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Metal-organic and covalent organic frameworks as single-site catalysts

(2017) CHEMICAL SOCIETY REVIEWS. 46(11). p.3134-3184
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Abstract
Heterogeneous single-site catalysts consist of isolated, well-defined, active sites that are spatially separated in a given solid and, ideally, structurally identical. In this review, the potential of metal-organic frameworks (MOFs) and covalent organic frameworks (COFs) as platforms for the development of heterogeneous single-site catalysts is reviewed thoroughly. In the first part of this article, synthetic strategies and progress in the implementation of such sites in these two classes of materials are discussed. Because these solids are excellent playgrounds to allow a better understanding of catalytic functions, we highlight the most important recent advances in the modelling and spectroscopic characterization of single-site catalysts based on these materials. Finally, we discuss the potential of MOFs as materials in which several single-site catalytic functions can be combined within one framework along with their potential as powerful enzyme-mimicking materials. The review is wrapped up with our personal vision on future research directions.
Keywords
CONJUGATED MICROPOROUS POLYMER, COORDINATIVELY UNSATURATED SITES, QUATERNARY AMMONIUM-SALTS, DENSITY-FUNCTIONAL THEORY, TRIAZINE-BASED FRAMEWORKS, LOW-TEMPERATURE OXIDATION, TOTAL-ENERGY CALCULATIONS, CHEMICAL WARFARE AGENTS, LEWIS-ACID CATALYSIS, HIGH-SURFACE-AREA

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Chicago
Rogge, Sven, A Bavykina, Julianna Hajek, H Garcia, AI Olivos-Suarez, A Sepulveda-Escribano, A Vimont, et al. 2017. “Metal-organic and Covalent Organic Frameworks as Single-site Catalysts.” Chemical Society Reviews 46 (11): 3134–3184.
APA
Rogge, S., Bavykina, A., Hajek, J., Garcia, H., Olivos-Suarez, A., Sepulveda-Escribano, A., Vimont, A., et al. (2017). Metal-organic and covalent organic frameworks as single-site catalysts. CHEMICAL SOCIETY REVIEWS, 46(11), 3134–3184.
Vancouver
1.
Rogge S, Bavykina A, Hajek J, Garcia H, Olivos-Suarez A, Sepulveda-Escribano A, et al. Metal-organic and covalent organic frameworks as single-site catalysts. CHEMICAL SOCIETY REVIEWS. CAMBS, ENGLAND: ROYAL SOC CHEMISTRY; 2017;46(11):3134–84.
MLA
Rogge, Sven, A Bavykina, Julianna Hajek, et al. “Metal-organic and Covalent Organic Frameworks as Single-site Catalysts.” CHEMICAL SOCIETY REVIEWS 46.11 (2017): 3134–3184. Print.
@article{8531609,
  abstract     = {Heterogeneous single-site catalysts consist of isolated, well-defined, active sites that are spatially separated in a given solid and, ideally, structurally identical. In this review, the potential of metal-organic frameworks (MOFs) and covalent organic frameworks (COFs) as platforms for the development of heterogeneous single-site catalysts is reviewed thoroughly. In the first part of this article, synthetic strategies and progress in the implementation of such sites in these two classes of materials are discussed. Because these solids are excellent playgrounds to allow a better understanding of catalytic functions, we highlight the most important recent advances in the modelling and spectroscopic characterization of single-site catalysts based on these materials. Finally, we discuss the potential of MOFs as materials in which several single-site catalytic functions can be combined within one framework along with their potential as powerful enzyme-mimicking materials. The review is wrapped up with our personal vision on future research directions.},
  author       = {Rogge, Sven and Bavykina, A and Hajek, Julianna and Garcia, H and Olivos-Suarez,  AI and Sepulveda-Escribano, A and Vimont, A and Clet, G and Bazin, P and Kapteijn, F and Daturi, M and Ramos-Fernandez, EV and Llabres i Xamena, FX and Van Speybroeck, Veronique and Gascon, J},
  issn         = {0306-0012},
  journal      = {CHEMICAL SOCIETY REVIEWS},
  keyword      = {CONJUGATED MICROPOROUS POLYMER,COORDINATIVELY UNSATURATED SITES,QUATERNARY AMMONIUM-SALTS,DENSITY-FUNCTIONAL THEORY,TRIAZINE-BASED FRAMEWORKS,LOW-TEMPERATURE OXIDATION,TOTAL-ENERGY CALCULATIONS,CHEMICAL WARFARE AGENTS,LEWIS-ACID CATALYSIS,HIGH-SURFACE-AREA},
  language     = {eng},
  number       = {11},
  pages        = {3134--3184},
  publisher    = {ROYAL SOC CHEMISTRY},
  title        = {Metal-organic and covalent organic frameworks as single-site catalysts},
  url          = {http://dx.doi.org/10.1039/c7cs00033b},
  volume       = {46},
  year         = {2017},
}

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