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Regioselective synthesis of η3-(N-methoxycarbonyl-7-azabicyclo[2.2.1]hepta-2,5-dienyl)-η5-(C5Me5)RuCl complexes

Author
Organization
Abstract
The reactions of Cp*Ru(COD)Cl and CpRu(COD)Cl with N-methoxycarbonyl-7-azabicyclo[2.2.1]hepta-2,5-diene derivatives were found to give eta(3)-[N(CO2Me)C6H3(2-p-MeC6H4SO2)(6-CO2Me)(5-Me)]CpRuCl and eta(3)-[N(CO2Me)-7-azabicyclo[2.2.1]heptadienyl]Cp*RuCl complexes in good yields (54-78%). The coordination reaction was found to take place regioselectively at the least substituted pi-bond of the N-methoxycarbonyl-7-azabicyclo[2.2.1]hepta-2,5-diene derivatives. The structures of the complexes were determined by H-1 and C-13 NMR and the structure of eta(3)-[N(CO2Me)C6H3(2-p-MeC6H4SO2)(6-CO2Me)(5-Me)]Cp*RuCl was unequivocally established by X-ray crystallography.
Keywords
7-azabicyclo[2.2.1]heptadienes, regioselective, ruthenium, olefin complexes, 7-AZANORBORNADIENE DERIVATIVES, ENTHALPIES, LIGANDS

Citation

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Chicago
Chen, Zhengming, Lubin Luo, Steven Nolan, Jeffrey L Petersen, and Mark L Trudell. 1997. “Regioselective Synthesis of η3-(N-methoxycarbonyl-7-azabicyclo[2.2.1]hepta-2,5-dienyl)-η5-(C5Me5)RuCl Complexes.” Journal of Organometallic Chemistry 533 (1-2): 25–30.
APA
Chen, Zhengming, Luo, L., Nolan, S., Petersen, J. L., & Trudell, M. L. (1997). Regioselective synthesis of η3-(N-methoxycarbonyl-7-azabicyclo[2.2.1]hepta-2,5-dienyl)-η5-(C5Me5)RuCl complexes. JOURNAL OF ORGANOMETALLIC CHEMISTRY, 533(1-2), 25–30.
Vancouver
1.
Chen Z, Luo L, Nolan S, Petersen JL, Trudell ML. Regioselective synthesis of η3-(N-methoxycarbonyl-7-azabicyclo[2.2.1]hepta-2,5-dienyl)-η5-(C5Me5)RuCl complexes. JOURNAL OF ORGANOMETALLIC CHEMISTRY. 1997;533(1-2):25–30.
MLA
Chen, Zhengming, Lubin Luo, Steven Nolan, et al. “Regioselective Synthesis of η3-(N-methoxycarbonyl-7-azabicyclo[2.2.1]hepta-2,5-dienyl)-η5-(C5Me5)RuCl Complexes.” JOURNAL OF ORGANOMETALLIC CHEMISTRY 533.1-2 (1997): 25–30. Print.
@article{8171156,
  abstract     = {The reactions of Cp*Ru(COD)Cl and CpRu(COD)Cl with N-methoxycarbonyl-7-azabicyclo[2.2.1]hepta-2,5-diene derivatives were found to give eta(3)-[N(CO2Me)C6H3(2-p-MeC6H4SO2)(6-CO2Me)(5-Me)]CpRuCl and eta(3)-[N(CO2Me)-7-azabicyclo[2.2.1]heptadienyl]Cp*RuCl complexes in good yields (54-78\%). The coordination reaction was found to take place regioselectively at the least substituted pi-bond of the N-methoxycarbonyl-7-azabicyclo[2.2.1]hepta-2,5-diene derivatives. The structures of the complexes were determined by H-1 and C-13 NMR and the structure of eta(3)-[N(CO2Me)C6H3(2-p-MeC6H4SO2)(6-CO2Me)(5-Me)]Cp*RuCl was unequivocally established by X-ray crystallography.},
  author       = {Chen, Zhengming and Luo, Lubin and Nolan, Steven and Petersen, Jeffrey L and Trudell, Mark L},
  issn         = {0022-328X},
  journal      = {JOURNAL OF ORGANOMETALLIC CHEMISTRY},
  keyword      = {7-azabicyclo[2.2.1]heptadienes,regioselective,ruthenium,olefin complexes,7-AZANORBORNADIENE DERIVATIVES,ENTHALPIES,LIGANDS},
  language     = {eng},
  number       = {1-2},
  pages        = {25--30},
  title        = {Regioselective synthesis of \ensuremath{\eta}3-(N-methoxycarbonyl-7-azabicyclo[2.2.1]hepta-2,5-dienyl)-\ensuremath{\eta}5-(C5Me5)RuCl complexes},
  url          = {http://dx.doi.org/10.1016/S0022-328X(96)06827-1},
  volume       = {533},
  year         = {1997},
}

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