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Polycaprolactone-based, porous CaCO3 and Ag nanoparticle modified scaffolds as a SERS platform with molecule-specific adsorption

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Abstract
Surface-enhanced Raman scattering (SERS) is a high-performance technique allowing detection of extremely low concentrations of analytes. For such applications, fibrous polymeric matrices decorated with plasmonic metal nanostructures can be used as flexible SERS substrates for analysis of analytes in many application. In this study, a three-dimensional SERS substrate consisting of a CaCO3-mineralized electrospun (ES) polycaprolactone (PCL) fibrous matrix decorated with silver (Ag) nanoparticles is developed. Such modification of the fibrous substrate allows achieving a significant increase of the SERS signal amplification. Functionalization of fibers by porous CaCO3 (vaterite) and Ag nanoparticles provides an effective approach of selective adsorption of biomolecules and their precise detection by SERS. This new SERS substrate represents a promising biosensor platform with selectivity to low and high molecular weight molecules.
Keywords
SERS, Raman, calcium carbonate, silver nanoparticles, vaterite

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MLA
Saveleva, Mariia, et al. “Polycaprolactone-Based, Porous CaCO3 and Ag Nanoparticle Modified Scaffolds as a SERS Platform with Molecule-Specific Adsorption.” FRONTIERS IN CHEMISTRY, vol. 7, 2020.
APA
Saveleva, M., Prikhozhdenko, E., Gorin, D., Skirtach, A., Yashchenok, A., & Parakhonskiy, B. (2020). Polycaprolactone-based, porous CaCO3 and Ag nanoparticle modified scaffolds as a SERS platform with molecule-specific adsorption. FRONTIERS IN CHEMISTRY, 7.
Chicago author-date
Saveleva, Mariia, Ekaterina Prikhozhdenko, Dmitry Gorin, Andre Skirtach, Alexey Yashchenok, and Bogdan Parakhonskiy. 2020. “Polycaprolactone-Based, Porous CaCO3 and Ag Nanoparticle Modified Scaffolds as a SERS Platform with Molecule-Specific Adsorption.” FRONTIERS IN CHEMISTRY 7.
Chicago author-date (all authors)
Saveleva, Mariia, Ekaterina Prikhozhdenko, Dmitry Gorin, Andre Skirtach, Alexey Yashchenok, and Bogdan Parakhonskiy. 2020. “Polycaprolactone-Based, Porous CaCO3 and Ag Nanoparticle Modified Scaffolds as a SERS Platform with Molecule-Specific Adsorption.” FRONTIERS IN CHEMISTRY 7.
Vancouver
1.
Saveleva M, Prikhozhdenko E, Gorin D, Skirtach A, Yashchenok A, Parakhonskiy B. Polycaprolactone-based, porous CaCO3 and Ag nanoparticle modified scaffolds as a SERS platform with molecule-specific adsorption. FRONTIERS IN CHEMISTRY. 2020;7.
IEEE
[1]
M. Saveleva, E. Prikhozhdenko, D. Gorin, A. Skirtach, A. Yashchenok, and B. Parakhonskiy, “Polycaprolactone-based, porous CaCO3 and Ag nanoparticle modified scaffolds as a SERS platform with molecule-specific adsorption,” FRONTIERS IN CHEMISTRY, vol. 7, 2020.
@article{8643721,
  abstract     = {Surface-enhanced Raman scattering (SERS) is a high-performance technique allowing detection of extremely low concentrations of analytes. For such applications, fibrous polymeric matrices decorated with plasmonic metal nanostructures can be used as flexible SERS substrates for analysis of analytes in many application. In this study, a three-dimensional SERS substrate consisting of a CaCO3-mineralized electrospun (ES) polycaprolactone (PCL) fibrous matrix decorated with silver (Ag) nanoparticles is developed. Such modification of the fibrous substrate allows achieving a significant increase of the SERS signal amplification. Functionalization of fibers by porous CaCO3 (vaterite) and Ag nanoparticles provides an effective approach of selective adsorption of biomolecules and their precise detection by SERS. This new SERS substrate represents a promising biosensor platform with selectivity to low and high molecular weight molecules.},
  articleno    = {888},
  author       = {Saveleva, Mariia and Prikhozhdenko, Ekaterina and Gorin, Dmitry and Skirtach, Andre and Yashchenok, Alexey and Parakhonskiy, Bogdan},
  issn         = {2296-2646},
  journal      = {FRONTIERS IN CHEMISTRY},
  keywords     = {SERS,Raman,calcium carbonate,silver nanoparticles,vaterite},
  language     = {eng},
  pages        = {11},
  title        = {Polycaprolactone-based, porous CaCO3 and Ag nanoparticle modified scaffolds as a SERS platform with molecule-specific adsorption},
  url          = {http://dx.doi.org/10.3389/fchem.2019.00888},
  volume       = {7},
  year         = {2020},
}

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