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Synthetic and solution calorimetric investigations of chelating phosphine ligands in Ru(allyl)(2)(PP) complexes (PP = diphosphine)

D Smith, J Cadoret, L Jafarpour, ED Stevens and Steven Nolan UGent (2001) CANADIAN JOURNAL OF CHEMISTRY-REVUE CANADIENNE DE CHIMIE. 79(5-6). p.626-631
abstract
Reaction enthalpies of (COD)Ru(allyl)(2) (COD = eta (4)-1,5-cyclooctadiene; allyl = 2-methylpropenyl) with a series of bidentate phosphines (dppm, dppf, dppe, dppb, dppp, depe, dmpe) have been measured by anaerobic solution calorimetry. The relative stability of the resulting complexes is strongly influenced by the electronic donor properties of the bidentate phosphine ligand. Reactions involving ligands that are better sigma donors result in higher enthalpy values and, therefore, more thermodynamically stable complexes. Additionally, the synthesis and characterization of two new ruthenium allyl complexes Ru(allyl)2(dppf) (3) and Ru(allyl)(2)(depe) (8) and the X-ray crystal structure of 3 are reported.
Please use this url to cite or link to this publication:
author
organization
year
type
journalArticle (original)
publication status
published
subject
keyword
ruthenium, allyl, solution calorimetry, thermodynamics, X-ray structure, DYNAMIC KINETIC RESOLUTION, ORGANORUTHENIUM THERMOCHEMISTRY, PHOSPHORUS LIGANDS, GENERAL-SYNTHESIS, ENTHALPIES, BOND, CATALYSTS, SUBSTITUTION, ESTERS, HYDROGENATION
journal title
CANADIAN JOURNAL OF CHEMISTRY-REVUE CANADIENNE DE CHIMIE
Can. J. Chem.-Rev. Can. Chim.
volume
79
issue
5-6
pages
626 - 631
Web of Science type
Article
Web of Science id
000170070900024
JCR category
CHEMISTRY, MULTIDISCIPLINARY
JCR impact factor
1.144 (2001)
JCR rank
37/118 (2001)
JCR quartile
2 (2001)
ISSN
0008-4042
language
English
UGent publication?
no
classification
A1
id
8170690
handle
http://hdl.handle.net/1854/LU-8170690
date created
2016-11-24 15:58:26
date last changed
2018-01-29 12:12:30
@article{8170690,
  abstract     = {Reaction enthalpies of (COD)Ru(allyl)(2) (COD = eta (4)-1,5-cyclooctadiene; allyl = 2-methylpropenyl) with a series of bidentate phosphines (dppm, dppf, dppe, dppb, dppp, depe, dmpe) have been measured by anaerobic solution calorimetry. The relative stability of the resulting complexes is strongly influenced by the electronic donor properties of the bidentate phosphine ligand. Reactions involving ligands that are better sigma donors result in higher enthalpy values and, therefore, more thermodynamically stable complexes. Additionally, the synthesis and characterization of two new ruthenium allyl complexes Ru(allyl)2(dppf) (3) and Ru(allyl)(2)(depe) (8) and the X-ray crystal structure of 3 are reported.},
  author       = {Smith, D and Cadoret, J and Jafarpour, L and Stevens, ED and Nolan, Steven},
  issn         = {0008-4042},
  journal      = {CANADIAN JOURNAL OF CHEMISTRY-REVUE CANADIENNE DE CHIMIE},
  keyword      = {ruthenium,allyl,solution calorimetry,thermodynamics,X-ray structure,DYNAMIC KINETIC RESOLUTION,ORGANORUTHENIUM THERMOCHEMISTRY,PHOSPHORUS LIGANDS,GENERAL-SYNTHESIS,ENTHALPIES,BOND,CATALYSTS,SUBSTITUTION,ESTERS,HYDROGENATION},
  language     = {eng},
  number       = {5-6},
  pages        = {626--631},
  title        = {Synthetic and solution calorimetric investigations of chelating phosphine ligands in Ru(allyl)(2)(PP) complexes (PP = diphosphine)},
  volume       = {79},
  year         = {2001},
}

Chicago
Smith, D, J Cadoret, L Jafarpour, ED Stevens, and Steven Nolan. 2001. “Synthetic and Solution Calorimetric Investigations of Chelating Phosphine Ligands in Ru(allyl)(2)(PP) Complexes (PP = Diphosphine).” Canadian Journal of Chemistry-revue Canadienne De Chimie 79 (5-6): 626–631.
APA
Smith, D, Cadoret, J., Jafarpour, L., Stevens, E., & Nolan, S. (2001). Synthetic and solution calorimetric investigations of chelating phosphine ligands in Ru(allyl)(2)(PP) complexes (PP = diphosphine). CANADIAN JOURNAL OF CHEMISTRY-REVUE CANADIENNE DE CHIMIE, 79(5-6), 626–631.
Vancouver
1.
Smith D, Cadoret J, Jafarpour L, Stevens E, Nolan S. Synthetic and solution calorimetric investigations of chelating phosphine ligands in Ru(allyl)(2)(PP) complexes (PP = diphosphine). CANADIAN JOURNAL OF CHEMISTRY-REVUE CANADIENNE DE CHIMIE. 2001;79(5-6):626–31.
MLA
Smith, D, J Cadoret, L Jafarpour, et al. “Synthetic and Solution Calorimetric Investigations of Chelating Phosphine Ligands in Ru(allyl)(2)(PP) Complexes (PP = Diphosphine).” CANADIAN JOURNAL OF CHEMISTRY-REVUE CANADIENNE DE CHIMIE 79.5-6 (2001): 626–631. Print.