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N-pyrrolyl phosphines : enhanced π-acceptor character via carboalkoxy substitution

(1997) ORGANOMETALLICS. 16(15). p.3377-3380
Author
Organization
Abstract
A series of 3,4-dicarboethoxy-N-pyrrolyl phosphine ligands (R2P-NC4H2(CO2Et)(2)) is described. A number of techniques, including reaction calorimetry, infrared spectroscopy, and X-ray crystallography, demonstrate that these ligands are potent pi-acceptors and that the electronic substituent parameter chi(i) for the 3,4-(EtO2C)(2)C4H2N moiety is ca. 16, placing it in a position between fluorine and chlorine.
Keywords
REACTIVITY, COMPLEXES, LIGANDS, MOLYBDENUM, CHEMISTRY

Citation

Please use this url to cite or link to this publication:

MLA
Huang, A., et al. “N-Pyrrolyl Phosphines : Enhanced π-Acceptor Character via Carboalkoxy Substitution.” ORGANOMETALLICS, vol. 16, no. 15, 1997, pp. 3377–80.
APA
Huang, A., Marcone, J., Mason, K., Marshall, W., Moloy, K., Serron, S., & Nolan, S. (1997). N-pyrrolyl phosphines : enhanced π-acceptor character via carboalkoxy substitution. ORGANOMETALLICS, 16(15), 3377–3380.
Chicago author-date
Huang, A, JE Marcone, KL Mason, WJ Marshall, KG Moloy, S Serron, and Steven Nolan. 1997. “N-Pyrrolyl Phosphines : Enhanced π-Acceptor Character via Carboalkoxy Substitution.” ORGANOMETALLICS 16 (15): 3377–80.
Chicago author-date (all authors)
Huang, A, JE Marcone, KL Mason, WJ Marshall, KG Moloy, S Serron, and Steven Nolan. 1997. “N-Pyrrolyl Phosphines : Enhanced π-Acceptor Character via Carboalkoxy Substitution.” ORGANOMETALLICS 16 (15): 3377–3380.
Vancouver
1.
Huang A, Marcone J, Mason K, Marshall W, Moloy K, Serron S, et al. N-pyrrolyl phosphines : enhanced π-acceptor character via carboalkoxy substitution. ORGANOMETALLICS. 1997;16(15):3377–80.
IEEE
[1]
A. Huang et al., “N-pyrrolyl phosphines : enhanced π-acceptor character via carboalkoxy substitution,” ORGANOMETALLICS, vol. 16, no. 15, pp. 3377–3380, 1997.
@article{8171147,
  abstract     = {A series of 3,4-dicarboethoxy-N-pyrrolyl phosphine ligands (R2P-NC4H2(CO2Et)(2)) is described. A number of techniques, including reaction calorimetry, infrared spectroscopy, and X-ray crystallography, demonstrate that these ligands are potent pi-acceptors and that the electronic substituent parameter chi(i) for the 3,4-(EtO2C)(2)C4H2N moiety is ca. 16, placing it in a position between fluorine and chlorine.},
  author       = {Huang, A and Marcone, JE and Mason, KL and Marshall, WJ and Moloy, KG and Serron, S and Nolan, Steven},
  issn         = {0276-7333},
  journal      = {ORGANOMETALLICS},
  keywords     = {REACTIVITY,COMPLEXES,LIGANDS,MOLYBDENUM,CHEMISTRY},
  language     = {eng},
  number       = {15},
  pages        = {3377--3380},
  title        = {N-pyrrolyl phosphines : enhanced π-acceptor character via carboalkoxy substitution},
  url          = {http://dx.doi.org/10.1021/om970129q},
  volume       = {16},
  year         = {1997},
}

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