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Lignin inspired phenolic polyethers synthesized via ADMET : systematic structure-property investigation

(2017) EUROPEAN POLYMER JOURNAL. 95. p.503-513
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Abstract
A library of alpha,omega-dienes has been prepared via Williamson ether synthesis from aromatic diols, which can be extracted from lignin as biosource or exhibit related structural motifs. These dienes were subsequently subjected to acyclic diene metathesis polymerisation (ADMET). The molecular characterisation of monomers and polymers was performed using NMR spectroscopy, GC-MS, and SEC. The influence of the monomer structure on the thermal properties of the phenolic polyether polymers was investigated by DSC. Glass transition temperatures (T-g) in the range of -44 to 18 degrees C were detected depending on the monomer structure while TGA analysis showed degradation temperatures between 160 degrees C and 300 degrees C. T-g-values could be further increased up to a value of 110 degrees C by fast and versatile post-modification with 1,2,4-triazolinedione (TAD) click chemistry. In addition, the characteristic double bonds of the ADMET-derived polymer chains allowed for crosslinking by this TAD chemistry.
Keywords
ACYCLIC DIENE METATHESIS, OLEFIN ISOMERIZATION, BIOBASED POLYMERS, VANILLIN, POLYMERIZATION, CHEMISTRY, DEPOLYMERIZATION, DERIVATIVES, MONOMER, ACID, Lignin, Vanillin, ADMET, Triazolinediones

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Citation

Please use this url to cite or link to this publication:

MLA
Vlaminck, Laetitia et al. “Lignin Inspired Phenolic Polyethers Synthesized via ADMET : Systematic Structure-property Investigation.” EUROPEAN POLYMER JOURNAL 95 (2017): 503–513. Print.
APA
Vlaminck, Laetitia, Lingier, S., Hufendiek, A., & Du Prez, F. (2017). Lignin inspired phenolic polyethers synthesized via ADMET : systematic structure-property investigation. EUROPEAN POLYMER JOURNAL, 95, 503–513.
Chicago author-date
Vlaminck, Laetitia, Sophie Lingier, Andrea Hufendiek, and Filip Du Prez. 2017. “Lignin Inspired Phenolic Polyethers Synthesized via ADMET : Systematic Structure-property Investigation.” European Polymer Journal 95: 503–513.
Chicago author-date (all authors)
Vlaminck, Laetitia, Sophie Lingier, Andrea Hufendiek, and Filip Du Prez. 2017. “Lignin Inspired Phenolic Polyethers Synthesized via ADMET : Systematic Structure-property Investigation.” European Polymer Journal 95: 503–513.
Vancouver
1.
Vlaminck L, Lingier S, Hufendiek A, Du Prez F. Lignin inspired phenolic polyethers synthesized via ADMET : systematic structure-property investigation. EUROPEAN POLYMER JOURNAL. 2017;95:503–13.
IEEE
[1]
L. Vlaminck, S. Lingier, A. Hufendiek, and F. Du Prez, “Lignin inspired phenolic polyethers synthesized via ADMET : systematic structure-property investigation,” EUROPEAN POLYMER JOURNAL, vol. 95, pp. 503–513, 2017.
@article{8547575,
  abstract     = {{A library of alpha,omega-dienes has been prepared via Williamson ether synthesis from aromatic diols, which can be extracted from lignin as biosource or exhibit related structural motifs. These dienes were subsequently subjected to acyclic diene metathesis polymerisation (ADMET). The molecular characterisation of monomers and polymers was performed using NMR spectroscopy, GC-MS, and SEC. The influence of the monomer structure on the thermal properties of the phenolic polyether polymers was investigated by DSC. Glass transition temperatures (T-g) in the range of -44 to 18 degrees C were detected depending on the monomer structure while TGA analysis showed degradation temperatures between 160 degrees C and 300 degrees C. T-g-values could be further increased up to a value of 110 degrees C by fast and versatile post-modification with 1,2,4-triazolinedione (TAD) click chemistry. In addition, the characteristic double bonds of the ADMET-derived polymer chains allowed for crosslinking by this TAD chemistry.}},
  author       = {{Vlaminck, Laetitia and Lingier, Sophie and Hufendiek, Andrea and Du Prez, Filip}},
  issn         = {{0014-3057}},
  journal      = {{EUROPEAN POLYMER JOURNAL}},
  keywords     = {{ACYCLIC DIENE METATHESIS,OLEFIN ISOMERIZATION,BIOBASED POLYMERS,VANILLIN,POLYMERIZATION,CHEMISTRY,DEPOLYMERIZATION,DERIVATIVES,MONOMER,ACID,Lignin,Vanillin,ADMET,Triazolinediones}},
  language     = {{eng}},
  pages        = {{503--513}},
  title        = {{Lignin inspired phenolic polyethers synthesized via ADMET : systematic structure-property investigation}},
  url          = {{http://dx.doi.org/10.1016/j.eurpolymj.2017.08.042}},
  volume       = {{95}},
  year         = {{2017}},
}

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