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Synthesis, characterization and catalytic properties of a copper-containing polyoxovanadate nanocluster in azide-alkyne cycloaddition

(2017) JOURNAL OF COORDINATION CHEMISTRY. 70(9). p.1564-1572
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Abstract
A copper-containing polyoxovanadate nanocluster, [(C2H5)(4)N](4) [V8Cu2O24]center dot 2H(2)O(1), was synthesized through reaction between the Cu(NO3)(2)center dot 3H(2)O and [(C2H5)(4)N](4)VO3 in the molar ratio 1 : 4. Nanocluster 1 was characterized by IR, elemental analysis, XRD, SEM, TEM, and X-ray crystallography. The catalytic activity of 1 for the azide-alkyne cycloaddition of different terminal alkynes and organic azides generated in situ from sodium azide and different organic halides was tested. The protocol could afford the corresponding products in good to excellent yield at very low catalyst loadings (3.4 Mol%) under the optimized reaction conditions.
Keywords
Polyoxovanadate, copper, nanocluster, azide-alkyne cycloaddition, CU2O NANOPARTICLES, HETEROPOLY ACIDS, CLICK CHEMISTRY, POLYOXOMOLYBDATE, OXIDATION

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MLA
Amini, Mojtaba et al. “Synthesis, Characterization and Catalytic Properties of a Copper-containing Polyoxovanadate Nanocluster in Azide-alkyne Cycloaddition.” JOURNAL OF COORDINATION CHEMISTRY 70.9 (2017): 1564–1572. Print.
APA
Amini, M., Tekantappeh, S. B., Eftekhari-Sis, B., Gohari Derakhshandeh, P., & Van Hecke, K. (2017). Synthesis, characterization and catalytic properties of a copper-containing polyoxovanadate nanocluster in azide-alkyne cycloaddition. JOURNAL OF COORDINATION CHEMISTRY, 70(9), 1564–1572.
Chicago author-date
Amini, Mojtaba, Sajjad Bahadori Tekantappeh, Bagher Eftekhari-Sis, Parviz Gohari Derakhshandeh, and Kristof Van Hecke. 2017. “Synthesis, Characterization and Catalytic Properties of a Copper-containing Polyoxovanadate Nanocluster in Azide-alkyne Cycloaddition.” Journal of Coordination Chemistry 70 (9): 1564–1572.
Chicago author-date (all authors)
Amini, Mojtaba, Sajjad Bahadori Tekantappeh, Bagher Eftekhari-Sis, Parviz Gohari Derakhshandeh, and Kristof Van Hecke. 2017. “Synthesis, Characterization and Catalytic Properties of a Copper-containing Polyoxovanadate Nanocluster in Azide-alkyne Cycloaddition.” Journal of Coordination Chemistry 70 (9): 1564–1572.
Vancouver
1.
Amini M, Tekantappeh SB, Eftekhari-Sis B, Gohari Derakhshandeh P, Van Hecke K. Synthesis, characterization and catalytic properties of a copper-containing polyoxovanadate nanocluster in azide-alkyne cycloaddition. JOURNAL OF COORDINATION CHEMISTRY. 2017;70(9):1564–72.
IEEE
[1]
M. Amini, S. B. Tekantappeh, B. Eftekhari-Sis, P. Gohari Derakhshandeh, and K. Van Hecke, “Synthesis, characterization and catalytic properties of a copper-containing polyoxovanadate nanocluster in azide-alkyne cycloaddition,” JOURNAL OF COORDINATION CHEMISTRY, vol. 70, no. 9, pp. 1564–1572, 2017.
@article{8551395,
  abstract     = {A copper-containing polyoxovanadate nanocluster, [(C2H5)(4)N](4) [V8Cu2O24]center dot 2H(2)O(1), was synthesized through reaction between the Cu(NO3)(2)center dot 3H(2)O and [(C2H5)(4)N](4)VO3 in the molar ratio 1 : 4. Nanocluster 1 was characterized by IR, elemental analysis, XRD, SEM, TEM, and X-ray crystallography. The catalytic activity of 1 for the azide-alkyne cycloaddition of different terminal alkynes and organic azides generated in situ from sodium azide and different organic halides was tested. The protocol could afford the corresponding products in good to excellent yield at very low catalyst loadings (3.4 Mol%) under the optimized reaction conditions.},
  author       = {Amini, Mojtaba and Tekantappeh, Sajjad Bahadori and Eftekhari-Sis, Bagher and Gohari Derakhshandeh, Parviz and Van Hecke, Kristof},
  issn         = {0095-8972},
  journal      = {JOURNAL OF COORDINATION CHEMISTRY},
  keywords     = {Polyoxovanadate,copper,nanocluster,azide-alkyne cycloaddition,CU2O NANOPARTICLES,HETEROPOLY ACIDS,CLICK CHEMISTRY,POLYOXOMOLYBDATE,OXIDATION},
  language     = {eng},
  number       = {9},
  pages        = {1564--1572},
  title        = {Synthesis, characterization and catalytic properties of a copper-containing polyoxovanadate nanocluster in azide-alkyne cycloaddition},
  url          = {http://dx.doi.org/10.1080/00958972.2017.1313977},
  volume       = {70},
  year         = {2017},
}

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