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Electrospinning preparation of Pd@Co3O4-ZnO composite nanofibers and their highly enhanced VOC sensing properties

(2019) MATERIALS RESEARCH BULLETIN. 109. p.255-264
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Abstract
In this paper, pure ZnO, Co3O4-ZnO, Pd@ZnO and Pd@Co3O4-ZnO composite nanofibers were synthesized by electrospinning method. Multiple characterizations were employed to investigate the crystal structure, composition, morphology, and bonding states of the Pd@Co3O4-ZnO composite nanofibers. The sensing properties of the as -synthesized nanofibers were evaluated toward different volatile organic components (VOCs) including ethanol, acetone, isopropanol and formaldehyde under the various operating temperatures. The obtained results have clearly demonstrated that the Pd@Co3O4-ZnO composite nanofibers exhibits significantly enhanced VOC sensing performance compared with other nanofibers. Specifically, the response of Pd@Co3O4-ZnO composite nanofibers toward 200 ppm ethanol is 59 at 240 degrees C, which is much higher than that of ZnO nanofibers. The enhanced VOC sensing properties of Pd@Co3O4-ZnO composite nanofibers could be attributed to the electronic and chemical sensitizations of Pd and the p-n junction formation at the interface of Co3O4 and ZnO.
Keywords
Electrospinning, Gas sensor, Nanofiber, Pcl@Co3O4-ZnO, Ethanol, GAS SENSOR, DOPED ZNO, PD, NANOPARTICLES, PERFORMANCE, ARRAYS, MICROSTRUCTURES, NANOSTRUCTURES, MICROSPHERES, SENSITIVITY

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MLA
Sun, Yongjiao, et al. “Electrospinning Preparation of Pd@Co3O4-ZnO Composite Nanofibers and Their Highly Enhanced VOC Sensing Properties.” MATERIALS RESEARCH BULLETIN, vol. 109, 2019, pp. 255–64, doi:10.1016/j.materresbull.2018.10.001.
APA
Sun, Y., Wang, Z., Wang, W., Li, G., Li, P., Lian, K., … Chen, L. (2019). Electrospinning preparation of Pd@Co3O4-ZnO composite nanofibers and their highly enhanced VOC sensing properties. MATERIALS RESEARCH BULLETIN, 109, 255–264. https://doi.org/10.1016/j.materresbull.2018.10.001
Chicago author-date
Sun, Yongjiao, Zepeng Wang, Wenda Wang, Gang Li, Pengwei Li, Kun Lian, Wendong Zhang, Serge Zhuiykov, Jie Hu, and Lin Chen. 2019. “Electrospinning Preparation of Pd@Co3O4-ZnO Composite Nanofibers and Their Highly Enhanced VOC Sensing Properties.” MATERIALS RESEARCH BULLETIN 109: 255–64. https://doi.org/10.1016/j.materresbull.2018.10.001.
Chicago author-date (all authors)
Sun, Yongjiao, Zepeng Wang, Wenda Wang, Gang Li, Pengwei Li, Kun Lian, Wendong Zhang, Serge Zhuiykov, Jie Hu, and Lin Chen. 2019. “Electrospinning Preparation of Pd@Co3O4-ZnO Composite Nanofibers and Their Highly Enhanced VOC Sensing Properties.” MATERIALS RESEARCH BULLETIN 109: 255–264. doi:10.1016/j.materresbull.2018.10.001.
Vancouver
1.
Sun Y, Wang Z, Wang W, Li G, Li P, Lian K, et al. Electrospinning preparation of Pd@Co3O4-ZnO composite nanofibers and their highly enhanced VOC sensing properties. MATERIALS RESEARCH BULLETIN. 2019;109:255–64.
IEEE
[1]
Y. Sun et al., “Electrospinning preparation of Pd@Co3O4-ZnO composite nanofibers and their highly enhanced VOC sensing properties,” MATERIALS RESEARCH BULLETIN, vol. 109, pp. 255–264, 2019.
@article{8604799,
  abstract     = {{In this paper, pure ZnO, Co3O4-ZnO, Pd@ZnO and Pd@Co3O4-ZnO composite nanofibers were synthesized by electrospinning method. Multiple characterizations were employed to investigate the crystal structure, composition, morphology, and bonding states of the Pd@Co3O4-ZnO composite nanofibers. The sensing properties of the as -synthesized nanofibers were evaluated toward different volatile organic components (VOCs) including ethanol, acetone, isopropanol and formaldehyde under the various operating temperatures. The obtained results have clearly demonstrated that the Pd@Co3O4-ZnO composite nanofibers exhibits significantly enhanced VOC sensing performance compared with other nanofibers. Specifically, the response of Pd@Co3O4-ZnO composite nanofibers toward 200 ppm ethanol is 59 at 240 degrees C, which is much higher than that of ZnO nanofibers. The enhanced VOC sensing properties of Pd@Co3O4-ZnO composite nanofibers could be attributed to the electronic and chemical sensitizations of Pd and the p-n junction formation at the interface of Co3O4 and ZnO.}},
  author       = {{Sun, Yongjiao and Wang, Zepeng and Wang, Wenda and Li, Gang and Li, Pengwei and Lian, Kun and Zhang, Wendong and Zhuiykov, Serge and Hu, Jie and Chen, Lin}},
  issn         = {{0025-5408}},
  journal      = {{MATERIALS RESEARCH BULLETIN}},
  keywords     = {{Electrospinning,Gas sensor,Nanofiber,Pcl@Co3O4-ZnO,Ethanol,GAS SENSOR,DOPED ZNO,PD,NANOPARTICLES,PERFORMANCE,ARRAYS,MICROSTRUCTURES,NANOSTRUCTURES,MICROSPHERES,SENSITIVITY}},
  language     = {{eng}},
  pages        = {{255--264}},
  title        = {{Electrospinning preparation of Pd@Co3O4-ZnO composite nanofibers and their highly enhanced VOC sensing properties}},
  url          = {{http://doi.org/10.1016/j.materresbull.2018.10.001}},
  volume       = {{109}},
  year         = {{2019}},
}

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