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3D derived N-doped carbon matrix from 2D ZIF-L as an enhanced stable catalyst for chemical fixation

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Abstract
3D metal N-doped carbon frameworks (M-NCFs) are produced from the direct pyrolysis of 2D zeolitic imidazolate frameworks (ZIF-L Zn and Co) in a reducing atmosphere. The effects of the thermal treatment were studied in order to achieve the desired catalyst. The results show that metal nanoparticles and N-doping species present in the carbon matrix have a direct influence on the catalytic performance. Zn/NCF-1000 displayed quantitative conversion and selectivity towards the chemical fixation of carbon dioxide through the cycloaddition with epoxides. Furthermore, the magnetic property of the newly synthesized Co/NCF-600 was used to demonstrate its superior stability and recyclability, retaining the same catalytic activity for more than 10 cycles.
Keywords
ZIF-L, Pyrolysis, CO2 fixation, Carbonates, Heterogeneous catalyst, METAL-ORGANIC FRAMEWORK, ZEOLITIC IMIDAZOLATE FRAMEWORK, EFFICIENT HETEROGENEOUS CATALYST, COVALENT TRIAZINE FRAMEWORKS, POROUS CARBON, CO2 CAPTURE, CYCLIC CARBONATES, DIOXIDE CAPTURE, IONIC LIQUID, CONVERSION

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MLA
Ciprian, Matteo, et al. “3D Derived N-Doped Carbon Matrix from 2D ZIF-L as an Enhanced Stable Catalyst for Chemical Fixation.” MICROPOROUS AND MESOPOROUS MATERIALS, vol. 285, 2019, pp. 80–88.
APA
Ciprian, M., Hernandez Ruiz, K., Kassymova, M., Wang, T., Zhuiykov, S., Chaemchuen, S., … Verpoort, F. (2019). 3D derived N-doped carbon matrix from 2D ZIF-L as an enhanced stable catalyst for chemical fixation. MICROPOROUS AND MESOPOROUS MATERIALS, 285, 80–88.
Chicago author-date
Ciprian, Matteo, Karla Hernandez Ruiz, Meruyert Kassymova, Tingting Wang, Serge Zhuiykov, Somboon Chaemchuen, Rong Tu, and Francis Verpoort. 2019. “3D Derived N-Doped Carbon Matrix from 2D ZIF-L as an Enhanced Stable Catalyst for Chemical Fixation.” MICROPOROUS AND MESOPOROUS MATERIALS 285: 80–88.
Chicago author-date (all authors)
Ciprian, Matteo, Karla Hernandez Ruiz, Meruyert Kassymova, Tingting Wang, Serge Zhuiykov, Somboon Chaemchuen, Rong Tu, and Francis Verpoort. 2019. “3D Derived N-Doped Carbon Matrix from 2D ZIF-L as an Enhanced Stable Catalyst for Chemical Fixation.” MICROPOROUS AND MESOPOROUS MATERIALS 285: 80–88.
Vancouver
1.
Ciprian M, Hernandez Ruiz K, Kassymova M, Wang T, Zhuiykov S, Chaemchuen S, et al. 3D derived N-doped carbon matrix from 2D ZIF-L as an enhanced stable catalyst for chemical fixation. MICROPOROUS AND MESOPOROUS MATERIALS. 2019;285:80–8.
IEEE
[1]
M. Ciprian et al., “3D derived N-doped carbon matrix from 2D ZIF-L as an enhanced stable catalyst for chemical fixation,” MICROPOROUS AND MESOPOROUS MATERIALS, vol. 285, pp. 80–88, 2019.
@article{8616968,
  abstract     = {3D metal N-doped carbon frameworks (M-NCFs) are produced from the direct pyrolysis of 2D zeolitic imidazolate frameworks (ZIF-L Zn and Co) in a reducing atmosphere. The effects of the thermal treatment were studied in order to achieve the desired catalyst. The results show that metal nanoparticles and N-doping species present in the carbon matrix have a direct influence on the catalytic performance. Zn/NCF-1000 displayed quantitative conversion and selectivity towards the chemical fixation of carbon dioxide through the cycloaddition with epoxides. Furthermore, the magnetic property of the newly synthesized Co/NCF-600 was used to demonstrate its superior stability and recyclability, retaining the same catalytic activity for more than 10 cycles.},
  author       = {Ciprian, Matteo and Hernandez Ruiz, Karla and Kassymova, Meruyert and Wang, Tingting and Zhuiykov, Serge and Chaemchuen, Somboon and Tu, Rong and Verpoort, Francis},
  issn         = {1387-1811},
  journal      = {MICROPOROUS AND MESOPOROUS MATERIALS},
  keywords     = {ZIF-L,Pyrolysis,CO2 fixation,Carbonates,Heterogeneous catalyst,METAL-ORGANIC FRAMEWORK,ZEOLITIC IMIDAZOLATE FRAMEWORK,EFFICIENT HETEROGENEOUS CATALYST,COVALENT TRIAZINE FRAMEWORKS,POROUS CARBON,CO2 CAPTURE,CYCLIC CARBONATES,DIOXIDE CAPTURE,IONIC LIQUID,CONVERSION},
  language     = {eng},
  pages        = {80--88},
  title        = {3D derived N-doped carbon matrix from 2D ZIF-L as an enhanced stable catalyst for chemical fixation},
  url          = {http://dx.doi.org/10.1016/j.micromeso.2019.04.053},
  volume       = {285},
  year         = {2019},
}

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