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Investigating the structure and reactivity of azolyl-based copper(I)-NHC complexes : the role of the anionic ligand

(2017) ACS CATALYSIS. 7(12). p.8176-8183
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Abstract
A family of copper(I)-NHC azolyl complexes was synthesized and deployed in the hydrosilylation of dicyclo-hexylketone to probe the role of the anionic ligand on catalytic performance. The azolyl ligand is shown to have a crucial role in catalytic activity without the need for additives, and this at very low catalyst loading.
Keywords
N-HETEROCYCLIC CARBENE, EFFICIENT ENANTIOSELECTIVE HYDROSILYLATION, ARYL, KETONES, ASYMMETRIC HYDROSILYLATION, CATALYZED HYDROSILYLATION, CARBONYL-COMPOUNDS, CU-I, COPPER, HYDRIDE, REDUCTION, N-heterocyclic carbenes, copper(I), hydrosilylation, anionic ligand, dimer, autocatalytic

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Citation

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MLA
Trose, Michael, et al. “Investigating the Structure and Reactivity of Azolyl-Based Copper(I)-NHC Complexes : The Role of the Anionic Ligand.” ACS CATALYSIS, vol. 7, no. 12, 2017, pp. 8176–83, doi:10.1021/acscatal.7b02737.
APA
Trose, M., Nahra, F., Poater, A., Cordes, D. B., Slawin, A. M. Z., Cavallo, L., & Cazin, C. (2017). Investigating the structure and reactivity of azolyl-based copper(I)-NHC complexes : the role of the anionic ligand. ACS CATALYSIS, 7(12), 8176–8183. https://doi.org/10.1021/acscatal.7b02737
Chicago author-date
Trose, Michael, Fady Nahra, Albert Poater, David B. Cordes, Alexandra M. Z. Slawin, Luigi Cavallo, and Catherine Cazin. 2017. “Investigating the Structure and Reactivity of Azolyl-Based Copper(I)-NHC Complexes : The Role of the Anionic Ligand.” ACS CATALYSIS 7 (12): 8176–83. https://doi.org/10.1021/acscatal.7b02737.
Chicago author-date (all authors)
Trose, Michael, Fady Nahra, Albert Poater, David B. Cordes, Alexandra M. Z. Slawin, Luigi Cavallo, and Catherine Cazin. 2017. “Investigating the Structure and Reactivity of Azolyl-Based Copper(I)-NHC Complexes : The Role of the Anionic Ligand.” ACS CATALYSIS 7 (12): 8176–8183. doi:10.1021/acscatal.7b02737.
Vancouver
1.
Trose M, Nahra F, Poater A, Cordes DB, Slawin AMZ, Cavallo L, et al. Investigating the structure and reactivity of azolyl-based copper(I)-NHC complexes : the role of the anionic ligand. ACS CATALYSIS. 2017;7(12):8176–83.
IEEE
[1]
M. Trose et al., “Investigating the structure and reactivity of azolyl-based copper(I)-NHC complexes : the role of the anionic ligand,” ACS CATALYSIS, vol. 7, no. 12, pp. 8176–8183, 2017.
@article{8546307,
  abstract     = {{A family of copper(I)-NHC azolyl complexes was synthesized and deployed in the hydrosilylation of dicyclo-hexylketone to probe the role of the anionic ligand on catalytic performance. The azolyl ligand is shown to have a crucial role in catalytic activity without the need for additives, and this at very low catalyst loading.}},
  author       = {{Trose, Michael and Nahra, Fady and Poater, Albert and Cordes, David B. and Slawin, Alexandra M. Z. and Cavallo, Luigi and Cazin, Catherine}},
  issn         = {{2155-5435}},
  journal      = {{ACS CATALYSIS}},
  keywords     = {{N-HETEROCYCLIC CARBENE,EFFICIENT ENANTIOSELECTIVE HYDROSILYLATION,ARYL,KETONES,ASYMMETRIC HYDROSILYLATION,CATALYZED HYDROSILYLATION,CARBONYL-COMPOUNDS,CU-I,COPPER,HYDRIDE,REDUCTION,N-heterocyclic carbenes,copper(I),hydrosilylation,anionic ligand,dimer,autocatalytic}},
  language     = {{eng}},
  number       = {{12}},
  pages        = {{8176--8183}},
  title        = {{Investigating the structure and reactivity of azolyl-based copper(I)-NHC complexes : the role of the anionic ligand}},
  url          = {{http://dx.doi.org/10.1021/acscatal.7b02737}},
  volume       = {{7}},
  year         = {{2017}},
}

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