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N-heterocyclic carbene copper(I) catalysed N-methylation of amines using CO2

(2015) DALTON TRANSACTIONS. 44(41). p.18138-18144
Author
Organization
Abstract
The N-methylation of amines using CO2 and PhSiH3 as source of CH3 was efficiently performed using a N-heterocyclic carbene copper(I) complex. The methodology was found compatible with aromatic and aliphatic primary and secondary amines. Synthetic and computational studies have been carried out to support the proposed reaction mechanism for this transformation.
Keywords
CARBON-DIOXIDE, DIMETHYL CARBONATE, AROMATIC-AMINES, CHEMOSELECTIVE METHYLATION, FUNCTIONALIZED ANILINES, REDUCTIVE METHYLATION, ZINC BOROHYDRIDE, MESSENGER-RNA, FORMIC-ACID, BASIS-SETS

Citation

Please use this url to cite or link to this publication:

MLA
Santoro, Orlando, et al. “N-Heterocyclic Carbene Copper(I) Catalysed N-Methylation of Amines Using CO2.” DALTON TRANSACTIONS, vol. 44, no. 41, 2015, pp. 18138–44.
APA
Santoro, O., Lazreg, F., Minenkov, Y., Cavallo, L., & Cazin, C. (2015). N-heterocyclic carbene copper(I) catalysed N-methylation of amines using CO2. DALTON TRANSACTIONS, 44(41), 18138–18144.
Chicago author-date
Santoro, Orlando, Faima Lazreg, Yury Minenkov, Luigi Cavallo, and Catherine Cazin. 2015. “N-Heterocyclic Carbene Copper(I) Catalysed N-Methylation of Amines Using CO2.” DALTON TRANSACTIONS 44 (41): 18138–44.
Chicago author-date (all authors)
Santoro, Orlando, Faima Lazreg, Yury Minenkov, Luigi Cavallo, and Catherine Cazin. 2015. “N-Heterocyclic Carbene Copper(I) Catalysed N-Methylation of Amines Using CO2.” DALTON TRANSACTIONS 44 (41): 18138–18144.
Vancouver
1.
Santoro O, Lazreg F, Minenkov Y, Cavallo L, Cazin C. N-heterocyclic carbene copper(I) catalysed N-methylation of amines using CO2. DALTON TRANSACTIONS. 2015;44(41):18138–44.
IEEE
[1]
O. Santoro, F. Lazreg, Y. Minenkov, L. Cavallo, and C. Cazin, “N-heterocyclic carbene copper(I) catalysed N-methylation of amines using CO2,” DALTON TRANSACTIONS, vol. 44, no. 41, pp. 18138–18144, 2015.
@article{8536959,
  abstract     = {The N-methylation of amines using CO2 and PhSiH3 as source of CH3 was efficiently performed using a N-heterocyclic carbene copper(I) complex. The methodology was found compatible with aromatic and aliphatic primary and secondary amines. Synthetic and computational studies have been carried out to support the proposed reaction mechanism for this transformation.},
  author       = {Santoro, Orlando and Lazreg, Faima and Minenkov, Yury and Cavallo, Luigi and Cazin, Catherine},
  issn         = {1477-9226},
  journal      = {DALTON TRANSACTIONS},
  keywords     = {CARBON-DIOXIDE,DIMETHYL CARBONATE,AROMATIC-AMINES,CHEMOSELECTIVE METHYLATION,FUNCTIONALIZED ANILINES,REDUCTIVE METHYLATION,ZINC BOROHYDRIDE,MESSENGER-RNA,FORMIC-ACID,BASIS-SETS},
  language     = {eng},
  number       = {41},
  pages        = {18138--18144},
  title        = {N-heterocyclic carbene copper(I) catalysed N-methylation of amines using CO2},
  url          = {http://dx.doi.org/10.1039/c5dt03506f},
  volume       = {44},
  year         = {2015},
}

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