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Click and click-inspired chemistry for the design of sequence-controlled polymers

Steven Martens (UGent) , Joshua Holloway (UGent) and Filip Du Prez (UGent)
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Abstract
During the previous decade, many popular chemical reactions used in the area of "click" chemistry and similarly efficient "click-inspired" reactions have been applied for the design of sequence-defined and, more generally, sequence-controlled structures. This combination of topics has already made quite a significant impact on scientific research to date and has enabled the synthesis of highly functionalized and complex oligomeric and polymeric structures, which offer the prospect of many exciting further developments and applications in the near future. This minireview highlights the fruitful combination of these two topics for the preparation of sequence-controlled oligomeric and macromolecular structures and showcases the vast number of publications in this field within a relatively short span of time. It is divided into three sections according to the click-(inspired) reaction that has been applied: copper-catalyzed azide-alkyne cycloaddition, thiol-X, and related thiolactone-based reactions, and finally Diels-Alder-chemistry-based routes are outlined, respectively.
Keywords
AZIDE-ALKYNE CYCLOADDITION, SOLID-PHASE SYNTHESIS, ITERATIVE, EXPONENTIAL-GROWTH, SELECTIVE RADICAL-ADDITION, N-SUBSTITUTED, MALEIMIDES, HYBRID BLOCK-COPOLYMERS, PEPTIDE NUCLEIC-ACIDS, THIOL-ENE, BUILDING-BLOCKS, ONE-POT, click chemistry, CuAAC, Diels-Alder, sequence-controlled structures, thiol-X

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Citation

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Chicago
Martens, Steven, Joshua Holloway, and Filip Du Prez. 2017. “Click and Click-inspired Chemistry for the Design of Sequence-controlled Polymers.” Macromolecular Rapid Communications 38 (24).
APA
Martens, Steven, Holloway, J., & Du Prez, F. (2017). Click and click-inspired chemistry for the design of sequence-controlled polymers. MACROMOLECULAR RAPID COMMUNICATIONS, 38(24).
Vancouver
1.
Martens S, Holloway J, Du Prez F. Click and click-inspired chemistry for the design of sequence-controlled polymers. MACROMOLECULAR RAPID COMMUNICATIONS. 2017;38(24).
MLA
Martens, Steven, Joshua Holloway, and Filip Du Prez. “Click and Click-inspired Chemistry for the Design of Sequence-controlled Polymers.” MACROMOLECULAR RAPID COMMUNICATIONS 38.24 (2017): n. pag. Print.
@article{8547569,
  abstract     = {During the previous decade, many popular chemical reactions used in the area of "click" chemistry and similarly efficient "click-inspired" reactions have been applied for the design of sequence-defined and, more generally, sequence-controlled structures. This combination of topics has already made quite a significant impact on scientific research to date and has enabled the synthesis of highly functionalized and complex oligomeric and polymeric structures, which offer the prospect of many exciting further developments and applications in the near future. This minireview highlights the fruitful combination of these two topics for the preparation of sequence-controlled oligomeric and macromolecular structures and showcases the vast number of publications in this field within a relatively short span of time. It is divided into three sections according to the click-(inspired) reaction that has been applied: copper-catalyzed azide-alkyne cycloaddition, thiol-X, and related thiolactone-based reactions, and finally Diels-Alder-chemistry-based routes are outlined, respectively.},
  articleno    = {1700469},
  author       = {Martens, Steven and Holloway, Joshua and Du Prez, Filip},
  issn         = {1022-1336},
  journal      = {MACROMOLECULAR RAPID COMMUNICATIONS},
  keywords     = {AZIDE-ALKYNE CYCLOADDITION,SOLID-PHASE SYNTHESIS,ITERATIVE,EXPONENTIAL-GROWTH,SELECTIVE RADICAL-ADDITION,N-SUBSTITUTED,MALEIMIDES,HYBRID BLOCK-COPOLYMERS,PEPTIDE NUCLEIC-ACIDS,THIOL-ENE,BUILDING-BLOCKS,ONE-POT,click chemistry,CuAAC,Diels-Alder,sequence-controlled structures,thiol-X},
  language     = {eng},
  number       = {24},
  pages        = {15},
  title        = {Click and click-inspired chemistry for the design of sequence-controlled polymers},
  url          = {http://dx.doi.org/10.1002/marc.201700469},
  volume       = {38},
  year         = {2017},
}

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