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Synthesis of homoleptic and heteroleptic bis-N-heterocylic carbene group 11 complexes

(2015) ORGANOMETALLICS. 34(2). p.419-425
Author
Organization
Abstract
A straightforward synthetic route has been developed permitting the formation of homoleptic and heteroleptic bis-N-heterocyclic carbene metal complexes. The methodology has proven efficient for all group 11 members. These complexes are easily synthesized using [M(Cl)(NHC)] with different NHC salts in the presence of inexpensive bases such as sodium hydroxide. These systems were fully characterized and displayed high stability even in the presence of light.
Keywords
COPPER(I) COMPLEXES, GOLD COMPLEXES, LIGANDS, CATALYSIS, SILVER(I), METAL, HYDROSILYLATION, CHEMISTRY, PHOSPHINE, NHC

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Chicago
Lazreg, Faima, David B Cordes, Alexandra MZ Slawin, and Catherine Cazin. 2015. “Synthesis of Homoleptic and Heteroleptic bis-N-heterocylic Carbene Group 11 Complexes.” Organometallics 34 (2): 419–425.
APA
Lazreg, Faima, Cordes, D. B., Slawin, A. M., & Cazin, C. (2015). Synthesis of homoleptic and heteroleptic bis-N-heterocylic carbene group 11 complexes. ORGANOMETALLICS, 34(2), 419–425.
Vancouver
1.
Lazreg F, Cordes DB, Slawin AM, Cazin C. Synthesis of homoleptic and heteroleptic bis-N-heterocylic carbene group 11 complexes. ORGANOMETALLICS. 2015;34(2):419–25.
MLA
Lazreg, Faima, David B Cordes, Alexandra MZ Slawin, et al. “Synthesis of Homoleptic and Heteroleptic bis-N-heterocylic Carbene Group 11 Complexes.” ORGANOMETALLICS 34.2 (2015): 419–425. Print.
@article{8536958,
  abstract     = {A straightforward synthetic route has been developed permitting the formation of homoleptic and heteroleptic bis-N-heterocyclic carbene metal complexes. The methodology has proven efficient for all group 11 members. These complexes are easily synthesized using [M(Cl)(NHC)] with different NHC salts in the presence of inexpensive bases such as sodium hydroxide. These systems were fully characterized and displayed high stability even in the presence of light.},
  author       = {Lazreg, Faima and Cordes, David B and Slawin, Alexandra MZ and Cazin, Catherine},
  issn         = {0276-7333},
  journal      = {ORGANOMETALLICS},
  keyword      = {COPPER(I) COMPLEXES,GOLD COMPLEXES,LIGANDS,CATALYSIS,SILVER(I),METAL,HYDROSILYLATION,CHEMISTRY,PHOSPHINE,NHC},
  language     = {eng},
  number       = {2},
  pages        = {419--425},
  title        = {Synthesis of homoleptic and heteroleptic bis-N-heterocylic carbene group 11 complexes},
  url          = {http://dx.doi.org/10.1021/om500882t},
  volume       = {34},
  year         = {2015},
}

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