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Bicyclic aziridinium ions in azaheterocyclic chemistry : preparation and synthetic application of 1-azoniabicyclo[n.1.0]alkanes

(2016) ADVANCED SYNTHESIS & CATALYSIS. 358(22). p.3485-3511
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Abstract
Recent advances in the field of ring-expansion chemistry, involving 1-azoniabicyclo[n.1.0]alkane scaffolds (bicyclic aziridinium ions) as key transient intermediates, have made it possible to efficiently construct a broad variety of medium-and large-sized functionalized nitrogen-containing heterocycles. In this tutorial review, a comprehensive survey of all pathways leading to the generation of 1-azoniabicyclo[n.1.0]alkanes is provided, as well as a discussion on their subsequent ring expansions to relevant azaheterocycles governed by ring size, substitution pattern, and/or nature of applied nucleophiles.
Keywords
Organic Chemistry, Catalysis

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MLA
Dolfen, Jeroen et al. “Bicyclic Aziridinium Ions in Azaheterocyclic Chemistry : Preparation and Synthetic Application of 1-azoniabicyclo[n.1.0]alkanes.” ADVANCED SYNTHESIS & CATALYSIS 358.22 (2016): 3485–3511. Print.
APA
Dolfen, J., Yadav, N. N., De Kimpe, N., D’hooghe, M., & Ha, H.-J. (2016). Bicyclic aziridinium ions in azaheterocyclic chemistry : preparation and synthetic application of 1-azoniabicyclo[n.1.0]alkanes. ADVANCED SYNTHESIS & CATALYSIS, 358(22), 3485–3511.
Chicago author-date
Dolfen, Jeroen, Nagendra Nath Yadav, Norbert De Kimpe, Matthias D’hooghe, and Hyun-Joon Ha. 2016. “Bicyclic Aziridinium Ions in Azaheterocyclic Chemistry : Preparation and Synthetic Application of 1-azoniabicyclo[n.1.0]alkanes.” Advanced Synthesis & Catalysis 358 (22): 3485–3511.
Chicago author-date (all authors)
Dolfen, Jeroen, Nagendra Nath Yadav, Norbert De Kimpe, Matthias D’hooghe, and Hyun-Joon Ha. 2016. “Bicyclic Aziridinium Ions in Azaheterocyclic Chemistry : Preparation and Synthetic Application of 1-azoniabicyclo[n.1.0]alkanes.” Advanced Synthesis & Catalysis 358 (22): 3485–3511.
Vancouver
1.
Dolfen J, Yadav NN, De Kimpe N, D’hooghe M, Ha H-J. Bicyclic aziridinium ions in azaheterocyclic chemistry : preparation and synthetic application of 1-azoniabicyclo[n.1.0]alkanes. ADVANCED SYNTHESIS & CATALYSIS. 2016;358(22):3485–511.
IEEE
[1]
J. Dolfen, N. N. Yadav, N. De Kimpe, M. D’hooghe, and H.-J. Ha, “Bicyclic aziridinium ions in azaheterocyclic chemistry : preparation and synthetic application of 1-azoniabicyclo[n.1.0]alkanes,” ADVANCED SYNTHESIS & CATALYSIS, vol. 358, no. 22, pp. 3485–3511, 2016.
@article{8500774,
  abstract     = {Recent advances in the field of ring-expansion chemistry, involving 1-azoniabicyclo[n.1.0]alkane scaffolds (bicyclic aziridinium ions) as key transient intermediates, have made it possible to efficiently construct a broad variety of medium-and large-sized functionalized nitrogen-containing heterocycles. In this tutorial review, a comprehensive survey of all pathways leading to the generation of 1-azoniabicyclo[n.1.0]alkanes is provided, as well as a discussion on their subsequent ring expansions to relevant azaheterocycles governed by ring size, substitution pattern, and/or nature of applied nucleophiles.},
  author       = {Dolfen, Jeroen and Yadav, Nagendra Nath and De Kimpe, Norbert and D'hooghe, Matthias and Ha, Hyun-Joon},
  issn         = {1615-4150},
  journal      = {ADVANCED SYNTHESIS & CATALYSIS},
  keywords     = {Organic Chemistry,Catalysis},
  language     = {eng},
  number       = {22},
  pages        = {3485--3511},
  title        = {Bicyclic aziridinium ions in azaheterocyclic chemistry : preparation and synthetic application of 1-azoniabicyclo[n.1.0]alkanes},
  url          = {http://dx.doi.org/10.1002/adsc.201600750},
  volume       = {358},
  year         = {2016},
}

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