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An intramolecular cycloaddition approach to the kauranoid family of diterpene metabolites

Brenda Callebaut (UGent) , Jan Hullaert (UGent) , Kristof Van Hecke (UGent) and Johan Winne (UGent)
(2019) ORGANIC LETTERS. 21(1). p.310-314
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Organization
Abstract
Synthetic studies toward the ent-kauranoid family of diterpene natural products are reported. An intramolecular (4 + 3) cycloaddition allows the direct elaboration of diverse natural product frameworks, encompassing a challenging bicyclo[3.2.1]octane core. The established routes comprise only a few synthetic operations (3-5 steps), transforming a range of simple starting materials into the tetracyclic scaffolds that are commonly found in many ent-kaurene metabolites.
Keywords
GIBBERELLINS, ROUTE

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Chicago
Callebaut, Brenda, Jan Hullaert, Kristof Van Hecke, and Johan Winne. 2019. “An Intramolecular Cycloaddition Approach to the Kauranoid Family of Diterpene Metabolites.” Organic Letters 21 (1): 310–314.
APA
Callebaut, B., Hullaert, J., Van Hecke, K., & Winne, J. (2019). An intramolecular cycloaddition approach to the kauranoid family of diterpene metabolites. ORGANIC LETTERS, 21(1), 310–314.
Vancouver
1.
Callebaut B, Hullaert J, Van Hecke K, Winne J. An intramolecular cycloaddition approach to the kauranoid family of diterpene metabolites. ORGANIC LETTERS. 2019;21(1):310–4.
MLA
Callebaut, Brenda et al. “An Intramolecular Cycloaddition Approach to the Kauranoid Family of Diterpene Metabolites.” ORGANIC LETTERS 21.1 (2019): 310–314. Print.
@article{8586631,
  abstract     = {Synthetic studies toward the ent-kauranoid family of diterpene natural products are reported. An intramolecular (4 + 3) cycloaddition allows the direct elaboration of diverse natural product frameworks, encompassing a challenging bicyclo[3.2.1]octane core. The established routes comprise only a few synthetic operations (3-5 steps), transforming a range of simple starting materials into the tetracyclic scaffolds that are commonly found in many ent-kaurene metabolites.},
  author       = {Callebaut, Brenda and Hullaert, Jan and Van Hecke, Kristof and Winne, Johan},
  issn         = {1523-7060},
  journal      = {ORGANIC LETTERS},
  language     = {eng},
  number       = {1},
  pages        = {310--314},
  title        = {An intramolecular cycloaddition approach to the kauranoid family of diterpene metabolites},
  url          = {http://dx.doi.org/10.1021/acs.orglett.8b03810},
  volume       = {21},
  year         = {2019},
}

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