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Organolanthanide-catalyzed dehydrogenative coupling of silanes : mechanistic implications

(1991) ORGANOMETALLICS. 10(8). p.2543-2545
Author
Organization
Abstract
Organolanthanide complexes of the type Cp'2LnR (Cp' = eta-5-Me5C5; Ln = La, Nd, Sm, Y, Lu; R = Nd; R = CH(SiMe3)2), Cp'2Sm, and Cp'2Sm(THF)2 catalyze the rapid dehydrogenative oligomerization of PhSiH3. Kinetic and mechanistic arguments exclude the importance of metal-centered redox processes in the catalytic cycle and support instead ''four-center'' ''heterolytic'' bond-scission/bond-forming sequences.
Keywords
HIGHLY REACTIVE ORGANOLANTHANIDES, POLYSILANE HIGH POLYMERS, HYDRIDE COMPLEXES, POLYMERIZATION, CHEMISTRY, ROUTES, BIS(PENTAMETHYLCYCLOPENTADIENYL), HYDROGENATION, HYDROSILATION, DERIVATIVES

Citation

Please use this url to cite or link to this publication:

MLA
Forsyth, CM, et al. “Organolanthanide-Catalyzed Dehydrogenative Coupling of Silanes : Mechanistic Implications.” ORGANOMETALLICS, vol. 10, no. 8, 1991, pp. 2543–45.
APA
Forsyth, C., Nolan, S., & Marks, T. (1991). Organolanthanide-catalyzed dehydrogenative coupling of silanes : mechanistic implications. ORGANOMETALLICS, 10(8), 2543–2545.
Chicago author-date
Forsyth, CM, Steven Nolan, and TJ Marks. 1991. “Organolanthanide-Catalyzed Dehydrogenative Coupling of Silanes : Mechanistic Implications.” ORGANOMETALLICS 10 (8): 2543–45.
Chicago author-date (all authors)
Forsyth, CM, Steven Nolan, and TJ Marks. 1991. “Organolanthanide-Catalyzed Dehydrogenative Coupling of Silanes : Mechanistic Implications.” ORGANOMETALLICS 10 (8): 2543–2545.
Vancouver
1.
Forsyth C, Nolan S, Marks T. Organolanthanide-catalyzed dehydrogenative coupling of silanes : mechanistic implications. ORGANOMETALLICS. 1991;10(8):2543–5.
IEEE
[1]
C. Forsyth, S. Nolan, and T. Marks, “Organolanthanide-catalyzed dehydrogenative coupling of silanes : mechanistic implications,” ORGANOMETALLICS, vol. 10, no. 8, pp. 2543–2545, 1991.
@article{8171493,
  abstract     = {Organolanthanide complexes of the type Cp'2LnR (Cp' = eta-5-Me5C5; Ln = La, Nd, Sm, Y, Lu; R = Nd; R = CH(SiMe3)2), Cp'2Sm, and Cp'2Sm(THF)2 catalyze the rapid dehydrogenative oligomerization of PhSiH3. Kinetic and mechanistic arguments exclude the importance of metal-centered redox processes in the catalytic cycle and support instead ''four-center'' ''heterolytic'' bond-scission/bond-forming sequences.},
  author       = {Forsyth, CM and Nolan, Steven and Marks, TJ},
  issn         = {0276-7333},
  journal      = {ORGANOMETALLICS},
  keywords     = {HIGHLY REACTIVE ORGANOLANTHANIDES,POLYSILANE HIGH POLYMERS,HYDRIDE COMPLEXES,POLYMERIZATION,CHEMISTRY,ROUTES,BIS(PENTAMETHYLCYCLOPENTADIENYL),HYDROGENATION,HYDROSILATION,DERIVATIVES},
  language     = {eng},
  number       = {8},
  pages        = {2543--2545},
  title        = {Organolanthanide-catalyzed dehydrogenative coupling of silanes : mechanistic implications},
  url          = {http://dx.doi.org/10.1021/om00054a008},
  volume       = {10},
  year         = {1991},
}

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