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Generalization of the copper to late-transition-metal transmetallation to carbenes beyond N-heterocyclic carbenes

Yannick D Bidal, Orlando Santoro, Mohand Melaimi, David B Cordes, Alexandra MZ Slawin, Guy Bertrand and Catherine Cazin UGent (2016) CHEMISTRY-A EUROPEAN JOURNAL. 22(27). p.9404-9409
abstract
Carbene transition-metal complexes have become a prevalent family of catalysts enabling numerous organic transformations. Their facile synthetic access is a matter of great importance. To this end, the Cu-I-NHC transfer methodology has emerged as a powerful alternative presenting attractive advantages over other methods. Herein, we report the remarkable ability of copper to transfer not only NHCs but also other types of carbenes such as abnormal NHCs (aNHCs), cyclic (alkyl)(amino)carbenes (CAACs), and mesoionic carbenes (MICs) to various transition metal precursors.
Please use this url to cite or link to this publication:
author
organization
year
type
journalArticle (original)
publication status
published
subject
keyword
abnormal, CAAC, carbene transfer, copper, n-heterocyclic carbene, LIGANDS SYNTHESIS, COMPLEXES, PALLADIUM, CATALYSIS, CHEMISTRY, STABILIZATION, IMIDAZOLIUM, REACTIVITY, CHROMIUM, REMOTE
journal title
CHEMISTRY-A EUROPEAN JOURNAL
Chem.-Eur. J.
volume
22
issue
27
pages
9404 - 9409
Web of Science type
Article
Web of Science id
000380271100050
JCR category
CHEMISTRY, MULTIDISCIPLINARY
JCR impact factor
5.317 (2016)
JCR rank
29/166 (2016)
JCR quartile
1 (2016)
ISSN
0947-6539
1521-3765
DOI
10.1002/chem.201601254
language
English
UGent publication?
no
classification
A1
id
8536970
handle
http://hdl.handle.net/1854/LU-8536970
date created
2017-11-10 14:01:07
date last changed
2018-01-29 12:12:45
@article{8536970,
  abstract     = {Carbene transition-metal complexes have become a prevalent family of catalysts enabling numerous organic transformations. Their facile synthetic access is a matter of great importance. To this end, the Cu-I-NHC transfer methodology has emerged as a powerful alternative presenting attractive advantages over other methods. Herein, we report the remarkable ability of copper to transfer not only NHCs but also other types of carbenes such as abnormal NHCs (aNHCs), cyclic (alkyl)(amino)carbenes (CAACs), and mesoionic carbenes (MICs) to various transition metal precursors.},
  author       = {Bidal, Yannick D and Santoro, Orlando and Melaimi, Mohand and Cordes, David B and Slawin, Alexandra MZ and Bertrand, Guy and Cazin, Catherine},
  issn         = {0947-6539},
  journal      = {CHEMISTRY-A EUROPEAN JOURNAL},
  keyword      = {abnormal,CAAC,carbene transfer,copper,n-heterocyclic carbene,LIGANDS SYNTHESIS,COMPLEXES,PALLADIUM,CATALYSIS,CHEMISTRY,STABILIZATION,IMIDAZOLIUM,REACTIVITY,CHROMIUM,REMOTE},
  language     = {eng},
  number       = {27},
  pages        = {9404--9409},
  title        = {Generalization of the copper to late-transition-metal transmetallation to carbenes beyond N-heterocyclic carbenes},
  url          = {http://dx.doi.org/10.1002/chem.201601254},
  volume       = {22},
  year         = {2016},
}

Chicago
Bidal, Yannick D, Orlando Santoro, Mohand Melaimi, David B Cordes, Alexandra MZ Slawin, Guy Bertrand, and Catherine Cazin. 2016. “Generalization of the Copper to Late-transition-metal Transmetallation to Carbenes Beyond N-heterocyclic Carbenes.” Chemistry-a European Journal 22 (27): 9404–9409.
APA
Bidal, Y. D., Santoro, O., Melaimi, M., Cordes, D. B., Slawin, A. M., Bertrand, G., & Cazin, C. (2016). Generalization of the copper to late-transition-metal transmetallation to carbenes beyond N-heterocyclic carbenes. CHEMISTRY-A EUROPEAN JOURNAL, 22(27), 9404–9409.
Vancouver
1.
Bidal YD, Santoro O, Melaimi M, Cordes DB, Slawin AM, Bertrand G, et al. Generalization of the copper to late-transition-metal transmetallation to carbenes beyond N-heterocyclic carbenes. CHEMISTRY-A EUROPEAN JOURNAL. 2016;22(27):9404–9.
MLA
Bidal, Yannick D, Orlando Santoro, Mohand Melaimi, et al. “Generalization of the Copper to Late-transition-metal Transmetallation to Carbenes Beyond N-heterocyclic Carbenes.” CHEMISTRY-A EUROPEAN JOURNAL 22.27 (2016): 9404–9409. Print.