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Correlation between structural and solution calorimetric data for Cp*Ru(PR3)2Cl (Cp* = C5Me5) complexes

(1999) ORGANOMETALLICS. 18(12). p.2357-2361
Author
Organization
Abstract
Single-crystal X-ray diffraction studies were conducted bn the following compounds: Cp*Ru(PMe3)(2)Cl (1), Cp*Ru(PPhMe2)(2)Cl (2), Cp*Ru(PMePh2)(2)Cl (3), Cp*Ru(PPh3)(2)Cl (4), Cp*Ru(PEt3)(2)Cl (5), Cp*Ru(AsEt3)(2)Cl (6), Cp*Ru((PBu3)-Bu-n)(2)Cl (7), and Cp*Ru(dmpm)Cl (8). Structural information obtained from these X-ray studies can be correlated with enthalpies of ligand substitution previously determined from solution calorimetry. The cone angle of the phosphine ligand (monodentate) and the Ru-P bond distance were found to be proportional to the enthalpy of reaction.
Keywords
TERTIARY PHOSPHINE-LIGANDS, ORGANORUTHENIUM THERMOCHEMISTRY, PHOSPHORUS LIGANDS, ENTHALPIES, SUBSTITUTION, ENERGIES, SYSTEM, MONODENTATE, CHEMISTRY, FRAGMENT

Citation

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MLA
Smith, DC, et al. “Correlation between Structural and Solution Calorimetric Data for Cp*Ru(PR3)2Cl (Cp* = C5Me5) Complexes.” ORGANOMETALLICS, vol. 18, no. 12, 1999, pp. 2357–61.
APA
Smith, D., Haar, C., Luo, L., Li, C., Cucullu, M., Mahler, C., … Fagan, P. (1999). Correlation between structural and solution calorimetric data for Cp*Ru(PR3)2Cl (Cp* = C5Me5) complexes. ORGANOMETALLICS, 18(12), 2357–2361.
Chicago author-date
Smith, DC, CM Haar, LB Luo, CB Li, ME Cucullu, CH Mahler, Steven Nolan, WJ Marshall, NL Jones, and PJ Fagan. 1999. “Correlation between Structural and Solution Calorimetric Data for Cp*Ru(PR3)2Cl (Cp* = C5Me5) Complexes.” ORGANOMETALLICS 18 (12): 2357–61.
Chicago author-date (all authors)
Smith, DC, CM Haar, LB Luo, CB Li, ME Cucullu, CH Mahler, Steven Nolan, WJ Marshall, NL Jones, and PJ Fagan. 1999. “Correlation between Structural and Solution Calorimetric Data for Cp*Ru(PR3)2Cl (Cp* = C5Me5) Complexes.” ORGANOMETALLICS 18 (12): 2357–2361.
Vancouver
1.
Smith D, Haar C, Luo L, Li C, Cucullu M, Mahler C, et al. Correlation between structural and solution calorimetric data for Cp*Ru(PR3)2Cl (Cp* = C5Me5) complexes. ORGANOMETALLICS. 1999;18(12):2357–61.
IEEE
[1]
D. Smith et al., “Correlation between structural and solution calorimetric data for Cp*Ru(PR3)2Cl (Cp* = C5Me5) complexes,” ORGANOMETALLICS, vol. 18, no. 12, pp. 2357–2361, 1999.
@article{8170943,
  abstract     = {Single-crystal X-ray diffraction studies were conducted bn the following compounds: Cp*Ru(PMe3)(2)Cl (1), Cp*Ru(PPhMe2)(2)Cl (2), Cp*Ru(PMePh2)(2)Cl (3), Cp*Ru(PPh3)(2)Cl (4), Cp*Ru(PEt3)(2)Cl (5), Cp*Ru(AsEt3)(2)Cl (6), Cp*Ru((PBu3)-Bu-n)(2)Cl (7), and Cp*Ru(dmpm)Cl (8). Structural information obtained from these X-ray studies can be correlated with enthalpies of ligand substitution previously determined from solution calorimetry. The cone angle of the phosphine ligand (monodentate) and the Ru-P bond distance were found to be proportional to the enthalpy of reaction.},
  author       = {Smith, DC and Haar, CM and Luo, LB and Li, CB and Cucullu, ME and Mahler, CH and Nolan, Steven and Marshall, WJ and Jones, NL and Fagan, PJ},
  issn         = {0276-7333},
  journal      = {ORGANOMETALLICS},
  keywords     = {TERTIARY PHOSPHINE-LIGANDS,ORGANORUTHENIUM THERMOCHEMISTRY,PHOSPHORUS LIGANDS,ENTHALPIES,SUBSTITUTION,ENERGIES,SYSTEM,MONODENTATE,CHEMISTRY,FRAGMENT},
  language     = {eng},
  number       = {12},
  pages        = {2357--2361},
  title        = {Correlation between structural and solution calorimetric data for Cp*Ru(PR3)2Cl (Cp* = C5Me5) complexes},
  url          = {http://dx.doi.org/10.1021/om990090k},
  volume       = {18},
  year         = {1999},
}

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