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Reductive elimination at carbon under steric control

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Abstract
It has been previously demonstrated that stable singlet electrophilic carbenes can behave as metal surrogates in the activation of strong E-H bonds (E = H, B, N, Si, P), but it was believed that these activations only proceed through an irreversible activation barrier. Herein we show that, as is the case with transition metals, the steric environment can be used to promote reductive elimination at carbon centers.
Keywords
Colloid and Surface Chemistry, Biochemistry, General Chemistry, Catalysis, CYCLIC (ALKYL)(AMINO)CARBENES CAACS, H ACTIVATION, B-H, CARBENES, AMMONIA, REACTIVITY, N, N'-DIAMIDOCARBENES, CHEMISTRY, HYDROGEN, BONDS

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Citation

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MLA
Tolentino, Daniel R., et al. “Reductive Elimination at Carbon under Steric Control.” JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, vol. 141, no. 25, 2019, pp. 9823–26.
APA
Tolentino, D. R., Neale, S., Isaac, C. J., Macgregor, S. A., Whittlesey, M. K., Jazzar, R., & Bertrand, G. (2019). Reductive elimination at carbon under steric control. JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 141(25), 9823–9826.
Chicago author-date
Tolentino, Daniel R., Samuel Neale, Connie J. Isaac, Stuart A. Macgregor, Michael K. Whittlesey, Rodolphe Jazzar, and Guy Bertrand. 2019. “Reductive Elimination at Carbon under Steric Control.” JOURNAL OF THE AMERICAN CHEMICAL SOCIETY 141 (25): 9823–26.
Chicago author-date (all authors)
Tolentino, Daniel R., Samuel Neale, Connie J. Isaac, Stuart A. Macgregor, Michael K. Whittlesey, Rodolphe Jazzar, and Guy Bertrand. 2019. “Reductive Elimination at Carbon under Steric Control.” JOURNAL OF THE AMERICAN CHEMICAL SOCIETY 141 (25): 9823–9826.
Vancouver
1.
Tolentino DR, Neale S, Isaac CJ, Macgregor SA, Whittlesey MK, Jazzar R, et al. Reductive elimination at carbon under steric control. JOURNAL OF THE AMERICAN CHEMICAL SOCIETY. 2019;141(25):9823–6.
IEEE
[1]
D. R. Tolentino et al., “Reductive elimination at carbon under steric control,” JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, vol. 141, no. 25, pp. 9823–9826, 2019.
@article{8661066,
  abstract     = {It has been previously demonstrated that stable singlet electrophilic carbenes can behave as metal surrogates in the activation of strong E-H bonds (E = H, B, N, Si, P), but it was believed that these activations only proceed through an irreversible activation barrier. Herein we show that, as is the case with transition metals, the steric environment can be used to promote reductive elimination at carbon centers.},
  author       = {Tolentino, Daniel R. and Neale, Samuel and Isaac, Connie J. and Macgregor, Stuart A. and Whittlesey, Michael K. and Jazzar, Rodolphe and Bertrand, Guy},
  issn         = {0002-7863},
  journal      = {JOURNAL OF THE AMERICAN CHEMICAL SOCIETY},
  keywords     = {Colloid and Surface Chemistry,Biochemistry,General Chemistry,Catalysis,CYCLIC (ALKYL)(AMINO)CARBENES CAACS,H ACTIVATION,B-H,CARBENES,AMMONIA,REACTIVITY,N,N'-DIAMIDOCARBENES,CHEMISTRY,HYDROGEN,BONDS},
  language     = {eng},
  number       = {25},
  pages        = {9823--9826},
  title        = {Reductive elimination at carbon under steric control},
  url          = {http://dx.doi.org/10.1021/jacs.9b04957},
  volume       = {141},
  year         = {2019},
}

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