Ghent University Academic Bibliography

Advanced

Oxidative coupling of methane : opportunities for microkinetic model-assisted process implementations

Ana Obradović UGent, Joris Thybaut UGent and Guy Marin UGent (2016) CHEMICAL ENGINEERING & TECHNOLOGY . 39(11). p.1996-2010
abstract
Oxidative coupling of methane is a low-cost alternative for ethylene production. However, its high exothermicity, complex reaction network, and low selectivity to C-2 products require more in-depth analysis for economically viable process implementation. Microkinetic modeling enables assessment of operating conditions and catalyst properties on the overall performance via elementary gas-phase and catalytic reactions. The know-how to reproduce and interpret experimental kinetic data, especially the role of highly reactive intermediate species, is crucial for correct reaction network determination. Once the catalyst descriptors, physical catalyst properties, and operating conditions are determined and optimized, next catalyst generations can be developed tailored to the process implementation.
Please use this url to cite or link to this publication:
author
organization
year
type
journalArticle (original)
publication status
published
keyword
METAL-ORGANIC FRAMEWORKS, OXYGEN MOBILITY, GAS-PHASE, COMBUSTION CHEMISTRY, CARBON-DIOXIDE, NATURAL-GAS, CATALYSTS, CONVERSION, HYDROCARBONS, SEPARATION
journal title
CHEMICAL ENGINEERING & TECHNOLOGY
volume
39
issue
11
pages
1996 - 2010
publisher
Wiley-Blackwell
Web of Science type
Article
JCR category
ENGINEERING, CHEMICAL
JCR impact factor
2.051 (2016)
JCR rank
52/135 (2016)
JCR quartile
2 (2016)
ISSN
0930-7516
DOI
10.1002/ceat.201600216
language
English
UGent publication?
yes
classification
A1
id
8507461
handle
http://hdl.handle.net/1854/LU-8507461
date created
2017-02-03 14:32:24
date last changed
2017-03-09 12:56:06
@article{8507461,
  abstract     = {Oxidative coupling of methane is a low-cost alternative for ethylene production. However, its high exothermicity, complex reaction network, and low selectivity to C-2 products require more in-depth analysis for economically viable process implementation. Microkinetic modeling enables assessment of operating conditions and catalyst properties on the overall performance via elementary gas-phase and catalytic reactions. The know-how to reproduce and interpret experimental kinetic data, especially the role of highly reactive intermediate species, is crucial for correct reaction network determination. Once the catalyst descriptors, physical catalyst properties, and operating conditions are determined and optimized, next catalyst generations can be developed tailored to the process implementation.},
  author       = {Obradovi\'{c}, Ana and Thybaut, Joris and Marin, Guy},
  issn         = {0930-7516},
  journal      = {CHEMICAL ENGINEERING \& TECHNOLOGY                                        },
  keyword      = {METAL-ORGANIC FRAMEWORKS,OXYGEN MOBILITY,GAS-PHASE,COMBUSTION CHEMISTRY,CARBON-DIOXIDE,NATURAL-GAS,CATALYSTS,CONVERSION,HYDROCARBONS,SEPARATION},
  language     = {eng},
  number       = {11},
  pages        = {1996--2010},
  publisher    = {Wiley-Blackwell},
  title        = {Oxidative coupling of methane : opportunities for microkinetic model-assisted process implementations},
  url          = {http://dx.doi.org/10.1002/ceat.201600216},
  volume       = {39},
  year         = {2016},
}

Chicago
Obradović, Ana, Joris Thybaut, and Guy Marin. 2016. “Oxidative Coupling of Methane : Opportunities for Microkinetic Model-assisted Process Implementations.” Chemical Engineering & Technology  39 (11): 1996–2010.
APA
Obradović, A., Thybaut, J., & Marin, G. (2016). Oxidative coupling of methane : opportunities for microkinetic model-assisted process implementations. CHEMICAL ENGINEERING & TECHNOLOGY  , 39(11), 1996–2010.
Vancouver
1.
Obradović A, Thybaut J, Marin G. Oxidative coupling of methane : opportunities for microkinetic model-assisted process implementations. CHEMICAL ENGINEERING & TECHNOLOGY  . Wiley-Blackwell; 2016;39(11):1996–2010.
MLA
Obradović, Ana, Joris Thybaut, and Guy Marin. “Oxidative Coupling of Methane : Opportunities for Microkinetic Model-assisted Process Implementations.” CHEMICAL ENGINEERING & TECHNOLOGY  39.11 (2016): 1996–2010. Print.