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Responsive thiolactone-derived N-substituted poly(urethane-amide)s

Pieter Espeel, Sensu Celasun, Pinar Sinem Omurtag, Steven Martens UGent and Filip Du Prez UGent (2017) MACROMOLECULAR RAPID COMMUNICATIONS. 38(7).
abstract
AB' type monomers containing a thiolactone unit and vinyl ether moiety have been prepared with high yields. Aminolysis of the thiolactone moiety generates the corresponding thiol in situ, and upon UV-irradiation, radical polyaddition occurs in the same medium, yielding linear poly(amide-urethane)s with different side chain residues and (Poly(Ethylene Oxide)) PEO-like backbone. Moreover, these unique polymers feature lower critical solution temperature behavior in water. Systematic modification of the responsive polymers reveals the influence of the variation of the side chains and the backbone structure on the corresponding solubility properties. In selected cases, multiresponsive polymers have been developed, which also respond to pH and metal concentration.
Please use this url to cite or link to this publication:
author
organization
year
type
journalArticle (original)
publication status
published
subject
keyword
ONE-POT, CHEMISTRY, POLYMERS, SCIENCE, TOOL, aminolysis, polyaddition, responsive polymers, thiolactone, thiol-ene
journal title
MACROMOLECULAR RAPID COMMUNICATIONS
Macromol. Rapid Commun.
volume
38
issue
7
article number
1600783
pages
5 pages
Web of Science type
Article
Web of Science id
000398605700002
ISSN
1022-1336
1521-3927
DOI
10.1002/marc.201600783
language
English
UGent publication?
yes
classification
A1
copyright statement
I have transferred the copyright for this publication to the publisher
id
8547592
handle
http://hdl.handle.net/1854/LU-8547592
date created
2018-02-02 12:30:45
date last changed
2018-06-12 11:52:18
@article{8547592,
  abstract     = {AB' type monomers containing a thiolactone unit and vinyl ether moiety have been prepared with high yields. Aminolysis of the thiolactone moiety generates the corresponding thiol in situ, and upon UV-irradiation, radical polyaddition occurs in the same medium, yielding linear poly(amide-urethane)s with different side chain residues and (Poly(Ethylene Oxide)) PEO-like backbone. Moreover, these unique polymers feature lower critical solution temperature behavior in water. Systematic modification of the responsive polymers reveals the influence of the variation of the side chains and the backbone structure on the corresponding solubility properties. In selected cases, multiresponsive polymers have been developed, which also respond to pH and metal concentration.},
  articleno    = {1600783},
  author       = {Espeel, Pieter and Celasun, Sensu and Omurtag, Pinar Sinem and Martens, Steven and Du Prez, Filip},
  issn         = {1022-1336},
  journal      = {MACROMOLECULAR RAPID COMMUNICATIONS},
  keyword      = {ONE-POT,CHEMISTRY,POLYMERS,SCIENCE,TOOL,aminolysis,polyaddition,responsive polymers,thiolactone,thiol-ene},
  language     = {eng},
  number       = {7},
  pages        = {5},
  title        = {Responsive thiolactone-derived N-substituted poly(urethane-amide)s},
  url          = {http://dx.doi.org/10.1002/marc.201600783},
  volume       = {38},
  year         = {2017},
}

Chicago
Espeel, Pieter, Sensu Celasun, Pinar Sinem Omurtag, Steven Martens, and Filip Du Prez. 2017. “Responsive Thiolactone-derived N-substituted Poly(urethane-amide)s.” Macromolecular Rapid Communications 38 (7).
APA
Espeel, P., Celasun, S., Omurtag, P. S., Martens, S., & Du Prez, F. (2017). Responsive thiolactone-derived N-substituted poly(urethane-amide)s. MACROMOLECULAR RAPID COMMUNICATIONS, 38(7).
Vancouver
1.
Espeel P, Celasun S, Omurtag PS, Martens S, Du Prez F. Responsive thiolactone-derived N-substituted poly(urethane-amide)s. MACROMOLECULAR RAPID COMMUNICATIONS. 2017;38(7).
MLA
Espeel, Pieter, Sensu Celasun, Pinar Sinem Omurtag, et al. “Responsive Thiolactone-derived N-substituted Poly(urethane-amide)s.” MACROMOLECULAR RAPID COMMUNICATIONS 38.7 (2017): n. pag. Print.