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Gold-N-heterocyclic carbene complexes of mineral acids

Marcel Brill, Fady Nahra UGent, Alberto Gomez-Herrera, Caroline Zinser, David B Cordes, Alexandra MZ Slawin and Steven Nolan UGent (2017) CHEMCATCHEM. 9(1). p.117-120
abstract
We have synthesized and characterized new gold-N-heterocyclic carbene (NHC) complexes derived from the deprotonation of mineral acids. The use of sulfuric acid was a particularly interesting case. These complexes were tested in known gold-catalyzed reactions, such as the hydration of alkynes and the Meyer-Schuster rearrangement. They proved to be highly efficient in both reactions.
Please use this url to cite or link to this publication:
author
organization
year
type
journalArticle (original)
publication status
published
subject
keyword
MEYER-SCHUSTER REARRANGEMENT, ONE-POT SYNTHESIS, MECHANISTIC INSIGHTS, SILVER-FREE, CATALYSIS, ALKYNES, COUNTERION, HYDRATION, REACTIVITY, ALCOHOLS
journal title
CHEMCATCHEM
ChemCatChem
volume
9
issue
1
pages
117 - 120
Web of Science type
Article
Web of Science id
000395797000019
ISSN
1867-3880
1867-3899
DOI
10.1002/cctc.201601290
language
English
UGent publication?
yes
classification
A1
additional info
the first two authors contributed equally to this work
copyright statement
I have transferred the copyright for this publication to the publisher
id
8536747
handle
http://hdl.handle.net/1854/LU-8536747
date created
2017-11-09 11:49:28
date last changed
2017-12-05 14:50:55
@article{8536747,
  abstract     = {We have synthesized and characterized new gold-N-heterocyclic carbene (NHC) complexes derived from the deprotonation of mineral acids. The use of sulfuric acid was a particularly interesting case. These complexes were tested in known gold-catalyzed reactions, such as the hydration of alkynes and the Meyer-Schuster rearrangement. They proved to be highly efficient in both reactions.},
  author       = {Brill, Marcel and Nahra, Fady and Gomez-Herrera, Alberto and Zinser, Caroline and Cordes, David B and Slawin, Alexandra MZ and Nolan, Steven},
  issn         = {1867-3880},
  journal      = {CHEMCATCHEM},
  keyword      = {MEYER-SCHUSTER REARRANGEMENT,ONE-POT SYNTHESIS,MECHANISTIC INSIGHTS,SILVER-FREE,CATALYSIS,ALKYNES,COUNTERION,HYDRATION,REACTIVITY,ALCOHOLS},
  language     = {eng},
  number       = {1},
  pages        = {117--120},
  title        = {Gold-N-heterocyclic carbene complexes of mineral acids},
  url          = {http://dx.doi.org/10.1002/cctc.201601290},
  volume       = {9},
  year         = {2017},
}

Chicago
Brill, Marcel, Fady Nahra, Alberto Gomez-Herrera, Caroline Zinser, David B Cordes, Alexandra MZ Slawin, and Steven Nolan. 2017. “Gold-N-heterocyclic Carbene Complexes of Mineral Acids.” Chemcatchem 9 (1): 117–120.
APA
Brill, M., Nahra, F., Gomez-Herrera, A., Zinser, C., Cordes, D. B., Slawin, A. M., & Nolan, S. (2017). Gold-N-heterocyclic carbene complexes of mineral acids. CHEMCATCHEM, 9(1), 117–120.
Vancouver
1.
Brill M, Nahra F, Gomez-Herrera A, Zinser C, Cordes DB, Slawin AM, et al. Gold-N-heterocyclic carbene complexes of mineral acids. CHEMCATCHEM. 2017;9(1):117–20.
MLA
Brill, Marcel, Fady Nahra, Alberto Gomez-Herrera, et al. “Gold-N-heterocyclic Carbene Complexes of Mineral Acids.” CHEMCATCHEM 9.1 (2017): 117–120. Print.