Synthesis, X-ray characterization, and in vitro biological approach of dimeric and polymeric mercury(II) complexes with α-keto stabilized sulfur ylide
- Author
- Seyyed Javad Sabounchei, Mojdeh Sadat Hashemi, Roya Karamian, Seyed Hamed Moazzami Farida, Parviz Gohari Derakhshandeh (UGent) , Robert W Gable and Kristof Van Hecke (UGent)
- Organization
- Abstract
- Reaction of alpha-keto stabilized sulfur ylide (Me)(2)SCHC(O)C6H4-p-CN (Y) with HgX2 (X = Cl, Br, and I) led to the formation of new dinuclear products of the type [HgX2(Y)](2) (X = Cl (1), Br (2), and I (3)). Furthermore, the reaction of the corresponding sulfur ylide (Y) with Hg(NO3)(2)center dot H2O in equimolar ratio, using methanol as a solvent, was shown to produce the polynuclear complex [(Y)Hg(NO3)(2)](n) (4). The obtained compounds were characterized using elemental analysis, IR, H-1 and C-13 NMR techniques. The structures of compounds Y and 1 were characterized by single-crystal X-ray diffraction (XRD) analysis. Also, in order to confirm the crystalline nature of complexes 1-3, powder XRD pattern was used. Likewise, the antioxidant property of the complexes was examined by 1,1-diphenyl-2-picryl-hydrazyl (DPPH) free radical scavenging which revealed the strong-to-moderate radical scavenging ability (IC50; 0.163 +/- 0.004 to 0.936 +/- 0.012 mg center dot mL(-1)) of the synthesized compounds. Further, results from this study indicated that the compounds possess moderate antibacterial activity.
- Keywords
- PHOSPHORUS YLIDES, STRUCTURAL-CHARACTERIZATION, SULFONIUM YLIDES, PALLADIUM(II), ANTIOXIDANT, PLATINUM(II), SILVER(I), ARSONIUM, LIGANDS, DENSITY, Synthesis, sulfur ylide, Hg(II) complexes, single-crystal X-ray, diffraction, antioxidant, biological activity
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Citation
Please use this url to cite or link to this publication: http://hdl.handle.net/1854/LU-8621379
- MLA
- Sabounchei, Seyyed Javad et al. “Synthesis, X-ray Characterization, and in Vitro Biological Approach of Dimeric and Polymeric mercury(II) Complexes with Α-keto Stabilized Sulfur Ylide.” JOURNAL OF COORDINATION CHEMISTRY 71.20 (2018): 3277–3291. Print.
- APA
- Sabounchei, S. J., Hashemi, M. S., Karamian, R., Farida, S. H. M., Gohari Derakhshandeh, P., Gable, R. W., & Van Hecke, K. (2018). Synthesis, X-ray characterization, and in vitro biological approach of dimeric and polymeric mercury(II) complexes with α-keto stabilized sulfur ylide. JOURNAL OF COORDINATION CHEMISTRY, 71(20), 3277–3291.
- Chicago author-date
- Sabounchei, Seyyed Javad, Mojdeh Sadat Hashemi, Roya Karamian, Seyed Hamed Moazzami Farida, Parviz Gohari Derakhshandeh, Robert W Gable, and Kristof Van Hecke. 2018. “Synthesis, X-ray Characterization, and in Vitro Biological Approach of Dimeric and Polymeric mercury(II) Complexes with Α-keto Stabilized Sulfur Ylide.” Journal of Coordination Chemistry 71 (20): 3277–3291.
- Chicago author-date (all authors)
- Sabounchei, Seyyed Javad, Mojdeh Sadat Hashemi, Roya Karamian, Seyed Hamed Moazzami Farida, Parviz Gohari Derakhshandeh, Robert W Gable, and Kristof Van Hecke. 2018. “Synthesis, X-ray Characterization, and in Vitro Biological Approach of Dimeric and Polymeric mercury(II) Complexes with Α-keto Stabilized Sulfur Ylide.” Journal of Coordination Chemistry 71 (20): 3277–3291.
- Vancouver
- 1.Sabounchei SJ, Hashemi MS, Karamian R, Farida SHM, Gohari Derakhshandeh P, Gable RW, et al. Synthesis, X-ray characterization, and in vitro biological approach of dimeric and polymeric mercury(II) complexes with α-keto stabilized sulfur ylide. JOURNAL OF COORDINATION CHEMISTRY. 2018;71(20):3277–91.
- IEEE
- [1]S. J. Sabounchei et al., “Synthesis, X-ray characterization, and in vitro biological approach of dimeric and polymeric mercury(II) complexes with α-keto stabilized sulfur ylide,” JOURNAL OF COORDINATION CHEMISTRY, vol. 71, no. 20, pp. 3277–3291, 2018.
@article{8621379,
abstract = {Reaction of alpha-keto stabilized sulfur ylide (Me)(2)SCHC(O)C6H4-p-CN (Y) with HgX2 (X = Cl, Br, and I) led to the formation of new dinuclear products of the type [HgX2(Y)](2) (X = Cl (1), Br (2), and I (3)). Furthermore, the reaction of the corresponding sulfur ylide (Y) with Hg(NO3)(2)center dot H2O in equimolar ratio, using methanol as a solvent, was shown to produce the polynuclear complex [(Y)Hg(NO3)(2)](n) (4). The obtained compounds were characterized using elemental analysis, IR, H-1 and C-13 NMR techniques. The structures of compounds Y and 1 were characterized by single-crystal X-ray diffraction (XRD) analysis. Also, in order to confirm the crystalline nature of complexes 1-3, powder XRD pattern was used. Likewise, the antioxidant property of the complexes was examined by 1,1-diphenyl-2-picryl-hydrazyl (DPPH) free radical scavenging which revealed the strong-to-moderate radical scavenging ability (IC50; 0.163 +/- 0.004 to 0.936 +/- 0.012 mg center dot mL(-1)) of the synthesized compounds. Further, results from this study indicated that the compounds possess moderate antibacterial activity.},
author = {Sabounchei, Seyyed Javad and Hashemi, Mojdeh Sadat and Karamian, Roya and Farida, Seyed Hamed Moazzami and Gohari Derakhshandeh, Parviz and Gable, Robert W and Van Hecke, Kristof},
issn = {0095-8972},
journal = {JOURNAL OF COORDINATION CHEMISTRY},
keywords = {PHOSPHORUS YLIDES,STRUCTURAL-CHARACTERIZATION,SULFONIUM YLIDES,PALLADIUM(II),ANTIOXIDANT,PLATINUM(II),SILVER(I),ARSONIUM,LIGANDS,DENSITY,Synthesis,sulfur ylide,Hg(II) complexes,single-crystal X-ray,diffraction,antioxidant,biological activity},
language = {eng},
number = {20},
pages = {3277--3291},
title = {Synthesis, X-ray characterization, and in vitro biological approach of dimeric and polymeric mercury(II) complexes with α-keto stabilized sulfur ylide},
url = {http://dx.doi.org/10.1080/00958972.2018.1510493},
volume = {71},
year = {2018},
}
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