3D derived N-doped carbon matrix from 2D ZIF-L as an enhanced stable catalyst for chemical fixation
- Author
- Matteo Ciprian, Karla Hernandez Ruiz, Meruyert Kassymova, Tingting Wang, Serge Zhuiykov (UGent) , Somboon Chaemchuen, Rong Tu and Francis Verpoort (UGent)
- Organization
- Abstract
- 3D metal N-doped carbon frameworks (M-NCFs) are produced from the direct pyrolysis of 2D zeolitic imidazolate frameworks (ZIF-L Zn and Co) in a reducing atmosphere. The effects of the thermal treatment were studied in order to achieve the desired catalyst. The results show that metal nanoparticles and N-doping species present in the carbon matrix have a direct influence on the catalytic performance. Zn/NCF-1000 displayed quantitative conversion and selectivity towards the chemical fixation of carbon dioxide through the cycloaddition with epoxides. Furthermore, the magnetic property of the newly synthesized Co/NCF-600 was used to demonstrate its superior stability and recyclability, retaining the same catalytic activity for more than 10 cycles.
- Keywords
- ZIF-L, Pyrolysis, CO2 fixation, Carbonates, Heterogeneous catalyst, METAL-ORGANIC FRAMEWORK, ZEOLITIC IMIDAZOLATE FRAMEWORK, EFFICIENT HETEROGENEOUS CATALYST, COVALENT TRIAZINE FRAMEWORKS, POROUS CARBON, CO2 CAPTURE, CYCLIC CARBONATES, DIOXIDE CAPTURE, IONIC LIQUID, CONVERSION
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Citation
Please use this url to cite or link to this publication: http://hdl.handle.net/1854/LU-8616968
- MLA
- Ciprian, Matteo, et al. “3D Derived N-Doped Carbon Matrix from 2D ZIF-L as an Enhanced Stable Catalyst for Chemical Fixation.” MICROPOROUS AND MESOPOROUS MATERIALS, vol. 285, 2019, pp. 80–88, doi:10.1016/j.micromeso.2019.04.053.
- APA
- Ciprian, M., Hernandez Ruiz, K., Kassymova, M., Wang, T., Zhuiykov, S., Chaemchuen, S., … Verpoort, F. (2019). 3D derived N-doped carbon matrix from 2D ZIF-L as an enhanced stable catalyst for chemical fixation. MICROPOROUS AND MESOPOROUS MATERIALS, 285, 80–88. https://doi.org/10.1016/j.micromeso.2019.04.053
- Chicago author-date
- Ciprian, Matteo, Karla Hernandez Ruiz, Meruyert Kassymova, Tingting Wang, Serge Zhuiykov, Somboon Chaemchuen, Rong Tu, and Francis Verpoort. 2019. “3D Derived N-Doped Carbon Matrix from 2D ZIF-L as an Enhanced Stable Catalyst for Chemical Fixation.” MICROPOROUS AND MESOPOROUS MATERIALS 285: 80–88. https://doi.org/10.1016/j.micromeso.2019.04.053.
- Chicago author-date (all authors)
- Ciprian, Matteo, Karla Hernandez Ruiz, Meruyert Kassymova, Tingting Wang, Serge Zhuiykov, Somboon Chaemchuen, Rong Tu, and Francis Verpoort. 2019. “3D Derived N-Doped Carbon Matrix from 2D ZIF-L as an Enhanced Stable Catalyst for Chemical Fixation.” MICROPOROUS AND MESOPOROUS MATERIALS 285: 80–88. doi:10.1016/j.micromeso.2019.04.053.
- Vancouver
- 1.Ciprian M, Hernandez Ruiz K, Kassymova M, Wang T, Zhuiykov S, Chaemchuen S, et al. 3D derived N-doped carbon matrix from 2D ZIF-L as an enhanced stable catalyst for chemical fixation. MICROPOROUS AND MESOPOROUS MATERIALS. 2019;285:80–8.
- IEEE
- [1]M. Ciprian et al., “3D derived N-doped carbon matrix from 2D ZIF-L as an enhanced stable catalyst for chemical fixation,” MICROPOROUS AND MESOPOROUS MATERIALS, vol. 285, pp. 80–88, 2019.
@article{8616968,
abstract = {{3D metal N-doped carbon frameworks (M-NCFs) are produced from the direct pyrolysis of 2D zeolitic imidazolate frameworks (ZIF-L Zn and Co) in a reducing atmosphere. The effects of the thermal treatment were studied in order to achieve the desired catalyst. The results show that metal nanoparticles and N-doping species present in the carbon matrix have a direct influence on the catalytic performance. Zn/NCF-1000 displayed quantitative conversion and selectivity towards the chemical fixation of carbon dioxide through the cycloaddition with epoxides. Furthermore, the magnetic property of the newly synthesized Co/NCF-600 was used to demonstrate its superior stability and recyclability, retaining the same catalytic activity for more than 10 cycles.}},
author = {{Ciprian, Matteo and Hernandez Ruiz, Karla and Kassymova, Meruyert and Wang, Tingting and Zhuiykov, Serge and Chaemchuen, Somboon and Tu, Rong and Verpoort, Francis}},
issn = {{1387-1811}},
journal = {{MICROPOROUS AND MESOPOROUS MATERIALS}},
keywords = {{ZIF-L,Pyrolysis,CO2 fixation,Carbonates,Heterogeneous catalyst,METAL-ORGANIC FRAMEWORK,ZEOLITIC IMIDAZOLATE FRAMEWORK,EFFICIENT HETEROGENEOUS CATALYST,COVALENT TRIAZINE FRAMEWORKS,POROUS CARBON,CO2 CAPTURE,CYCLIC CARBONATES,DIOXIDE CAPTURE,IONIC LIQUID,CONVERSION}},
language = {{eng}},
pages = {{80--88}},
title = {{3D derived N-doped carbon matrix from 2D ZIF-L as an enhanced stable catalyst for chemical fixation}},
url = {{http://doi.org/10.1016/j.micromeso.2019.04.053}},
volume = {{285}},
year = {{2019}},
}
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