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Copper(I)-N-heterocyclic carbene complexes as efficient catalysts for the synthesis of 1,4-disubstituted 1,2,3-sulfonyltriazoles in air

(2018) ORGANOMETALLICS. 37(5). p.679-683
Author
Organization
Abstract
Bis-NHC and mixed NHC/PR3 copper(I) complexes (NHC = N-heterocyclic carbene) were found to be efficient catalysts enabling the azide-alkyne cycloaddition reaction leading to the formation of 1,2,3-sulfonyltriazoles under Click conditions. The mechanism of this transformation was probed and decoordination of the NHC ligand (even in the NHC/PR3 mixed ligand systems) during the catalytic transformation was observed.
Keywords
SULFONYL AZIDES, CONTROLLING SELECTIVITY, CLICK CHEMISTRY, ALKYNES, 1-SULFONYL-1, 2, 3-TRIAZOLES, N-SULFONYL-1, 2, 3-TRIAZOLES, TRANSANNULATION, CYCLOADDITION, WATER, REACTIVITY

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Citation

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Chicago
Lazreg, Faïma, and Catherine Cazin. 2018. “Copper(I)-N-heterocyclic Carbene Complexes as Efficient Catalysts for the Synthesis of 1,4-disubstituted 1,2,3-sulfonyltriazoles in Air.” Organometallics 37 (5): 679–683.
APA
Lazreg, Faïma, & Cazin, C. (2018). Copper(I)-N-heterocyclic carbene complexes as efficient catalysts for the synthesis of 1,4-disubstituted 1,2,3-sulfonyltriazoles in air. ORGANOMETALLICS, 37(5), 679–683.
Vancouver
1.
Lazreg F, Cazin C. Copper(I)-N-heterocyclic carbene complexes as efficient catalysts for the synthesis of 1,4-disubstituted 1,2,3-sulfonyltriazoles in air. ORGANOMETALLICS. 2018;37(5):679–83.
MLA
Lazreg, Faïma, and Catherine Cazin. “Copper(I)-N-heterocyclic Carbene Complexes as Efficient Catalysts for the Synthesis of 1,4-disubstituted 1,2,3-sulfonyltriazoles in Air.” ORGANOMETALLICS 37.5 (2018): 679–683. Print.
@article{8555574,
  abstract     = {Bis-NHC and mixed NHC/PR3 copper(I) complexes (NHC = N-heterocyclic carbene) were found to be efficient catalysts enabling the azide-alkyne cycloaddition reaction leading to the formation of 1,2,3-sulfonyltriazoles under Click conditions. The mechanism of this transformation was probed and decoordination of the NHC ligand (even in the NHC/PR3 mixed ligand systems) during the catalytic transformation was observed.},
  author       = {Lazreg, Fa{\"i}ma and Cazin, Catherine},
  issn         = {0276-7333},
  journal      = {ORGANOMETALLICS},
  language     = {eng},
  number       = {5},
  pages        = {679--683},
  title        = {Copper(I)-N-heterocyclic carbene complexes as efficient catalysts for the synthesis of 1,4-disubstituted 1,2,3-sulfonyltriazoles in air},
  url          = {http://dx.doi.org/10.1021/acs.organomet.7b00506},
  volume       = {37},
  year         = {2018},
}

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