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Tuning of polymeric nanoparticles by coassembly of thermoresponsive polymers and a double hydrophilic thermoresponsive block copolymer

(2016) JOURNAL OF PHYSICAL CHEMISTRY B. 120(20). p.4635-4643
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Abstract
The coassembly behavior of thermoresponsive statistical copolymers and a double hydrophilic block copolymer having a permanently hydrophilic block and a thermoresponsive block is investigated. By adjusting the hydrophilicity of the thermoresponsive statistical copolymers, hybrid nanoparticles are obtained with various ratios of the two species. Importantly, the size of these nanoparticles can be controlled in between 40 and 250 nm dependent on the To, and the amount of statistical copolymers in the solution. Simultaneous analysis of static and dynamic light scattering data indicates that the possible structure of nanoparticles varies from hard sphere to less compact architecture and most probably depends on a difference between cloud point temperatures of individual components. This developed coassembly method provides a simple platform for the preparation of defined polymeric nanoparticles.
Keywords
FRAGMENTATION CHAIN TRANSFER, DYNAMIC LIGHT-SCATTERING, LIVING RADICAL POLYMERIZATION, RAFT PROCESS, PEGYLATED POLYPLEX, BRANCHED POLYMERS, DRUG-DELIVERY, MICELLES, POLYDISPERSITY, VESICLES

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MLA
Zhang, Qilu, Lenny Voorhaar, Sergey K Filippov, et al. “Tuning of Polymeric Nanoparticles by Coassembly of Thermoresponsive Polymers and a Double Hydrophilic Thermoresponsive Block Copolymer.” JOURNAL OF PHYSICAL CHEMISTRY B 120.20 (2016): 4635–4643. Print.
APA
Zhang, Qilu, Voorhaar, L., Filippov, S. K., Yesil, B. F., & Hoogenboom, R. (2016). Tuning of polymeric nanoparticles by coassembly of thermoresponsive polymers and a double hydrophilic thermoresponsive block copolymer. JOURNAL OF PHYSICAL CHEMISTRY B, 120(20), 4635–4643.
Chicago author-date
Zhang, Qilu, Lenny Voorhaar, Sergey K Filippov, Berin Fatma Yesil, and Richard Hoogenboom. 2016. “Tuning of Polymeric Nanoparticles by Coassembly of Thermoresponsive Polymers and a Double Hydrophilic Thermoresponsive Block Copolymer.” Journal of Physical Chemistry B 120 (20): 4635–4643.
Chicago author-date (all authors)
Zhang, Qilu, Lenny Voorhaar, Sergey K Filippov, Berin Fatma Yesil, and Richard Hoogenboom. 2016. “Tuning of Polymeric Nanoparticles by Coassembly of Thermoresponsive Polymers and a Double Hydrophilic Thermoresponsive Block Copolymer.” Journal of Physical Chemistry B 120 (20): 4635–4643.
Vancouver
1.
Zhang Q, Voorhaar L, Filippov SK, Yesil BF, Hoogenboom R. Tuning of polymeric nanoparticles by coassembly of thermoresponsive polymers and a double hydrophilic thermoresponsive block copolymer. JOURNAL OF PHYSICAL CHEMISTRY B. 2016;120(20):4635–43.
IEEE
[1]
Q. Zhang, L. Voorhaar, S. K. Filippov, B. F. Yesil, and R. Hoogenboom, “Tuning of polymeric nanoparticles by coassembly of thermoresponsive polymers and a double hydrophilic thermoresponsive block copolymer,” JOURNAL OF PHYSICAL CHEMISTRY B, vol. 120, no. 20, pp. 4635–4643, 2016.
@article{8201455,
  abstract     = {The coassembly behavior of thermoresponsive statistical copolymers and a double hydrophilic block copolymer having a permanently hydrophilic block and a thermoresponsive block is investigated. By adjusting the hydrophilicity of the thermoresponsive statistical copolymers, hybrid nanoparticles are obtained with various ratios of the two species. Importantly, the size of these nanoparticles can be controlled in between 40 and 250 nm dependent on the To, and the amount of statistical copolymers in the solution. Simultaneous analysis of static and dynamic light scattering data indicates that the possible structure of nanoparticles varies from hard sphere to less compact architecture and most probably depends on a difference between cloud point temperatures of individual components. This developed coassembly method provides a simple platform for the preparation of defined polymeric nanoparticles.},
  author       = {Zhang, Qilu and Voorhaar, Lenny and Filippov, Sergey K and Yesil, Berin Fatma and Hoogenboom, Richard},
  issn         = {1520-6106},
  journal      = {JOURNAL OF PHYSICAL CHEMISTRY B},
  keywords     = {FRAGMENTATION CHAIN TRANSFER,DYNAMIC LIGHT-SCATTERING,LIVING RADICAL POLYMERIZATION,RAFT PROCESS,PEGYLATED POLYPLEX,BRANCHED POLYMERS,DRUG-DELIVERY,MICELLES,POLYDISPERSITY,VESICLES},
  language     = {eng},
  number       = {20},
  pages        = {4635--4643},
  title        = {Tuning of polymeric nanoparticles by coassembly of thermoresponsive polymers and a double hydrophilic thermoresponsive block copolymer},
  url          = {http://dx.doi.org/10.1021/acs.jpcb.6b03414},
  volume       = {120},
  year         = {2016},
}

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