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Discovery of a novel, large pore phase in a bimetallic Al/V metal-organic framework

Hannes Depauw (UGent) , Irena Nevjestic (UGent) , Guangbo Wang (UGent) , Karen Leus (UGent) , Freddy Callens (UGent) , Els De Canck (UGent) , Klaartje De Buysser (UGent) , Henk Vrielinck (UGent) and Pascal Van Der Voort (UGent)
(2017) JOURNAL OF MATERIALS CHEMISTRY A. 5(47). p.24580-24584
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Abstract
A new series of bimetallic COMOC-2(V)/DUT-5(Al) frameworks are developed and fully characterized. Electron paramagnetic resonance and transmission electron microscopy confirm the homogeneous dispersion of Al/V in the entire framework. The study of the flexibility by means of CO2 pressure dependent XRPD and high pressure sorption reveals the co-existence of two different large pore phases and a narrow pore phase in the entire pressure regime.
Keywords
ELECTRON-PARAMAGNETIC-RESONANCE, CO2 ADSORPTION, MIL-53, FLEXIBILITY, NH2-MIL-47, CATALYST

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Chicago
Depauw, Hannes, Irena Nevjestic, Guangbo Wang, Karen Leus, Freddy Callens, Els De Canck, Klaartje De Buysser, Henk Vrielinck, and Pascal Van Der Voort. 2017. “Discovery of a Novel, Large Pore Phase in a Bimetallic Al/V Metal-organic Framework.” Journal of Materials Chemistry A 5 (47): 24580–24584.
APA
Depauw, H., Nevjestic, I., Wang, G., Leus, K., Callens, F., De Canck, E., De Buysser, K., et al. (2017). Discovery of a novel, large pore phase in a bimetallic Al/V metal-organic framework. JOURNAL OF MATERIALS CHEMISTRY A, 5(47), 24580–24584.
Vancouver
1.
Depauw H, Nevjestic I, Wang G, Leus K, Callens F, De Canck E, et al. Discovery of a novel, large pore phase in a bimetallic Al/V metal-organic framework. JOURNAL OF MATERIALS CHEMISTRY A. 2017;5(47):24580–4.
MLA
Depauw, Hannes, Irena Nevjestic, Guangbo Wang, et al. “Discovery of a Novel, Large Pore Phase in a Bimetallic Al/V Metal-organic Framework.” JOURNAL OF MATERIALS CHEMISTRY A 5.47 (2017): 24580–24584. Print.
@article{8543509,
  abstract     = {A new series of bimetallic COMOC-2(V)/DUT-5(Al) frameworks are developed and fully characterized. Electron paramagnetic resonance and transmission electron microscopy confirm the homogeneous dispersion of Al/V in the entire framework. The study of the flexibility by means of CO2 pressure dependent XRPD and high pressure sorption reveals the co-existence of two different large pore phases and a narrow pore phase in the entire pressure regime.},
  author       = {Depauw, Hannes and Nevjestic, Irena and Wang, Guangbo and Leus, Karen and Callens, Freddy and De Canck, Els and De Buysser, Klaartje and Vrielinck, Henk and Van Der Voort, Pascal},
  issn         = {2050-7488},
  journal      = {JOURNAL OF MATERIALS CHEMISTRY A},
  keyword      = {ELECTRON-PARAMAGNETIC-RESONANCE,CO2 ADSORPTION,MIL-53,FLEXIBILITY,NH2-MIL-47,CATALYST},
  language     = {eng},
  number       = {47},
  pages        = {24580--24584},
  title        = {Discovery of a novel, large pore phase in a bimetallic Al/V metal-organic framework},
  url          = {http://dx.doi.org/10.1039/c7ta08103k},
  volume       = {5},
  year         = {2017},
}

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