A simple access to transition metal cyclopropenylidene complexes
- Author
- Yannick D Bidal, Mathieu Lesieur, Mohand Melaimi, David B Cordes, Alexandra MZ Slawin, Guy Bertrand and Catherine Cazin (UGent)
- Organization
- Abstract
- We report the first example of BAC-Cu complex (BAC = bis-(diisopropylamino)cyclopropenylidene) and its use as a carbene-transfer reagent, allowing access to Au-, Pd-, Ir- and Rh-BAC compounds. Catalytic experiments show the high activity of the [CuCl(BAC)] complex in Click chemistry.
- Keywords
- N-HETEROCYCLIC CARBENE, COUPLING CATALYSIS, 3+2 CYCLOADDITION, ROOM-TEMPERATURE, TERMINAL ALKYNES, LIGANDS, DIAMINOCYCLOPROPENYLIDENE, EFFICIENT, SYSTEMS, TRANSMETALATION
Citation
Please use this url to cite or link to this publication: http://hdl.handle.net/1854/LU-8536963
- MLA
- Bidal, Yannick D., et al. “A Simple Access to Transition Metal Cyclopropenylidene Complexes.” CHEMICAL COMMUNICATIONS, vol. 51, no. 23, 2015, pp. 4778–81.
- APA
- Bidal, Y. D., Lesieur, M., Melaimi, M., Cordes, D. B., Slawin, A. M., Bertrand, G., & Cazin, C. (2015). A simple access to transition metal cyclopropenylidene complexes. CHEMICAL COMMUNICATIONS, 51(23), 4778–4781.
- Chicago author-date
- Bidal, Yannick D, Mathieu Lesieur, Mohand Melaimi, David B Cordes, Alexandra MZ Slawin, Guy Bertrand, and Catherine Cazin. 2015. “A Simple Access to Transition Metal Cyclopropenylidene Complexes.” CHEMICAL COMMUNICATIONS 51 (23): 4778–81.
- Chicago author-date (all authors)
- Bidal, Yannick D, Mathieu Lesieur, Mohand Melaimi, David B Cordes, Alexandra MZ Slawin, Guy Bertrand, and Catherine Cazin. 2015. “A Simple Access to Transition Metal Cyclopropenylidene Complexes.” CHEMICAL COMMUNICATIONS 51 (23): 4778–4781.
- Vancouver
- 1.Bidal YD, Lesieur M, Melaimi M, Cordes DB, Slawin AM, Bertrand G, et al. A simple access to transition metal cyclopropenylidene complexes. CHEMICAL COMMUNICATIONS. 2015;51(23):4778–81.
- IEEE
- [1]Y. D. Bidal et al., “A simple access to transition metal cyclopropenylidene complexes,” CHEMICAL COMMUNICATIONS, vol. 51, no. 23, pp. 4778–4781, 2015.
@article{8536963,
abstract = {We report the first example of BAC-Cu complex (BAC = bis-(diisopropylamino)cyclopropenylidene) and its use as a carbene-transfer reagent, allowing access to Au-, Pd-, Ir- and Rh-BAC compounds. Catalytic experiments show the high activity of the [CuCl(BAC)] complex in Click chemistry.},
author = {Bidal, Yannick D and Lesieur, Mathieu and Melaimi, Mohand and Cordes, David B and Slawin, Alexandra MZ and Bertrand, Guy and Cazin, Catherine},
issn = {1359-7345},
journal = {CHEMICAL COMMUNICATIONS},
keywords = {N-HETEROCYCLIC CARBENE,COUPLING CATALYSIS,3+2 CYCLOADDITION,ROOM-TEMPERATURE,TERMINAL ALKYNES,LIGANDS,DIAMINOCYCLOPROPENYLIDENE,EFFICIENT,SYSTEMS,TRANSMETALATION},
language = {eng},
number = {23},
pages = {4778--4781},
title = {A simple access to transition metal cyclopropenylidene complexes},
url = {http://dx.doi.org/10.1039/c4cc10375k},
volume = {51},
year = {2015},
}
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