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Fast synthesis of CdS/CdS host-shell quantum dots

Min Zeng, Shalini Singh (UGent) , Zeger Hens (UGent) and Rik Van Deun (UGent)
Author
Organization
Abstract
The downconverting photoluminescence with heterogeneous core/shell nanocrystals has been largely investigated. While the homogeneous core/shell quantum dots have seldom been reported. For the small CdS (~2.2 nm) reference quantum dot, it exhibits serious trap emission. In most cases, wider-gap heterogeneous shells of ZnS1or ZnSe2 by slowly hot-injection method are employed to improve the surface passivation and thus improving its photoluminescence performance. The step by step hot-injection method is time-consuming. While the homogeneous CdS shell with fast and controllable epitaxial growth has never been reported. Herein, we demonstrate a flash fabrication method to synthesize the host-shell CdS capped CdS (CdS/CdS). The shell with different layers can be controlled by the amount of precursors added initially. The fluorescence results of the as synthesized host-shell CdS quantum dots, show that the growth of the CdS shell can efficiently remove the surface trap states, leading to high photoluminescence performance. Furthermore, this special core-host shell structure is used to increase the size of CdS, and to adjust the dopant positions inside nanocrystals.3 The fast synthetic procedure and the special host-shell structure present great potentials in preparing large-scale productions of core/shell quantum dots and site-dependent ions doped nanocrystals to avoid lattice mismatch caused by hetero-shell materials, respectively.
Keywords
CdS, quantum dots, core/shell, fast synthesis

Citation

Please use this url to cite or link to this publication:

MLA
Zeng, Min, et al. “Fast Synthesis of CdS/CdS Host-Shell Quantum Dots.” ChemCYS Book of Abstracts, Koninklijke Vlaamse Chemische Vereniging (KVCV), 2018.
APA
Zeng, M., Singh, S., Hens, Z., & Van Deun, R. (2018). Fast synthesis of CdS/CdS host-shell quantum dots. ChemCYS Book of Abstracts. Presented at the 14th Chemistry conference for Young Scientists (ChemCYS 2018), Blankenberge, Belgium.
Chicago author-date
Zeng, Min, Shalini Singh, Zeger Hens, and Rik Van Deun. 2018. “Fast Synthesis of CdS/CdS Host-Shell Quantum Dots.” In ChemCYS Book of Abstracts. Koninklijke Vlaamse Chemische Vereniging (KVCV).
Chicago author-date (all authors)
Zeng, Min, Shalini Singh, Zeger Hens, and Rik Van Deun. 2018. “Fast Synthesis of CdS/CdS Host-Shell Quantum Dots.” In ChemCYS Book of Abstracts. Koninklijke Vlaamse Chemische Vereniging (KVCV).
Vancouver
1.
Zeng M, Singh S, Hens Z, Van Deun R. Fast synthesis of CdS/CdS host-shell quantum dots. In: ChemCYS book of abstracts. Koninklijke Vlaamse Chemische Vereniging (KVCV); 2018.
IEEE
[1]
M. Zeng, S. Singh, Z. Hens, and R. Van Deun, “Fast synthesis of CdS/CdS host-shell quantum dots,” in ChemCYS book of abstracts, Blankenberge, Belgium, 2018.
@inproceedings{8575711,
  abstract     = {{The downconverting photoluminescence with heterogeneous core/shell nanocrystals has been largely investigated. While the homogeneous core/shell quantum dots have seldom been reported. For the small CdS (~2.2 nm) reference quantum dot, it exhibits serious trap emission. In most cases, wider-gap heterogeneous shells of ZnS1or ZnSe2 by slowly hot-injection method are employed to improve the surface passivation and thus improving its photoluminescence performance. The step by step hot-injection method is time-consuming. While the homogeneous CdS shell with fast and controllable epitaxial growth has never been reported. Herein, we demonstrate a flash fabrication method to synthesize the host-shell CdS capped CdS (CdS/CdS). The shell with different layers can be controlled by the amount of precursors added initially. The fluorescence results of the as synthesized host-shell CdS quantum dots, show that the growth of the CdS shell can efficiently remove the surface trap states, leading to high photoluminescence performance. Furthermore, this special core-host shell structure is used to increase the size of CdS, and to adjust the dopant positions inside nanocrystals.3 The fast synthetic procedure and the special host-shell structure present great potentials in preparing large-scale productions of core/shell quantum dots and site-dependent ions doped nanocrystals to avoid lattice mismatch caused by hetero-shell materials, respectively.}},
  author       = {{Zeng, Min and Singh, Shalini and Hens, Zeger and Van Deun, Rik}},
  booktitle    = {{ChemCYS book of abstracts}},
  keywords     = {{CdS,quantum dots,core/shell,fast synthesis}},
  language     = {{eng}},
  location     = {{Blankenberge, Belgium}},
  publisher    = {{Koninklijke Vlaamse Chemische Vereniging (KVCV)}},
  title        = {{Fast synthesis of CdS/CdS host-shell quantum dots}},
  year         = {{2018}},
}