracil solubility but depress that of the pyrimidine nucleosides.
In urea solutions the influence of the ribosyl substituent shows up by enhanced solubility increments of the purine nucleosides and diminished ones for cytidine, uridine taking an intermediate position. In sucrose solutions the attachment of the ribosyl group to the bases results into a negative slope for the relation nucleocide solubility: base solubility ratio vs sucrose concentration for adenosine, cytidine and uridine.}},
author = {{Stockx, Jean and Van Aert, A. and Clauwaert, J.}},
issn = {{0037-9646}},
journal = {{BULLETIN DES SOCIÉTÉS CHIMIQUES BELGES}},
keywords = {{General Chemistry}},
language = {{eng}},
number = {{9-10}},
pages = {{673--690}},
title = {{The solubilities of current purines, pyrimidines and their nucleosides in urea and sucrose solutions}},
url = {{http://doi.org/10.1002/bscb.19660750911}},
volume = {{75}},
year = {{1966}},
}
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