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A simple synthetic entryway into palladium cross-coupling catalysis

(2017) CHEMICAL COMMUNICATIONS. 53(57). p.7990-7993
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Abstract
The simple synthesis of a family of palladates containing an imidazolium counterion is presented. These ''ate'' complexes can be easily converted into well-defined palladium-N-heterocyclic carbene (NHC) complexes. The synthetic protocols leading to the ''ate'' and to the Pd-NHC neutral complexes have been exemplified with various NHC ligands. The palladates prove efficient pre-catalysts enabling Suzuki-Miyaura and Mizoroki-Heck reactions.
Keywords
N-HETEROCYCLIC CARBENE, ORTHO-SUBSTITUTED BIARYLS, SUZUKI-MIYAURA REACTION, ROOM-TEMPERATURE, VERSATILE PRECATALYST, (NHC)PD(ALLYL)CL NHC, BOND FORMATION, I COMPLEXES, ARYLATION, EFFICIENT

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Citation

Please use this url to cite or link to this publication:

Chicago
Zinser, Caroline M, Fady Nahra, Marcel Brill, Rebecca E Meadows, David B Cordes, Alexandra MZ Slawin, Steven Nolan, and Catherine Cazin. 2017. “A Simple Synthetic Entryway into Palladium Cross-coupling Catalysis.” Chemical Communications 53 (57): 7990–7993.
APA
Zinser, C. M., Nahra, F., Brill, M., Meadows, R. E., Cordes, D. B., Slawin, A. M., Nolan, S., et al. (2017). A simple synthetic entryway into palladium cross-coupling catalysis. CHEMICAL COMMUNICATIONS, 53(57), 7990–7993.
Vancouver
1.
Zinser CM, Nahra F, Brill M, Meadows RE, Cordes DB, Slawin AM, et al. A simple synthetic entryway into palladium cross-coupling catalysis. CHEMICAL COMMUNICATIONS. 2017;53(57):7990–3.
MLA
Zinser, Caroline M, Fady Nahra, Marcel Brill, et al. “A Simple Synthetic Entryway into Palladium Cross-coupling Catalysis.” CHEMICAL COMMUNICATIONS 53.57 (2017): 7990–7993. Print.
@article{8528488,
  abstract     = {The simple synthesis of a family of palladates containing an imidazolium counterion is presented. These ''ate'' complexes can be easily converted into well-defined palladium-N-heterocyclic carbene (NHC) complexes. The synthetic protocols leading to the ''ate'' and to the Pd-NHC neutral complexes have been exemplified with various NHC ligands. The palladates prove efficient pre-catalysts enabling Suzuki-Miyaura and Mizoroki-Heck reactions.},
  author       = {Zinser, Caroline M and Nahra, Fady and Brill, Marcel and Meadows, Rebecca E and Cordes, David B and Slawin, Alexandra MZ and Nolan, Steven and Cazin, Catherine},
  issn         = {1359-7345},
  journal      = {CHEMICAL COMMUNICATIONS},
  keyword      = {N-HETEROCYCLIC CARBENE,ORTHO-SUBSTITUTED BIARYLS,SUZUKI-MIYAURA REACTION,ROOM-TEMPERATURE,VERSATILE PRECATALYST,(NHC)PD(ALLYL)CL NHC,BOND FORMATION,I COMPLEXES,ARYLATION,EFFICIENT},
  language     = {eng},
  number       = {57},
  pages        = {7990--7993},
  title        = {A simple synthetic entryway into palladium cross-coupling catalysis},
  url          = {http://dx.doi.org/10.1039/c7cc02487h},
  volume       = {53},
  year         = {2017},
}

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