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Acquisition of nonlinear kinetics from linear relations : application on homogeneous transesterification reactions

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Abstract
This paper proposes a fast method to determine kinetic parameters in systems with nonlinear concentration dependencies in equilibrium reactions. Without the use of complicated software, the corresponding parameters can be obtained from linear relations, with a minimum number of experimental data, acquired by semi-batch operation. The underlying theory is given for a general equilibrium reaction A+B. C+D and it is successfully applied for the real case of typical transesterification reactions. The proposed procedure opens the door for easy, i.e., linear, parameter estimation procedures using commercial software as Excel (R) without the tedious and nerve-racking nonlinear parameter estimation procedures. The presented methodology gives an easy access to forward as well as backward transesterification rate coefficients, which can be used for simulation purpose for non- steady reactor operation and corresponding optimization.
Keywords
Kinetic parameter estimation, Nonlinear kinetics, Biodiesel, Transesterification reactions, NEAR-INFRARED SPECTROSCOPY, MGO-CATALYZED TRANSESTERIFICATION, DESORPTION MASS-SPECTRA, OF-THE-ART, BIODIESEL PRODUCTION, SUNFLOWER OIL, SOYBEAN OIL, ACETIC-ACID, NIR SPECTROSCOPY, JATROPHA-CURCAS

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Citation

Please use this url to cite or link to this publication:

MLA
Heynderickx, Philippe. “Acquisition of Nonlinear Kinetics from Linear Relations : Application on Homogeneous Transesterification Reactions.” CHEMICAL ENGINEERING JOURNAL 342 (2018): 41–51. Print.
APA
Heynderickx, Philippe. (2018). Acquisition of nonlinear kinetics from linear relations : application on homogeneous transesterification reactions. CHEMICAL ENGINEERING JOURNAL, 342, 41–51.
Chicago author-date
Heynderickx, Philippe. 2018. “Acquisition of Nonlinear Kinetics from Linear Relations : Application on Homogeneous Transesterification Reactions.” Chemical Engineering Journal 342: 41–51.
Chicago author-date (all authors)
Heynderickx, Philippe. 2018. “Acquisition of Nonlinear Kinetics from Linear Relations : Application on Homogeneous Transesterification Reactions.” Chemical Engineering Journal 342: 41–51.
Vancouver
1.
Heynderickx P. Acquisition of nonlinear kinetics from linear relations : application on homogeneous transesterification reactions. CHEMICAL ENGINEERING JOURNAL. 2018;342:41–51.
IEEE
[1]
P. Heynderickx, “Acquisition of nonlinear kinetics from linear relations : application on homogeneous transesterification reactions,” CHEMICAL ENGINEERING JOURNAL, vol. 342, pp. 41–51, 2018.
@article{8573501,
  abstract     = {This paper proposes a fast method to determine kinetic parameters in systems with nonlinear concentration dependencies in equilibrium reactions. Without the use of complicated software, the corresponding parameters can be obtained from linear relations, with a minimum number of experimental data, acquired by semi-batch operation. 
The underlying theory is given for a general equilibrium reaction A+B. C+D and it is successfully applied for the real case of typical transesterification reactions. The proposed procedure opens the door for easy, i.e., linear, parameter estimation procedures using commercial software as Excel (R) without the tedious and nerve-racking nonlinear parameter estimation procedures. 
The presented methodology gives an easy access to forward as well as backward transesterification rate coefficients, which can be used for simulation purpose for non- steady reactor operation and corresponding optimization.},
  author       = {Heynderickx, Philippe},
  issn         = {1385-8947},
  journal      = {CHEMICAL ENGINEERING JOURNAL},
  keywords     = {Kinetic parameter estimation,Nonlinear kinetics,Biodiesel,Transesterification reactions,NEAR-INFRARED SPECTROSCOPY,MGO-CATALYZED TRANSESTERIFICATION,DESORPTION MASS-SPECTRA,OF-THE-ART,BIODIESEL PRODUCTION,SUNFLOWER OIL,SOYBEAN OIL,ACETIC-ACID,NIR SPECTROSCOPY,JATROPHA-CURCAS},
  language     = {eng},
  pages        = {41--51},
  title        = {Acquisition of nonlinear kinetics from linear relations : application on homogeneous transesterification reactions},
  volume       = {342},
  year         = {2018},
}

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