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The influence of pre-electrospinning plasma treatment on physicochemical characteristics of PLA nanofibers

Fatemeh Rezaei (UGent) , Tom Planckaert (UGent) , Chris Vercruysse (UGent) , Jente Verjans (UGent) , Pascal Van Der Voort (UGent) , Heidi Declercq (UGent) , Richard Hoogenboom (UGent) , Rino Morent (UGent) and Nathalie De Geyter (UGent)
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Abstract
Morphology, crystallinity, thermal, and mechanical properties of nanofibrous mats are known to highly affect the behavior of these materials in desired applications. In this study, multiple characteristics of poly(lactic acid) (PLA) nanofibrous mats prepared from plasma-treated pre-electrospinning solutions are studied as a function of various plasma operational parameters. X-ray diffraction, differential scanning calorimetry, thermogravimetric analysis, X-ray photoelectron spectroscopy, scanning electron microscopy, and tensile tests are performed. In addition, the pristine and plasma-treated PLA solutions are examined with size exclusion chromatography to study the effect of the conducted pre-electrospinning plasma treatments (PEPT) on the molecular weight of PLA. Aging analysis of the pristine and plasma-treated solutions is also performed by evaluating the viscosity, conductivity, surface tension, and pH during an aging period of 10 days. To investigate if the results are only affected by the plasma treatment or also affected by the electrospinning, pristine and plasma-treated PLA cast layers are also analyzed. The results reveal that PEPT preserved the surface chemical composition of the nanofibers and the molecular weight distribution of PLA, while morphology and mechanical properties of the nanofibers are considerably enhanced. Moreover, plasma-treated polymer solutions resulted in the formation of nicely elongated nanofibers up to 4 days after plasma treatment.
Keywords
aging, cast layers, nanofiber characterization, PLA nanofibers, pre-electrospinning plasma treatment, MODIFICATION, MECHANICAL-PROPERTIES, POLYMER CONCENTRATION, CRYSTALLIZATION, CRYSTALLINITY, MORPHOLOGY, IMPROVE, NANOCOMPOSITES, BEHAVIOR, NYLON-6, aging, cast layers, nanofiber characterization, PLA nanofibers, pre-electrospinning plasma treatment

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MLA
Rezaei, Fatemeh, et al. “The Influence of Pre-Electrospinning Plasma Treatment on Physicochemical Characteristics of PLA Nanofibers.” MACROMOLECULAR MATERIALS AND ENGINEERING, vol. 304, no. 11, 2019.
APA
Rezaei, F., Planckaert, T., Vercruysse, C., Verjans, J., Van Der Voort, P., Declercq, H., … De Geyter, N. (2019). The influence of pre-electrospinning plasma treatment on physicochemical characteristics of PLA nanofibers. MACROMOLECULAR MATERIALS AND ENGINEERING, 304(11).
Chicago author-date
Rezaei, Fatemeh, Tom Planckaert, Chris Vercruysse, Jente Verjans, Pascal Van Der Voort, Heidi Declercq, Richard Hoogenboom, Rino Morent, and Nathalie De Geyter. 2019. “The Influence of Pre-Electrospinning Plasma Treatment on Physicochemical Characteristics of PLA Nanofibers.” MACROMOLECULAR MATERIALS AND ENGINEERING 304 (11).
Chicago author-date (all authors)
Rezaei, Fatemeh, Tom Planckaert, Chris Vercruysse, Jente Verjans, Pascal Van Der Voort, Heidi Declercq, Richard Hoogenboom, Rino Morent, and Nathalie De Geyter. 2019. “The Influence of Pre-Electrospinning Plasma Treatment on Physicochemical Characteristics of PLA Nanofibers.” MACROMOLECULAR MATERIALS AND ENGINEERING 304 (11).
Vancouver
1.
Rezaei F, Planckaert T, Vercruysse C, Verjans J, Van Der Voort P, Declercq H, et al. The influence of pre-electrospinning plasma treatment on physicochemical characteristics of PLA nanofibers. MACROMOLECULAR MATERIALS AND ENGINEERING. 2019;304(11).
IEEE
[1]
F. Rezaei et al., “The influence of pre-electrospinning plasma treatment on physicochemical characteristics of PLA nanofibers,” MACROMOLECULAR MATERIALS AND ENGINEERING, vol. 304, no. 11, 2019.
@article{8628543,
  abstract     = {Morphology, crystallinity, thermal, and mechanical properties of nanofibrous mats are known to highly affect the behavior of these materials in desired applications. In this study, multiple characteristics of poly(lactic acid) (PLA) nanofibrous mats prepared from plasma-treated pre-electrospinning solutions are studied as a function of various plasma operational parameters. X-ray diffraction, differential scanning calorimetry, thermogravimetric analysis, X-ray photoelectron spectroscopy, scanning electron microscopy, and tensile tests are performed. In addition, the pristine and plasma-treated PLA solutions are examined with size exclusion chromatography to study the effect of the conducted pre-electrospinning plasma treatments (PEPT) on the molecular weight of PLA. Aging analysis of the pristine and plasma-treated solutions is also performed by evaluating the viscosity, conductivity, surface tension, and pH during an aging period of 10 days. To investigate if the results are only affected by the plasma treatment or also affected by the electrospinning, pristine and plasma-treated PLA cast layers are also analyzed. The results reveal that PEPT preserved the surface chemical composition of the nanofibers and the molecular weight distribution of PLA, while morphology and mechanical properties of the nanofibers are considerably enhanced. Moreover, plasma-treated polymer solutions resulted in the formation of nicely elongated nanofibers up to 4 days after plasma treatment.},
  articleno    = {1900391},
  author       = {Rezaei, Fatemeh and Planckaert, Tom and Vercruysse, Chris and Verjans, Jente and Van Der Voort, Pascal and Declercq, Heidi and Hoogenboom, Richard and Morent, Rino and De Geyter, Nathalie},
  issn         = {1438-7492},
  journal      = {MACROMOLECULAR MATERIALS AND ENGINEERING},
  keywords     = {aging,cast layers,nanofiber characterization,PLA nanofibers,pre-electrospinning plasma treatment,MODIFICATION,MECHANICAL-PROPERTIES,POLYMER CONCENTRATION,CRYSTALLIZATION,CRYSTALLINITY,MORPHOLOGY,IMPROVE,NANOCOMPOSITES,BEHAVIOR,NYLON-6,aging,cast layers,nanofiber characterization,PLA nanofibers,pre-electrospinning plasma treatment},
  language     = {eng},
  number       = {11},
  pages        = {16},
  title        = {The influence of pre-electrospinning plasma treatment on physicochemical characteristics of PLA nanofibers},
  url          = {http://dx.doi.org/10.1002/mame.201900391},
  volume       = {304},
  year         = {2019},
}

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