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Generalization of the copper to late-transition-metal transmetallation to carbenes beyond N-heterocyclic carbenes

Yannick D Bidal, Orlando Santoro, Mohand Melaimi, David B Cordes, Alexandra MZ Slawin, Guy Bertrand and Catherine Cazin (UGent)
(2016) CHEMISTRY-A EUROPEAN JOURNAL. 22(27). p.9404-9409
Author
Organization
Abstract
Carbene transition-metal complexes have become a prevalent family of catalysts enabling numerous organic transformations. Their facile synthetic access is a matter of great importance. To this end, the Cu-I-NHC transfer methodology has emerged as a powerful alternative presenting attractive advantages over other methods. Herein, we report the remarkable ability of copper to transfer not only NHCs but also other types of carbenes such as abnormal NHCs (aNHCs), cyclic (alkyl)(amino)carbenes (CAACs), and mesoionic carbenes (MICs) to various transition metal precursors.
Keywords
abnormal, CAAC, carbene transfer, copper, n-heterocyclic carbene, LIGANDS SYNTHESIS, COMPLEXES, PALLADIUM, CATALYSIS, CHEMISTRY, STABILIZATION, IMIDAZOLIUM, REACTIVITY, CHROMIUM, REMOTE

Citation

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Chicago
Bidal, Yannick D, Orlando Santoro, Mohand Melaimi, David B Cordes, Alexandra MZ Slawin, Guy Bertrand, and Catherine Cazin. 2016. “Generalization of the Copper to Late-transition-metal Transmetallation to Carbenes Beyond N-heterocyclic Carbenes.” Chemistry-a European Journal 22 (27): 9404–9409.
APA
Bidal, Y. D., Santoro, O., Melaimi, M., Cordes, D. B., Slawin, A. M., Bertrand, G., & Cazin, C. (2016). Generalization of the copper to late-transition-metal transmetallation to carbenes beyond N-heterocyclic carbenes. CHEMISTRY-A EUROPEAN JOURNAL, 22(27), 9404–9409.
Vancouver
1.
Bidal YD, Santoro O, Melaimi M, Cordes DB, Slawin AM, Bertrand G, et al. Generalization of the copper to late-transition-metal transmetallation to carbenes beyond N-heterocyclic carbenes. CHEMISTRY-A EUROPEAN JOURNAL. 2016;22(27):9404–9.
MLA
Bidal, Yannick D, Orlando Santoro, Mohand Melaimi, et al. “Generalization of the Copper to Late-transition-metal Transmetallation to Carbenes Beyond N-heterocyclic Carbenes.” CHEMISTRY-A EUROPEAN JOURNAL 22.27 (2016): 9404–9409. Print.
@article{8536970,
  abstract     = {Carbene transition-metal complexes have become a prevalent family of catalysts enabling numerous organic transformations. Their facile synthetic access is a matter of great importance. To this end, the Cu-I-NHC transfer methodology has emerged as a powerful alternative presenting attractive advantages over other methods. Herein, we report the remarkable ability of copper to transfer not only NHCs but also other types of carbenes such as abnormal NHCs (aNHCs), cyclic (alkyl)(amino)carbenes (CAACs), and mesoionic carbenes (MICs) to various transition metal precursors.},
  author       = {Bidal, Yannick D and Santoro, Orlando and Melaimi, Mohand and Cordes, David B and Slawin, Alexandra MZ and Bertrand, Guy and Cazin, Catherine},
  issn         = {0947-6539},
  journal      = {CHEMISTRY-A EUROPEAN JOURNAL},
  keyword      = {abnormal,CAAC,carbene transfer,copper,n-heterocyclic carbene,LIGANDS SYNTHESIS,COMPLEXES,PALLADIUM,CATALYSIS,CHEMISTRY,STABILIZATION,IMIDAZOLIUM,REACTIVITY,CHROMIUM,REMOTE},
  language     = {eng},
  number       = {27},
  pages        = {9404--9409},
  title        = {Generalization of the copper to late-transition-metal transmetallation to carbenes beyond N-heterocyclic carbenes},
  url          = {http://dx.doi.org/10.1002/chem.201601254},
  volume       = {22},
  year         = {2016},
}
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