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Gold-catalyzed synthesis of 2-aryl-3-fluoropyrroles

Riccardo Surmont (UGent) , Guido Verniest (UGent) and Norbert De Kimpe (UGent)
(2009) ORGANIC LETTERS. 11(13). p.2920-2923
Author
Organization
Abstract
The gold-catalyzed cyclization and dehydrofluorination of gem-difluorohomopropargylamines provides a novel access to 2-aryl-3-fluoropyrroles. Difluorinated homopropargylamines are prepared by the addition of gem-difluoropropargyllithium reagents to arylated N-tosylimines.
Keywords
BROMODIFLUOROMETHYLACETYLENE DERIVATIVES, ALDEHYDES, EFFICIENT, DIFLUOROPROPARGYL BROMIDES, PHARMACEUTICALS, FLUORINE, MEDICINAL CHEMISTRY, INDIUM, BOND

Citation

Please use this url to cite or link to this publication:

MLA
Surmont, Riccardo, et al. “Gold-Catalyzed Synthesis of 2-Aryl-3-Fluoropyrroles.” ORGANIC LETTERS, vol. 11, no. 13, 2009, pp. 2920–23, doi:10.1021/ol900953n.
APA
Surmont, R., Verniest, G., & De Kimpe, N. (2009). Gold-catalyzed synthesis of 2-aryl-3-fluoropyrroles. ORGANIC LETTERS, 11(13), 2920–2923. https://doi.org/10.1021/ol900953n
Chicago author-date
Surmont, Riccardo, Guido Verniest, and Norbert De Kimpe. 2009. “Gold-Catalyzed Synthesis of 2-Aryl-3-Fluoropyrroles.” ORGANIC LETTERS 11 (13): 2920–23. https://doi.org/10.1021/ol900953n.
Chicago author-date (all authors)
Surmont, Riccardo, Guido Verniest, and Norbert De Kimpe. 2009. “Gold-Catalyzed Synthesis of 2-Aryl-3-Fluoropyrroles.” ORGANIC LETTERS 11 (13): 2920–2923. doi:10.1021/ol900953n.
Vancouver
1.
Surmont R, Verniest G, De Kimpe N. Gold-catalyzed synthesis of 2-aryl-3-fluoropyrroles. ORGANIC LETTERS. 2009;11(13):2920–3.
IEEE
[1]
R. Surmont, G. Verniest, and N. De Kimpe, “Gold-catalyzed synthesis of 2-aryl-3-fluoropyrroles,” ORGANIC LETTERS, vol. 11, no. 13, pp. 2920–2923, 2009.
@article{852242,
  abstract     = {{The gold-catalyzed cyclization and dehydrofluorination of gem-difluorohomopropargylamines provides a novel access to 2-aryl-3-fluoropyrroles. Difluorinated homopropargylamines are prepared by the addition of gem-difluoropropargyllithium reagents to arylated N-tosylimines.}},
  author       = {{Surmont, Riccardo and Verniest, Guido and De Kimpe, Norbert}},
  issn         = {{1523-7060}},
  journal      = {{ORGANIC LETTERS}},
  keywords     = {{BROMODIFLUOROMETHYLACETYLENE DERIVATIVES,ALDEHYDES,EFFICIENT,DIFLUOROPROPARGYL BROMIDES,PHARMACEUTICALS,FLUORINE,MEDICINAL CHEMISTRY,INDIUM,BOND}},
  language     = {{eng}},
  number       = {{13}},
  pages        = {{2920--2923}},
  title        = {{Gold-catalyzed synthesis of 2-aryl-3-fluoropyrroles}},
  url          = {{http://dx.doi.org/10.1021/ol900953n}},
  volume       = {{11}},
  year         = {{2009}},
}

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