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[Pd(NHC)(PR3)] (NHC = N-heterocyclic carbene) catalysed alcohol oxidation using molecular oxygen

(2012) DALTON TRANSACTIONS. 41(40). p.12619-12623
Author
Organization
Abstract
A series of [Pd(NHC)(PR3)] complexes quantitatively form [Pd(eta(2)-O-2)(NHC)(PR3)] products when submitted to an dioxygen atmosphere. Synthetic details and structural features of these Pd-peroxo complexes are described. The palladium compounds were found to be efficient catalysts in the oxidation of alcohols into corresponding carbonyl compounds using O-2 or air as oxidant. Reactions proceed at low catalyst loadings with a wide range of alcohols.
Keywords
AEROBIC OXIDATION, PALLADIUM(II)-CATALYZED OXIDATION, COORDINATED PALLADIUM(0), ORGANIC-CHEMICALS, COMPLEXES, DIOXYGEN, O-2, LIGANDS, KETONES

Citation

Please use this url to cite or link to this publication:

MLA
Jurcik, Vaclav, et al. “[Pd(NHC)(PR3)] (NHC = N-Heterocyclic Carbene) Catalysed Alcohol Oxidation Using Molecular Oxygen.” DALTON TRANSACTIONS, vol. 41, no. 40, 2012, pp. 12619–23.
APA
Jurcik, V., Schmid, T. E., Dumont, Q., Slawin, A. M., & Cazin, C. (2012). [Pd(NHC)(PR3)] (NHC = N-heterocyclic carbene) catalysed alcohol oxidation using molecular oxygen. DALTON TRANSACTIONS, 41(40), 12619–12623.
Chicago author-date
Jurcik, Vaclav, Thibault E Schmid, Quentin Dumont, Alexandra MZ Slawin, and Catherine Cazin. 2012. “[Pd(NHC)(PR3)] (NHC = N-Heterocyclic Carbene) Catalysed Alcohol Oxidation Using Molecular Oxygen.” DALTON TRANSACTIONS 41 (40): 12619–23.
Chicago author-date (all authors)
Jurcik, Vaclav, Thibault E Schmid, Quentin Dumont, Alexandra MZ Slawin, and Catherine Cazin. 2012. “[Pd(NHC)(PR3)] (NHC = N-Heterocyclic Carbene) Catalysed Alcohol Oxidation Using Molecular Oxygen.” DALTON TRANSACTIONS 41 (40): 12619–12623.
Vancouver
1.
Jurcik V, Schmid TE, Dumont Q, Slawin AM, Cazin C. [Pd(NHC)(PR3)] (NHC = N-heterocyclic carbene) catalysed alcohol oxidation using molecular oxygen. DALTON TRANSACTIONS. 2012;41(40):12619–23.
IEEE
[1]
V. Jurcik, T. E. Schmid, Q. Dumont, A. M. Slawin, and C. Cazin, “[Pd(NHC)(PR3)] (NHC = N-heterocyclic carbene) catalysed alcohol oxidation using molecular oxygen,” DALTON TRANSACTIONS, vol. 41, no. 40, pp. 12619–12623, 2012.
@article{8536935,
  abstract     = {A series of [Pd(NHC)(PR3)] complexes quantitatively form [Pd(eta(2)-O-2)(NHC)(PR3)] products when submitted to an dioxygen atmosphere. Synthetic details and structural features of these Pd-peroxo complexes are described. The palladium compounds were found to be efficient catalysts in the oxidation of alcohols into corresponding carbonyl compounds using O-2 or air as oxidant. Reactions proceed at low catalyst loadings with a wide range of alcohols.},
  author       = {Jurcik, Vaclav and Schmid, Thibault E and Dumont, Quentin and Slawin, Alexandra MZ and Cazin, Catherine},
  issn         = {1477-9226},
  journal      = {DALTON TRANSACTIONS},
  keywords     = {AEROBIC OXIDATION,PALLADIUM(II)-CATALYZED OXIDATION,COORDINATED PALLADIUM(0),ORGANIC-CHEMICALS,COMPLEXES,DIOXYGEN,O-2,LIGANDS,KETONES},
  language     = {eng},
  number       = {40},
  pages        = {12619--12623},
  title        = {[Pd(NHC)(PR3)] (NHC = N-heterocyclic carbene) catalysed alcohol oxidation using molecular oxygen},
  url          = {http://dx.doi.org/10.1039/c2dt30133d},
  volume       = {41},
  year         = {2012},
}

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