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Metal-organic and covalent organic frameworks as single-site catalysts

Sven Rogge UGent, A Bavykina, Julianna Hajek UGent, H Garcia, AI Olivos-Suarez, A Sepulveda-Escribano, A Vimont, G Clet, P Bazin, F Kapteijn, et al. (2017) CHEMICAL SOCIETY REVIEWS. 46(11). p.3134-3184
abstract
Heterogeneous single-site catalysts consist of isolated, well-defined, active sites that are spatially separated in a given solid and, ideally, structurally identical. In this review, the potential of metal-organic frameworks (MOFs) and covalent organic frameworks (COFs) as platforms for the development of heterogeneous single-site catalysts is reviewed thoroughly. In the first part of this article, synthetic strategies and progress in the implementation of such sites in these two classes of materials are discussed. Because these solids are excellent playgrounds to allow a better understanding of catalytic functions, we highlight the most important recent advances in the modelling and spectroscopic characterization of single-site catalysts based on these materials. Finally, we discuss the potential of MOFs as materials in which several single-site catalytic functions can be combined within one framework along with their potential as powerful enzyme-mimicking materials. The review is wrapped up with our personal vision on future research directions.
Please use this url to cite or link to this publication:
author
organization
year
type
journalArticle (review)
publication status
published
subject
keyword
CONJUGATED MICROPOROUS POLYMER, COORDINATIVELY UNSATURATED SITES, QUATERNARY AMMONIUM-SALTS, DENSITY-FUNCTIONAL THEORY, TRIAZINE-BASED FRAMEWORKS, LOW-TEMPERATURE OXIDATION, TOTAL-ENERGY CALCULATIONS, CHEMICAL WARFARE AGENTS, LEWIS-ACID CATALYSIS, HIGH-SURFACE-AREA
journal title
CHEMICAL SOCIETY REVIEWS
volume
46
issue
11
pages
3134 - 3184
publisher
ROYAL SOC CHEMISTRY
place of publication
CAMBS, ENGLAND
Web of Science type
Review
Web of Science id
000402730200003
ISSN
0306-0012
1460-4744
DOI
10.1039/c7cs00033b
language
English
UGent publication?
yes
classification
A1
copyright statement
Creative Commons Attribution 4.0 International Public License (CC-BY 4.0)
id
8531609
handle
http://hdl.handle.net/1854/LU-8531609
date created
2017-09-19 08:16:40
date last changed
2017-09-22 09:47:06
@article{8531609,
  abstract     = {Heterogeneous single-site catalysts consist of isolated, well-defined, active sites that are spatially separated in a given solid and, ideally, structurally identical. In this review, the potential of metal-organic frameworks (MOFs) and covalent organic frameworks (COFs) as platforms for the development of heterogeneous single-site catalysts is reviewed thoroughly. In the first part of this article, synthetic strategies and progress in the implementation of such sites in these two classes of materials are discussed. Because these solids are excellent playgrounds to allow a better understanding of catalytic functions, we highlight the most important recent advances in the modelling and spectroscopic characterization of single-site catalysts based on these materials. Finally, we discuss the potential of MOFs as materials in which several single-site catalytic functions can be combined within one framework along with their potential as powerful enzyme-mimicking materials. The review is wrapped up with our personal vision on future research directions.},
  author       = {Rogge, Sven and Bavykina, A and Hajek, Julianna and Garcia, H and Olivos-Suarez,  AI and Sepulveda-Escribano, A and Vimont, A and Clet, G and Bazin, P and Kapteijn, F and Daturi, M and Ramos-Fernandez, EV and Llabres i Xamena, FX and Van Speybroeck, Veronique and Gascon, J},
  issn         = {0306-0012},
  journal      = {CHEMICAL SOCIETY REVIEWS},
  keyword      = {CONJUGATED MICROPOROUS POLYMER,COORDINATIVELY UNSATURATED SITES,QUATERNARY AMMONIUM-SALTS,DENSITY-FUNCTIONAL THEORY,TRIAZINE-BASED FRAMEWORKS,LOW-TEMPERATURE OXIDATION,TOTAL-ENERGY CALCULATIONS,CHEMICAL WARFARE AGENTS,LEWIS-ACID CATALYSIS,HIGH-SURFACE-AREA},
  language     = {eng},
  number       = {11},
  pages        = {3134--3184},
  publisher    = {ROYAL SOC CHEMISTRY},
  title        = {Metal-organic and covalent organic frameworks as single-site catalysts},
  url          = {http://dx.doi.org/10.1039/c7cs00033b},
  volume       = {46},
  year         = {2017},
}

Chicago
Rogge, Sven, A Bavykina, Julianna Hajek, H Garcia, AI Olivos-Suarez, A Sepulveda-Escribano, A Vimont, et al. 2017. “Metal-organic and Covalent Organic Frameworks as Single-site Catalysts.” Chemical Society Reviews 46 (11): 3134–3184.
APA
Rogge, S., Bavykina, A., Hajek, J., Garcia, H., Olivos-Suarez, A., Sepulveda-Escribano, A., Vimont, A., et al. (2017). Metal-organic and covalent organic frameworks as single-site catalysts. CHEMICAL SOCIETY REVIEWS, 46(11), 3134–3184.
Vancouver
1.
Rogge S, Bavykina A, Hajek J, Garcia H, Olivos-Suarez A, Sepulveda-Escribano A, et al. Metal-organic and covalent organic frameworks as single-site catalysts. CHEMICAL SOCIETY REVIEWS. CAMBS, ENGLAND: ROYAL SOC CHEMISTRY; 2017;46(11):3134–84.
MLA
Rogge, Sven, A Bavykina, Julianna Hajek, et al. “Metal-organic and Covalent Organic Frameworks as Single-site Catalysts.” CHEMICAL SOCIETY REVIEWS 46.11 (2017): 3134–3184. Print.