Advanced search
1 file | 3.71 MB

Coinage metal complexes of selenoureas derived from N-heterocyclic carbenes

(2018) DALTON TRANSACTIONS. 47(31). p.10671-10684
Author
Organization
Abstract
We describe the synthesis and characterisation of a series of new copper and silver complexes with selenourea ligands derived from common and readily-prepared N-heterocyclic carbenes (NHCs). The copper complexes behave somewhat predictably, typically leading to [CuCl(L)] complexes (with two exceptions). The silver complexes display a diverse range of structural motifs, including [AgCl(-L)](2), [AgCl(L)(2)], [Ag(L)(2)](+), [Ag(L)(3)](+), and [(Ag(L)(2))(2)(-L)](2+) species. All new complexes are characterised by multinuclear NMR spectroscopy, and several examples are characterised by X-ray crystallography. This study demonstrates the diversity of coordination behaviour that these selenourea ligands can engage in.
Keywords
NMR-SPECTROSCOPY, STERIC PROPERTIES, I COMPLEXES, LIGANDS, SELENIUM, COORDINATION, CHEMISTRY, SELONE, THIONE, COPPER

Downloads

  • (...).pdf
    • full text
    • |
    • UGent only
    • |
    • PDF
    • |
    • 3.71 MB

Citation

Please use this url to cite or link to this publication:

Chicago
Nahra, Fady, Kristof Van Hecke, Alan R Kennedy, and David J Nelson. 2018. “Coinage Metal Complexes of Selenoureas Derived from N-heterocyclic Carbenes.” Dalton Transactions 47 (31): 10671–10684.
APA
Nahra, F., Van Hecke, K., Kennedy, A. R., & Nelson, D. J. (2018). Coinage metal complexes of selenoureas derived from N-heterocyclic carbenes. DALTON TRANSACTIONS, 47(31), 10671–10684.
Vancouver
1.
Nahra F, Van Hecke K, Kennedy AR, Nelson DJ. Coinage metal complexes of selenoureas derived from N-heterocyclic carbenes. DALTON TRANSACTIONS. 2018;47(31):10671–84.
MLA
Nahra, Fady et al. “Coinage Metal Complexes of Selenoureas Derived from N-heterocyclic Carbenes.” DALTON TRANSACTIONS 47.31 (2018): 10671–10684. Print.
@article{8581221,
  abstract     = {We describe the synthesis and characterisation of a series of new copper and silver complexes with selenourea ligands derived from common and readily-prepared N-heterocyclic carbenes (NHCs). The copper complexes behave somewhat predictably, typically leading to [CuCl(L)] complexes (with two exceptions). The silver complexes display a diverse range of structural motifs, including [AgCl(-L)](2), [AgCl(L)(2)], [Ag(L)(2)](+), [Ag(L)(3)](+), and [(Ag(L)(2))(2)(-L)](2+) species. All new complexes are characterised by multinuclear NMR spectroscopy, and several examples are characterised by X-ray crystallography. This study demonstrates the diversity of coordination behaviour that these selenourea ligands can engage in.},
  author       = {Nahra, Fady and Van Hecke, Kristof and Kennedy, Alan R and Nelson, David J},
  issn         = {1477-9226},
  journal      = {DALTON TRANSACTIONS},
  language     = {eng},
  number       = {31},
  pages        = {10671--10684},
  title        = {Coinage metal complexes of selenoureas derived from N-heterocyclic carbenes},
  url          = {http://dx.doi.org/10.1039/c8dt01506f},
  volume       = {47},
  year         = {2018},
}

Altmetric
View in Altmetric
Web of Science
Times cited: