Advanced search
1 file | 757.80 KB

Oxidative coupling of methane : opportunities for microkinetic model-assisted process implementations

Ana Obradović (UGent) , Joris Thybaut (UGent) and Guy Marin (UGent)
(2016) CHEMICAL ENGINEERING & TECHNOLOGY . 39(11). p.1996-2010
Author
Organization
Abstract
Oxidative coupling of methane is a low-cost alternative for ethylene production. However, its high exothermicity, complex reaction network, and low selectivity to C-2 products require more in-depth analysis for economically viable process implementation. Microkinetic modeling enables assessment of operating conditions and catalyst properties on the overall performance via elementary gas-phase and catalytic reactions. The know-how to reproduce and interpret experimental kinetic data, especially the role of highly reactive intermediate species, is crucial for correct reaction network determination. Once the catalyst descriptors, physical catalyst properties, and operating conditions are determined and optimized, next catalyst generations can be developed tailored to the process implementation.
Keywords
METAL-ORGANIC FRAMEWORKS, OXYGEN MOBILITY, GAS-PHASE, COMBUSTION CHEMISTRY, CARBON-DIOXIDE, NATURAL-GAS, CATALYSTS, CONVERSION, HYDROCARBONS, SEPARATION

Downloads

  • (...).pdf
    • full text
    • |
    • UGent only
    • |
    • PDF
    • |
    • 757.80 KB

Citation

Please use this url to cite or link to this publication:

Chicago
Obradović, Ana, Joris Thybaut, and Guy Marin. 2016. “Oxidative Coupling of Methane : Opportunities for Microkinetic Model-assisted Process Implementations.” Chemical Engineering & Technology  39 (11): 1996–2010.
APA
Obradović, A., Thybaut, J., & Marin, G. (2016). Oxidative coupling of methane : opportunities for microkinetic model-assisted process implementations. CHEMICAL ENGINEERING & TECHNOLOGY  , 39(11), 1996–2010.
Vancouver
1.
Obradović A, Thybaut J, Marin G. Oxidative coupling of methane : opportunities for microkinetic model-assisted process implementations. CHEMICAL ENGINEERING & TECHNOLOGY  . Wiley-Blackwell; 2016;39(11):1996–2010.
MLA
Obradović, Ana, Joris Thybaut, and Guy Marin. “Oxidative Coupling of Methane : Opportunities for Microkinetic Model-assisted Process Implementations.” CHEMICAL ENGINEERING & TECHNOLOGY  39.11 (2016): 1996–2010. Print.
@article{8507461,
  abstract     = {Oxidative coupling of methane is a low-cost alternative for ethylene production. However, its high exothermicity, complex reaction network, and low selectivity to C-2 products require more in-depth analysis for economically viable process implementation. Microkinetic modeling enables assessment of operating conditions and catalyst properties on the overall performance via elementary gas-phase and catalytic reactions. The know-how to reproduce and interpret experimental kinetic data, especially the role of highly reactive intermediate species, is crucial for correct reaction network determination. Once the catalyst descriptors, physical catalyst properties, and operating conditions are determined and optimized, next catalyst generations can be developed tailored to the process implementation.},
  author       = {Obradovi\'{c}, Ana and Thybaut, Joris and Marin, Guy},
  issn         = {0930-7516},
  journal      = {CHEMICAL ENGINEERING \& TECHNOLOGY                                        },
  keyword      = {METAL-ORGANIC FRAMEWORKS,OXYGEN MOBILITY,GAS-PHASE,COMBUSTION CHEMISTRY,CARBON-DIOXIDE,NATURAL-GAS,CATALYSTS,CONVERSION,HYDROCARBONS,SEPARATION},
  language     = {eng},
  number       = {11},
  pages        = {1996--2010},
  publisher    = {Wiley-Blackwell},
  title        = {Oxidative coupling of methane : opportunities for microkinetic model-assisted process implementations},
  url          = {http://dx.doi.org/10.1002/ceat.201600216},
  volume       = {39},
  year         = {2016},
}

Altmetric
View in Altmetric