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Homogeneously-acid catalyzed oligomerization of glycerol

(2015) GREEN CHEMISTRY. 17(8). p.4307-4314
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Abstract
Here we report the screening of various homogeneous acid catalysts in the oligomerization of glycerol at 150 degrees C. Under optimized conditions, a mixture of oligoglycerol with an average degree of oligomerization of 3.4 was obtained at a glycerol conversion of 80%. At such a conversion, the selectivity to oligoglycerols was higher than 90%. Oligoglycerols were then successfully alkylated, offering an attractive route to valuable molecules (biosurfactants or hydrotropes).
Keywords
SELECTIVE ETHERIFICATION, SUSTAINABLE PRODUCTION, MESOPOROUS CATALYSTS, REDUCTIVE ALKYLATION, ACTIVE CATALYSTS, FUEL ADDITIVES, FACILE ROUTE, TELOMERIZATION, POLYGLYCEROLS, 1, 3-BUTADIENE

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Citation

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MLA
Sayoud, N et al. “Homogeneously-acid Catalyzed Oligomerization of Glycerol.” GREEN CHEMISTRY 17.8 (2015): 4307–4314. Print.
APA
Sayoud, N., De Oliveira Vigier, K., Cucu, T., De Meulenaer, B., Fan, Z., Lai, J., Clacens, J.-M., et al. (2015). Homogeneously-acid catalyzed oligomerization of glycerol. GREEN CHEMISTRY, 17(8), 4307–4314.
Chicago author-date
Sayoud, N, K De Oliveira Vigier, Tatiana Cucu, Bruno De Meulenaer, Zhaoyu Fan, Jonathan Lai, Jean-Marc Clacens, Armin Liebens, and F Jérôme. 2015. “Homogeneously-acid Catalyzed Oligomerization of Glycerol.” Green Chemistry 17 (8): 4307–4314.
Chicago author-date (all authors)
Sayoud, N, K De Oliveira Vigier, Tatiana Cucu, Bruno De Meulenaer, Zhaoyu Fan, Jonathan Lai, Jean-Marc Clacens, Armin Liebens, and F Jérôme. 2015. “Homogeneously-acid Catalyzed Oligomerization of Glycerol.” Green Chemistry 17 (8): 4307–4314.
Vancouver
1.
Sayoud N, De Oliveira Vigier K, Cucu T, De Meulenaer B, Fan Z, Lai J, et al. Homogeneously-acid catalyzed oligomerization of glycerol. GREEN CHEMISTRY. 2015;17(8):4307–14.
IEEE
[1]
N. Sayoud et al., “Homogeneously-acid catalyzed oligomerization of glycerol,” GREEN CHEMISTRY, vol. 17, no. 8, pp. 4307–4314, 2015.
@article{8521516,
  abstract     = {Here we report the screening of various homogeneous acid catalysts in the oligomerization of glycerol at 150 degrees C. Under optimized conditions, a mixture of oligoglycerol with an average degree of oligomerization of 3.4 was obtained at a glycerol conversion of 80%. At such a conversion, the selectivity to oligoglycerols was higher than 90%. Oligoglycerols were then successfully alkylated, offering an attractive route to valuable molecules (biosurfactants or hydrotropes).},
  author       = {Sayoud, N and De Oliveira Vigier, K and Cucu, Tatiana and De Meulenaer, Bruno and Fan, Zhaoyu and Lai, Jonathan and Clacens, Jean-Marc and Liebens, Armin and Jérôme, F},
  issn         = {1463-9262},
  journal      = {GREEN CHEMISTRY},
  keywords     = {SELECTIVE ETHERIFICATION,SUSTAINABLE PRODUCTION,MESOPOROUS CATALYSTS,REDUCTIVE ALKYLATION,ACTIVE CATALYSTS,FUEL ADDITIVES,FACILE ROUTE,TELOMERIZATION,POLYGLYCEROLS,1,3-BUTADIENE},
  language     = {eng},
  number       = {8},
  pages        = {4307--4314},
  title        = {Homogeneously-acid catalyzed oligomerization of glycerol},
  url          = {http://dx.doi.org/10.1039/c5gc01020a},
  volume       = {17},
  year         = {2015},
}

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