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Gold-N-heterocyclic carbene complexes of mineral acids

(2017) CHEMCATCHEM. 9(1). p.117-120
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Abstract
We have synthesized and characterized new gold-N-heterocyclic carbene (NHC) complexes derived from the deprotonation of mineral acids. The use of sulfuric acid was a particularly interesting case. These complexes were tested in known gold-catalyzed reactions, such as the hydration of alkynes and the Meyer-Schuster rearrangement. They proved to be highly efficient in both reactions.
Keywords
MEYER-SCHUSTER REARRANGEMENT, ONE-POT SYNTHESIS, MECHANISTIC INSIGHTS, SILVER-FREE, CATALYSIS, ALKYNES, COUNTERION, HYDRATION, REACTIVITY, ALCOHOLS

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Citation

Please use this url to cite or link to this publication:

MLA
Brill, Marcel, et al. “Gold-N-Heterocyclic Carbene Complexes of Mineral Acids.” CHEMCATCHEM, vol. 9, no. 1, 2017, pp. 117–20, doi:10.1002/cctc.201601290.
APA
Brill, M., Nahra, F., Gomez-Herrera, A., Zinser, C., Cordes, D. B., Slawin, A. M., & Nolan, S. (2017). Gold-N-heterocyclic carbene complexes of mineral acids. CHEMCATCHEM, 9(1), 117–120. https://doi.org/10.1002/cctc.201601290
Chicago author-date
Brill, Marcel, Fady Nahra, Alberto Gomez-Herrera, Caroline Zinser, David B Cordes, Alexandra MZ Slawin, and Steven Nolan. 2017. “Gold-N-Heterocyclic Carbene Complexes of Mineral Acids.” CHEMCATCHEM 9 (1): 117–20. https://doi.org/10.1002/cctc.201601290.
Chicago author-date (all authors)
Brill, Marcel, Fady Nahra, Alberto Gomez-Herrera, Caroline Zinser, David B Cordes, Alexandra MZ Slawin, and Steven Nolan. 2017. “Gold-N-Heterocyclic Carbene Complexes of Mineral Acids.” CHEMCATCHEM 9 (1): 117–120. doi:10.1002/cctc.201601290.
Vancouver
1.
Brill M, Nahra F, Gomez-Herrera A, Zinser C, Cordes DB, Slawin AM, et al. Gold-N-heterocyclic carbene complexes of mineral acids. CHEMCATCHEM. 2017;9(1):117–20.
IEEE
[1]
M. Brill et al., “Gold-N-heterocyclic carbene complexes of mineral acids,” CHEMCATCHEM, vol. 9, no. 1, pp. 117–120, 2017.
@article{8536747,
  abstract     = {{We have synthesized and characterized new gold-N-heterocyclic carbene (NHC) complexes derived from the deprotonation of mineral acids. The use of sulfuric acid was a particularly interesting case. These complexes were tested in known gold-catalyzed reactions, such as the hydration of alkynes and the Meyer-Schuster rearrangement. They proved to be highly efficient in both reactions.}},
  author       = {{Brill, Marcel and Nahra, Fady and Gomez-Herrera, Alberto and Zinser, Caroline and Cordes, David B and Slawin, Alexandra MZ and Nolan, Steven}},
  issn         = {{1867-3880}},
  journal      = {{CHEMCATCHEM}},
  keywords     = {{MEYER-SCHUSTER REARRANGEMENT,ONE-POT SYNTHESIS,MECHANISTIC INSIGHTS,SILVER-FREE,CATALYSIS,ALKYNES,COUNTERION,HYDRATION,REACTIVITY,ALCOHOLS}},
  language     = {{eng}},
  number       = {{1}},
  pages        = {{117--120}},
  title        = {{Gold-N-heterocyclic carbene complexes of mineral acids}},
  url          = {{http://dx.doi.org/10.1002/cctc.201601290}},
  volume       = {{9}},
  year         = {{2017}},
}

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