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N-heterocyclic carbene complexes in C–H activation reactions

(2020) CHEMICAL REVIEWS. 120(4). p.1981-2048
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Abstract
In this contribution, we provide a comprehensive overview of C-H activation methods promoted by NHC-transition metal complexes, covering the literature since 2002 (the year of the first report on metal-NHC-catalyzed C-H activation) through June 2019, focusing on both NHC ligands and C-H activation methods. This review covers C-H activation reactions catalyzed by group 8 to 11 NHC-metal complexes. Through discussing the role of NHC ligands in promoting challenging C-H activation methods, the reader is provided with an overview of this important area and its crucial role in forging carbon carbon and carbon heteroatom bonds by directly engaging ubiquitous C-H bonds.
Keywords
General Chemistry, HYDROGEN-ISOTOPE-EXCHANGE, CATALYZED DIRECT ARYLATION, ENANTIOSELECTIVE ALLYLIC ALKYLATION, TRANSITION-METAL-COMPLEXES, PARA-SELECTIVE ALKYLATION, CROSS-COUPLING REACTIONS, KETONE ALPHA-ALKYLATION, CARBON-CARBON BONDS, PALLADIUM COMPLEXES, TERMINAL ALKYNES

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MLA
Zhao, Qun, et al. “N-Heterocyclic Carbene Complexes in C–H Activation Reactions.” CHEMICAL REVIEWS, vol. 120, no. 4, 2020, pp. 1981–2048, doi:10.1021/acs.chemrev.9b00634.
APA
Zhao, Q., Meng, G., Nolan, S., & Szostak, M. (2020). N-heterocyclic carbene complexes in C–H activation reactions. CHEMICAL REVIEWS, 120(4), 1981–2048. https://doi.org/10.1021/acs.chemrev.9b00634
Chicago author-date
Zhao, Qun, Guangrong Meng, Steven Nolan, and Michal Szostak. 2020. “N-Heterocyclic Carbene Complexes in C–H Activation Reactions.” CHEMICAL REVIEWS 120 (4): 1981–2048. https://doi.org/10.1021/acs.chemrev.9b00634.
Chicago author-date (all authors)
Zhao, Qun, Guangrong Meng, Steven Nolan, and Michal Szostak. 2020. “N-Heterocyclic Carbene Complexes in C–H Activation Reactions.” CHEMICAL REVIEWS 120 (4): 1981–2048. doi:10.1021/acs.chemrev.9b00634.
Vancouver
1.
Zhao Q, Meng G, Nolan S, Szostak M. N-heterocyclic carbene complexes in C–H activation reactions. CHEMICAL REVIEWS. 2020;120(4):1981–2048.
IEEE
[1]
Q. Zhao, G. Meng, S. Nolan, and M. Szostak, “N-heterocyclic carbene complexes in C–H activation reactions,” CHEMICAL REVIEWS, vol. 120, no. 4, pp. 1981–2048, 2020.
@article{8661462,
  abstract     = {In this contribution, we provide a comprehensive overview of C-H activation methods promoted by NHC-transition metal complexes, covering the literature since 2002 (the year of the first report on metal-NHC-catalyzed C-H activation) through June 2019, focusing on both NHC ligands and C-H activation methods. This review covers C-H activation reactions catalyzed by group 8 to 11 NHC-metal complexes. Through discussing the role of NHC ligands in promoting challenging C-H activation methods, the reader is provided with an overview of this important area and its crucial role in forging carbon carbon and carbon heteroatom bonds by directly engaging ubiquitous C-H bonds.},
  author       = {Zhao, Qun and Meng, Guangrong and Nolan, Steven and Szostak, Michal},
  issn         = {0009-2665},
  journal      = {CHEMICAL REVIEWS},
  keywords     = {General Chemistry,HYDROGEN-ISOTOPE-EXCHANGE,CATALYZED DIRECT ARYLATION,ENANTIOSELECTIVE ALLYLIC ALKYLATION,TRANSITION-METAL-COMPLEXES,PARA-SELECTIVE ALKYLATION,CROSS-COUPLING REACTIONS,KETONE ALPHA-ALKYLATION,CARBON-CARBON BONDS,PALLADIUM COMPLEXES,TERMINAL ALKYNES},
  language     = {eng},
  number       = {4},
  pages        = {1981--2048},
  title        = {N-heterocyclic carbene complexes in C–H activation reactions},
  url          = {http://dx.doi.org/10.1021/acs.chemrev.9b00634},
  volume       = {120},
  year         = {2020},
}

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