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Phosphite ligands in Ru-based olefin metathesis catalysts

Xavier Bantreil and Catherine Cazin (UGent)
(2015) MONATSHEFTE FUR CHEMIE. 146(7). p.1043-1052
Author
Organization
Abstract
In this short review, we focus on the synthesis and applications of new phosphite-bearing ruthenium complexes in olefin metathesis. These complexes were designed to take advantage of a known synergistic effect between strong sigma-donating NHC ligands and pi-acidic phosphites. The resulting catalysts display higher stability compared to their phosphine-containing congeners. A comparative summary of their use in ring-closing metathesis, cross metathesis, and ring-opening metathesis polymerization, as well as DFT calculations describing our mechanistic understanding, are presented.
Keywords
Phosphite, Metal complexes, Metathesis, Coordination chemistry, RING-CLOSING METATHESIS, RUTHENIUM-INDENYLIDENE COMPLEXES, N-HETEROCYCLIC CARBENE, NOBEL LECTURE 2005, DEMANDING NHC LIGAND, POLYMERIZATION ROMP, SINGLE-COMPONENT, ARYL CHLORIDES, EFFICIENT, METAL

Citation

Please use this url to cite or link to this publication:

MLA
Bantreil, Xavier, and Catherine Cazin. “Phosphite Ligands in Ru-Based Olefin Metathesis Catalysts.” MONATSHEFTE FUR CHEMIE, vol. 146, no. 7, 2015, pp. 1043–52, doi:10.1007/s00706-015-1487-7.
APA
Bantreil, X., & Cazin, C. (2015). Phosphite ligands in Ru-based olefin metathesis catalysts. MONATSHEFTE FUR CHEMIE, 146(7), 1043–1052. https://doi.org/10.1007/s00706-015-1487-7
Chicago author-date
Bantreil, Xavier, and Catherine Cazin. 2015. “Phosphite Ligands in Ru-Based Olefin Metathesis Catalysts.” MONATSHEFTE FUR CHEMIE 146 (7): 1043–52. https://doi.org/10.1007/s00706-015-1487-7.
Chicago author-date (all authors)
Bantreil, Xavier, and Catherine Cazin. 2015. “Phosphite Ligands in Ru-Based Olefin Metathesis Catalysts.” MONATSHEFTE FUR CHEMIE 146 (7): 1043–1052. doi:10.1007/s00706-015-1487-7.
Vancouver
1.
Bantreil X, Cazin C. Phosphite ligands in Ru-based olefin metathesis catalysts. MONATSHEFTE FUR CHEMIE. 2015;146(7):1043–52.
IEEE
[1]
X. Bantreil and C. Cazin, “Phosphite ligands in Ru-based olefin metathesis catalysts,” MONATSHEFTE FUR CHEMIE, vol. 146, no. 7, pp. 1043–1052, 2015.
@article{8536955,
  abstract     = {{In this short review, we focus on the synthesis and applications of new phosphite-bearing ruthenium complexes in olefin metathesis. These complexes were designed to take advantage of a known synergistic effect between strong sigma-donating NHC ligands and pi-acidic phosphites. The resulting catalysts display higher stability compared to their phosphine-containing congeners. A comparative summary of their use in ring-closing metathesis, cross metathesis, and ring-opening metathesis polymerization, as well as DFT calculations describing our mechanistic understanding, are presented.}},
  author       = {{Bantreil, Xavier and Cazin, Catherine}},
  issn         = {{0026-9247}},
  journal      = {{MONATSHEFTE FUR CHEMIE}},
  keywords     = {{Phosphite,Metal complexes,Metathesis,Coordination chemistry,RING-CLOSING METATHESIS,RUTHENIUM-INDENYLIDENE COMPLEXES,N-HETEROCYCLIC CARBENE,NOBEL LECTURE 2005,DEMANDING NHC LIGAND,POLYMERIZATION ROMP,SINGLE-COMPONENT,ARYL CHLORIDES,EFFICIENT,METAL}},
  language     = {{eng}},
  number       = {{7}},
  pages        = {{1043--1052}},
  title        = {{Phosphite ligands in Ru-based olefin metathesis catalysts}},
  url          = {{http://dx.doi.org/10.1007/s00706-015-1487-7}},
  volume       = {{146}},
  year         = {{2015}},
}
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