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Discovery of a novel, large pore phase in a bimetallic Al/V metal-organic framework

Hannes Depauw (UGent) , Irena Nevjestic (UGent) , Guangbo Wang, Karen Leus (UGent) , Freddy Callens (UGent) , Els De Canck (UGent) , Klaartje De Buysser (UGent) , Henk Vrielinck (UGent) and Pascal Van Der Voort (UGent)
(2017) JOURNAL OF MATERIALS CHEMISTRY A. 5(47). p.24580-24584
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Organization
Abstract
A new series of bimetallic COMOC-2(V)/DUT-5(Al) frameworks are developed and fully characterized. Electron paramagnetic resonance and transmission electron microscopy confirm the homogeneous dispersion of Al/V in the entire framework. The study of the flexibility by means of CO2 pressure dependent XRPD and high pressure sorption reveals the co-existence of two different large pore phases and a narrow pore phase in the entire pressure regime.
Keywords
ELECTRON-PARAMAGNETIC-RESONANCE, CO2 ADSORPTION, MIL-53, FLEXIBILITY, NH2-MIL-47, CATALYST

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MLA
Depauw, Hannes, et al. “Discovery of a Novel, Large Pore Phase in a Bimetallic Al/V Metal-Organic Framework.” JOURNAL OF MATERIALS CHEMISTRY A, vol. 5, no. 47, 2017, pp. 24580–84, doi:10.1039/c7ta08103k.
APA
Depauw, H., Nevjestic, I., Wang, G., Leus, K., Callens, F., De Canck, E., … Van Der Voort, P. (2017). Discovery of a novel, large pore phase in a bimetallic Al/V metal-organic framework. JOURNAL OF MATERIALS CHEMISTRY A, 5(47), 24580–24584. https://doi.org/10.1039/c7ta08103k
Chicago author-date
Depauw, Hannes, Irena Nevjestic, Guangbo Wang, Karen Leus, Freddy Callens, Els De Canck, Klaartje De Buysser, Henk Vrielinck, and Pascal Van Der Voort. 2017. “Discovery of a Novel, Large Pore Phase in a Bimetallic Al/V Metal-Organic Framework.” JOURNAL OF MATERIALS CHEMISTRY A 5 (47): 24580–84. https://doi.org/10.1039/c7ta08103k.
Chicago author-date (all authors)
Depauw, Hannes, Irena Nevjestic, Guangbo Wang, Karen Leus, Freddy Callens, Els De Canck, Klaartje De Buysser, Henk Vrielinck, and Pascal Van Der Voort. 2017. “Discovery of a Novel, Large Pore Phase in a Bimetallic Al/V Metal-Organic Framework.” JOURNAL OF MATERIALS CHEMISTRY A 5 (47): 24580–24584. doi:10.1039/c7ta08103k.
Vancouver
1.
Depauw H, Nevjestic I, Wang G, Leus K, Callens F, De Canck E, et al. Discovery of a novel, large pore phase in a bimetallic Al/V metal-organic framework. JOURNAL OF MATERIALS CHEMISTRY A. 2017;5(47):24580–4.
IEEE
[1]
H. Depauw et al., “Discovery of a novel, large pore phase in a bimetallic Al/V metal-organic framework,” JOURNAL OF MATERIALS CHEMISTRY A, vol. 5, no. 47, pp. 24580–24584, 2017.
@article{8543509,
  abstract     = {{A new series of bimetallic COMOC-2(V)/DUT-5(Al) frameworks are developed and fully characterized. Electron paramagnetic resonance and transmission electron microscopy confirm the homogeneous dispersion of Al/V in the entire framework. The study of the flexibility by means of CO2 pressure dependent XRPD and high pressure sorption reveals the co-existence of two different large pore phases and a narrow pore phase in the entire pressure regime.}},
  author       = {{Depauw, Hannes and Nevjestic, Irena and Wang, Guangbo and Leus, Karen and Callens, Freddy and De Canck, Els and De Buysser, Klaartje and Vrielinck, Henk and Van Der Voort, Pascal}},
  issn         = {{2050-7488}},
  journal      = {{JOURNAL OF MATERIALS CHEMISTRY A}},
  keywords     = {{ELECTRON-PARAMAGNETIC-RESONANCE,CO2 ADSORPTION,MIL-53,FLEXIBILITY,NH2-MIL-47,CATALYST}},
  language     = {{eng}},
  number       = {{47}},
  pages        = {{24580--24584}},
  title        = {{Discovery of a novel, large pore phase in a bimetallic Al/V metal-organic framework}},
  url          = {{http://dx.doi.org/10.1039/c7ta08103k}},
  volume       = {{5}},
  year         = {{2017}},
}

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