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Supramolecular competitive host-guest interaction induced reversible macromolecular metamorphosis

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Abstract
In this work, a rational strategy of competitive host-guest complexation between dioxynaphthalene (Naph) and tetrathiafulvalene (TTF) subunits as guests and cyclophane cyclobis(paraquat-p-phenylene) (CBPQT(4+)) module as host is exploited to modify the macromolecular architecture, so-called supramolecular metamorphosis, in aqueous media. The architectures of the polymers can be reversibly transformed from a linear diblock copolymer AB to a linear AC block copolymer or from a linear block copolymer to a comb copolymer by redox switching. Interestingly, as TTF- and Naph-based complexes feature different characteristic colors, it offers a great opportunity to directly observe nanoscaled macromolecular metamorphosis of materials with the naked eye.
Keywords
POLYMERS, HYDROGELS, TRANSFORMATION, host-guest complexation, supramolecular metamorphosis, thermoresponsive, properties

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MLA
Bera, Debaditya, et al. “Supramolecular Competitive Host-Guest Interaction Induced Reversible Macromolecular Metamorphosis.” MACROMOLECULAR RAPID COMMUNICATIONS, vol. 40, no. 22, 2019.
APA
Bera, D., Hou, Z., Glassner, M., Lyskawa, J., Malfait, A., Woisel, P., & Hoogenboom, R. (2019). Supramolecular competitive host-guest interaction induced reversible macromolecular metamorphosis. MACROMOLECULAR RAPID COMMUNICATIONS, 40(22).
Chicago author-date
Bera, Debaditya, Zhanyao Hou, Mathias Glassner, Joel Lyskawa, Aurelie Malfait, Patrice Woisel, and Richard Hoogenboom. 2019. “Supramolecular Competitive Host-Guest Interaction Induced Reversible Macromolecular Metamorphosis.” MACROMOLECULAR RAPID COMMUNICATIONS 40 (22).
Chicago author-date (all authors)
Bera, Debaditya, Zhanyao Hou, Mathias Glassner, Joel Lyskawa, Aurelie Malfait, Patrice Woisel, and Richard Hoogenboom. 2019. “Supramolecular Competitive Host-Guest Interaction Induced Reversible Macromolecular Metamorphosis.” MACROMOLECULAR RAPID COMMUNICATIONS 40 (22).
Vancouver
1.
Bera D, Hou Z, Glassner M, Lyskawa J, Malfait A, Woisel P, et al. Supramolecular competitive host-guest interaction induced reversible macromolecular metamorphosis. MACROMOLECULAR RAPID COMMUNICATIONS. 2019;40(22).
IEEE
[1]
D. Bera et al., “Supramolecular competitive host-guest interaction induced reversible macromolecular metamorphosis,” MACROMOLECULAR RAPID COMMUNICATIONS, vol. 40, no. 22, 2019.
@article{8638861,
  abstract     = {In this work, a rational strategy of competitive host-guest complexation between dioxynaphthalene (Naph) and tetrathiafulvalene (TTF) subunits as guests and cyclophane cyclobis(paraquat-p-phenylene) (CBPQT(4+)) module as host is exploited to modify the macromolecular architecture, so-called supramolecular metamorphosis, in aqueous media. The architectures of the polymers can be reversibly transformed from a linear diblock copolymer AB to a linear AC block copolymer or from a linear block copolymer to a comb copolymer by redox switching. Interestingly, as TTF- and Naph-based complexes feature different characteristic colors, it offers a great opportunity to directly observe nanoscaled macromolecular metamorphosis of materials with the naked eye.},
  articleno    = {1900376},
  author       = {Bera, Debaditya and Hou, Zhanyao and Glassner, Mathias and Lyskawa, Joel and Malfait, Aurelie and Woisel, Patrice and Hoogenboom, Richard},
  issn         = {1022-1336},
  journal      = {MACROMOLECULAR RAPID COMMUNICATIONS},
  keywords     = {POLYMERS,HYDROGELS,TRANSFORMATION,host-guest complexation,supramolecular metamorphosis,thermoresponsive,properties},
  language     = {eng},
  number       = {22},
  pages        = {6},
  title        = {Supramolecular competitive host-guest interaction induced reversible macromolecular metamorphosis},
  url          = {http://dx.doi.org/10.1002/marc.201900376},
  volume       = {40},
  year         = {2019},
}

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